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121.
Poly(L ‐lactic acid) (PLLA: Mw = 19.4 × 104)/poly(ethylene glycol) (PEG: Mw = 400) blend films were formed by use of a solvent‐cast technique. The properties and structures of these blend films were investigated. The Young's modulus of the PLLA decreased from 1220 to 417 MPa with the addition of PEG 5 wt %, but the elongation at break increased from 19 to 126%. The melting point of PLLA linearly decreased with increases in the PEG content (i.e., pure PLLA: 172.5°C, PLLA/PEG = 60/40 wt %: 159.6°C). The PEG 20 wt % blend film had a porous structure. The pore diameter was 3–5 μm. The alkali hydrolysis rate of this blend film was accelerated due to its porous structure. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 965–970, 2004 相似文献
122.
由于大部分的生物体都具有相对的自发性、功能性和有效率性,模仿生物体动作的机械研究在工程领域是非常重要的。根据这个观点,我们研究了一种基于水中微生物动作的微型推进机构。 相似文献
123.
Hirotami Nakano Takeshi Tanabe Masanobu Naitoh Yoshiki Kubota Tsuyoshi Morita Toyoaki Kimura Makoto Matsukawa Yushi Miura 《Electrical Engineering in Japan》2000,131(4):1-10
In a balanced three‐phase system, the three‐phase current distortion factor of three‐phase ac power sources has been expressed by applying the conventional single‐phase current distortion factor, which is defined for a single‐phase system. However, in an unbalanced three‐phase system, it is difficult to express the three‐phase current distortion factor for distorted three‐phase ac currents by means of the conventional single‐phase current distortion factor. For instance, the conventional current distortion factors for three‐phase ac currents are usually different from each other in the unbalanced three‐phase system. To solve the above problem, this paper proposes a novel definition of the three‐phase current distortion factor. The proposed three‐phase current distortion factor is quite effective for the unbalanced three‐phase system as well as the balanced three‐phase system. © 2000 Scripta Technica, Electr Eng Jpn, 131(4): 1–10, 2000 相似文献
124.
When the excited triplet states of disperse azo dyes with nitro groups abstract hydrogen to generate hydrazinyl (from azo groups) and nitrosyl hydroxide radicals (from nitro groups), both the radicals as H‐acceptors carry out azo scission, conversion to nitrogen dioxide via disproportionation reactions and self‐decomposition via rearrangement. A kinetic equation was formulated by the sum of these reactions, which describes the initial rates (KPA) of reductive fading. The KPA values were controlled by the rate constants of the reactions of hydrazinyl and nitrosyl hydroxide radicals as H‐acceptors, which were estimated by thermochemical analyses of the reactants, intermediates and end products using the semiempirical molecular orbital PM5 method, and by the concentrations of the reactants: H‐acceptors and H‐donors. The KPA values observed for 12 dyes were explained semi‐quantitatively by multiple routes of reactions depending upon to what extent each radical reaction was thermochemically favoured. 相似文献
125.
Toru Ikegami Tomotake Morita Shunichi Nakayama Hideyuki Negishi Dai Kitamoto Keiji Sakaki Yasunori Oumi Tsuneji Sano Kenji Haraya Hiroshi Yanagishita 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2009,84(8):1172-1177
BACKGROUND: Pervaporation employing ethanol‐permselective silicalite membranes as an alternative to distillation is a promising approach for refining low‐concentration bioethanol solutions. However, to make the separation process practicable, it is extremely important to avoid the problems caused by the adsorption of succinate on the membrane during the separation process. In this work, the pervaporation of an ethanol fermentation broth without succinate was investigated, as well as the influence of several fermentation broth nutrient components. RESULTS: Candida krusei IA‐1 produces an extremely low level of succinate. The decrease in permeate ethanol concentration through a silicone rubber‐coated silicalite membrane during the separation of low‐succinate C. krusei IA‐1 fermentation broth was significantly improved when compared with that obtained using Saccharomyces cerevisiae broth. By treating the fermentation broth with activated carbon, bioethanol was concentrated as efficiently as with binary mixtures of ethanol/water. The total flux was improved upto 56% of that obtained from the separation of binary mixtures, compared with 43% before the addition of activated carbon. Nutrients such as peptone, yeast extract and corn steep liquor had a negative effect on pervaporation, but this response was distinct from that caused by succinate. CONCLUSION: For consistent separation of bioethanol from C. krusei IA‐1 fermentation broth by pervaporation, it is useful to treat the low nutrient broth with activated carbon. To further improve pervaporation performance, it will be necessary to suppress the accumulation of glycerol. Copyright © 2009 Society of Chemical Industry 相似文献
126.
Three commercial kudzu starches from Vietnam, Japan and Korea were used to determine chemical compositions, isoflavone compounds, fine structure and physicochemical properties. The kudzu starch from Vietnam had polygonal granules, whereas the kudzu starches from Japan and Korea contained both polygonal and spherical granules. Total protein, lipid, ash and phosphorus contents present in these kudzu starches were less than 1% (starch basis). The kudzu starch from Vietnam and Korea contained both daidzein and daidzin, whereas the kudzu starch from Japan had only daidzein. These starches had similar actual amylose contents (22.2–22.9%). However, λmax, blue value and apparent amylose contents of the kudzu starch from Vietnam were lower than those from Japan and Korea. Amylose molecules of the kudzu starch from Vietnam had the largest average degree of polymerization (DPn) and number of chains (NC), followed by the kudzu starches from Japan and Korea. Amylopectin molecules of the kudzu starch from Vietnam also had the largest DPn and NC, followed by the kudzu starches from Korea and Japan. X-ray diffraction patterns of the kudzu starches from Vietnam, Japan and Korea were A-type, C-type and B-type, respectively. The kudzu starch from Vietnam was found to have the specific characteristics such as significantly high gelatinization temperature, transition enthalpy and degree of crystallinity as compared to the kudzu starch from Korea and Japan. 相似文献
127.
We retrospectively reviewed 11 patients with culture-proven Acanthamoeba keratitis who presented at the National Taiwan University Hospital between 1989 and 1996. We assessed predisposing factors, initial diagnosis, clinical presentation, treatment, and outcome. A history of contact lens-wear, poor contact lens hygiene, intractable eye pain, and ring infiltrates in the cornea were the most prominent characteristics and clinical manifestations. Acanthamoeba keratitis was often misdiagnosed, with herpetic keratitis (7/11) being the most common initial diagnosis from referring hospitals. These patients were usually treated on the basis of the inaccurate diagnosis for more than 1 month (range 1-8 mo) before referral. All patients ultimately received penetrating keratoplasty because of poor response to delayed medical treatment. We suggest that inadequate contact lens hygiene may be important in Acanthamoeba keratitis. This condition is often misdiagnosed and, as early diagnosis is a major factor for successful medical treatment in such patients, awareness in clinical practice is critical. 相似文献
128.
Yasutaka Hayamizu Kyoji Yamamoto Shinichiro Yanase Toru Hyakutake Toru Shinohara Shinichi Morita 《热科学学报(英文版)》2008,17(3):193-198
An objective of the present paper is to experimentally clarify the torsion effect on the flow in helical circular pipes. We have made six helical circular pipes having different pitches and common non-dimensional curvature δ of about 0.1. The torsion parameter β0, which is defined by β0 = τ/(2δ)1/2 with non-dimensional torsion r, are taken to be 0.02, 0.45, 0.69, 1.01, 1.38 and 1.89 covering from small to very large pitch. The velocity distributions and the turbulence of the flow are measured using an X-type hot-wire anemometer in the range of the Reynolds number from 200 to 20000. The results obtained are summarized as follows: The mean secondary flow pattern in a cross section of the pipe changes from an ordinary twin-vortex type as is seen in a curved pipe without torsion (toroidal pipe) to a single vortex type after one of the twin-vortex gradually disappears as β0 increases. The circulation direction of the single vortex is the same as the direction of torsion of the pipe. The mean velocity distribution of the axial flow is similar to that of the toroidal pipe at small β0, but changes its shape as β0 increases, and attains the shape similar to that in a straight circular pipe when ,β0 = 1.89. It is also found that the critical Reynolds number, at which the flow shows a marginal behavior to turbulence, decreases as ,β0 increases for small ,β0, and then increases after taking a minimum at ,β0 ≈ 1.4 as ,β0 increases. The minimum of the critical Reynolds number experimentally obtained is about 400 at ,β0 ≈ 1.4. 相似文献
129.
We perform a theoretical analysis of frictional-force microscopy(FFM) images of a cleaved graphite surface. The Tomlinson
model with a single-atom tip is powerful for reproducing experimental FFM images. A mapping relation between the tip atom
position and the cantilever basal position obtained by a stable equilibrium condition, gives a clear explanation of the physical
meaning of FFM image patterns.
This revised version was published online in June 2006 with corrections to the Cover Date. 相似文献
130.