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71.
Tong Li 《Polymer Bulletin》1990,24(4):397-404
Summary The photopolymerization of methyl methacrylate initiated by benzophenone-tertiary aromatic amines was studied under irradiation at 365 nm. The initiating amino radicals were investigated with combined ESR and spin-trapping method. The rate of polymerization for different amines was found in the sequence of p-hydroxymethyl-N,N-dimethylaniline>N,N-dimmethyltoluidine>N,N-dimethylaniline>p-methyl-N,N-dihydroxyethylaniline. The influence of diphenylmethanol on the polymerization reveals the incapacity of the benzophenone ketyl radical to initiate, while the amino end-group was detected in the polymers. This end-group can interact with benzophenone again, leading to initiate further polymerization to give a copolymer. 相似文献
72.
Nuclear magnetic resonance spectroscopy has been used to study the dissociation and reaction of N,N′-(2-propyloximino)-4,4′-methylenebis(phenylcarbamate), as a crosslinking agent for polymers containing labile hydrogens. The crosslinking of poly(acrylic acid), polyacrylamide, and poly(vinyl alcohol) was found to result upon heating each to 150°C for 10 min with this component at 2–10 wt %. 相似文献
73.
In this paper, an autonomous relative navigation and joint attitude determination algorithm in asteroid exploration descent stage is researched based on feature point information of perpendicular asteroid surface image observed by optical navigation camera, distance vectors from spacecraft to asteroid measured by three angled installed lidars and relative velocity increment measured by accelerometer when the relative distance vector to the centroid of asteroid can not be obtained. The inertial attitude of spacecraft is determined by sun vector, star vectors and inertial angular velocity respectively measured by sun sensor, star trackers and inertial reference unit. Also, in order to obtain measurement error model transferred from sensor noise, a covariance matrix solver considering error correlation is presented via the error model of normalized vector to first order. Numerical simulation and improved observability evaluation of filtering are undertaken to discuss the results of complete sensor observation and weak observation of lidars, and verify the effectiveness of the presented relative navigation and attitude determination algorithm. 相似文献
74.
A wake-up receiver with high energy efficiency and low power consumption is proposed for solving the power consuming problems of wireless nodes communication in the Internet of Things. The proposed wake-up receiver based on the wake-up mechanism can effectively schedule the network nodes communication, and use the simple envelope detection structure to achieve frequency down-conversion, which can flexibly manage energy and reduce power consumption. Based on UMC 65nm CMOS process technology, the wake-up receiver is designed and simulated. The results show that it can achieve S11 of -21dBm and a sensitivity of -75dBm at a data rate of 1Mb/s, when operating at the central frequency of 780MHz and input signal adopting an on-off keying (OOK) modulation, and the power consumption is 82μW at 1.2V voltage supply. 相似文献
75.
音频大地电磁(AMT)在隧道的工程地质勘察是一种非常有效的方法,它具有不受高阻屏蔽、轻便、探测深度相对较大等优点,在宏观上可以查明隧道地层岩性分界、地质构造及其赋水性。以某隧道音频大地电磁勘察为例,分别对AMT的采集手段、工频干扰去噪、静态校正、反演方法等关键技术问题进行分析,并结合实际资料对该工作区的地层分布、断层及其破碎带的赋水情况等进行分析和解释,在其应用中取得了理想的效果。 相似文献
76.
面向水流系统功能的多维度水资源承载力评价指标体系 总被引:2,自引:0,他引:2
在简述水资源承载力研究进展的基础上,基于系统结构与功能的相互关系和水资源系统的演变特征,从水资源系统自然演化、生态服务和社会服务三大功能推演出水资源系统的水量、水质、水生栖息环境和连通性四维结构,并以此对水资源承载力进行表征。基于对水资源承载主体、客体及承载过程的分析,以水资源承载支撑力、压力和调控力描述承载过程,建立了基于承载过程的"水量-水质-水生栖息环境-连通性"四维指标体系,该指标体系可用于不同流域或区域多维水资源承载力评价。 相似文献
77.
A hybrid remotely operated underwater vehicle (HROV) capable of working to the full ocean depth has been developed. In order for the vehicle to achieve a certain survivability level, a self-repairing control system (SRCS) has been designed. It consists of two basic technologies, fault diagnosis and isolation (FDI) and reconfigurable control. For F'DI, a model-based hierarchical fault diagnosis system is designed for the HROV. Then, control strategies which reconfigure the control system at intervals according to information from the FDI system are presented. Combining the two technologies, it can obtain the fundamental frame of SRCS for the HROV. Considering the hazardous underwater environment at the limiting depth and the hybrid operating modes, an assessment of the HROV' s survivability is vitally needed before it enters operational service. This paper presents a new definition of survivability for underwater vehicles and develops a simple survivability model for the SRCS. As a result of survivability assessment for the SRCS, we are able to figure out the survivability of SRCS and make further optimization about it. The methodology developed herein is also applicable to other types of underwater vehicles. 相似文献
78.
河南焦作某矿地处焦作煤田东部,该矿东三盘区地质构造复杂,主采的2号煤层底板与L_8灰岩平均间距仅20m,与奥灰顶界面平均间距约100m,因此断层的存在极易导通奥灰水,形成较大的水患事故。故查明区内构造分布情况十分必要。本文重点介绍了用三维地震常规解释方法结合偏移及方差数据体水平切片解释方法在构造复杂区的应用情况,具有一定的推广意义。 相似文献
79.
80.