Scanning electron microscopy of bio‐fabricated Fe2O3 nanoparticles and their application to control brown rot of citrus

Citrus is the leading fruit crop of Pakistan and exported to different parts of the world. Due to suitable weather condition, this crop is affected by different biotic factors which seriously deteriorate its quality and quantity. During the months of November 2018 to January 2019, citrus brown rot symptoms were recurrently observed on sweet oranges in National Agricultural Research Centre (NARC), Islamabad. Causal agent of citrus brown rot was isolated, characterized, and identified as Fusarium oxysporum. For environment‐friendly control of this disease, leaf extract of Azadirachta indica was used for the green synthesis of iron oxide (Fe₂O₃) nanoparticles. These nanoparticles were characterized before their application for disease control. Fourier transform infrared spectroscopy (FTIR) of these synthesized nanoparticles described the presence of stabilizing and reducing compounds like alcohol, phenol, carboxylic acid, and alkaline and aromatic compounds. X‐Ray diffraction (XRD) analysis revealed the crystalline nature and size (24 nm) of these nanoparticles. Energy dispersive X‐Ray (EDX) analysis elaborated the presence of major elements in the samples. Scanning electron microscopy (SEM) confirmed the spinal shaped morphology of prepared nanoparticles. Successfully synthesized nanoparticles were evaluated for their antifungal potential. Different concentrations of Fe₂O₃ nanoparticles were used and maximum mycelial inhibition was observed at 1.0 mg/ml concentration. On the basis of these findings, it could be concluded that Fe₂O₃ nanoparticles, synthesized in the leaf extract of A. indica, can be successfully used for the control of brown rot of sweet oranges.     

Quality practices in design organizations

Design organizations play a major role in the construction industry: they are the media that transfer the requirements of the client to the contractor and ensure that they are met. Thus they need to provide a high quality of service to ensure that their client's project achieves the best possible standards of cost, time and quality. Seventy quality practices (QP) were identified as having a bearing on the quality of service provided by the local design organizations. These quality practices were grouped into fifteen sections termed quality sections (QS). The prevalence of these practices among the local design organizations was surveyed and determined. The results indicate a significant need for improvement in the quality sections ‘working relationship’, ‘employee training and education’, and ‘performance quality audit’. The study reveals the need for the establishment of a design code, and evaluation standards for local design organizations.     

Effect of tartrazine dye on micellisation of cationic surfactants: conductometric,spectrophotometric, and tensiometric studies

The interactions between anionic dye (tartrazine) and cationic surfactants (dodecyltrimethylammonium bromide and cetyltrimethylammonium bromide) have been studied by conductometric, spectrophotometric, and tensiometric techniques. The conductance and surface tension of dodecyltrimethylammonium bromide and cetyltrimethylammonium bromide in pure water as well as in aqueous tartrazine when plotted with surfactant concentration gave values of the critical micelle concentration at different temperatures. As well as increasing the length of the carbon chain of surfactants, the presence of tartrazine reduces the critical micelle concentration. From specific conductivity data, the counterion dissociation constant, standard free energy, enthalpy, entropy of micellisation, surface excess concentration, surface tension at critical micelle concentration, minimum area per molecule, surface pressure at critical micelle concentration, and Gibbs energy of adsorption were evaluated. Spectroscopic studies reveal that the binding of dye to micelles brings a bathochromic shift in dye absorption spectra that indicates dye–surfactant interaction.     

Evaluation of alumina reinforced oil fly ash composites prepared by spark plasma sintering

The thermomechanical behavior of micro/nano-alumina (Al₂O₃) ceramics reinforced with 1-5 wt.% of acid-treated oil fly ash (OFA) was investigated. Composites were sintered using spark plasma sintering (SPS) technique at a temperature of 1400°C by applying a constant uniaxial pressure of 50 MPa. It was evaluated that the fracture toughness of micro- and nanosized composites improved in contrast with the monolithic alumina. Highest fracture toughness value of 4.85 MPam^1/2 was measured for the nanosized composite reinforced with 5 wt.% OFA. The thermal conductivity of the composites (nano-/microsized) decreased with the increase in temperature. However, the addition of OFA (1-5 wt.%) in nanosized alumina enhanced the thermal conductivity at an evaluated temperature. Furthermore, a minimum thermal expansion value of 6.17 ppm*K⁻¹ was measured for nanosized Al₂O₃/5 wt.% OFA composite. Microstructural characterization of Al₂O₃-OFA composites was done by x-ray diffraction and Raman spectroscopy. Oil fly ash particles were seen to be well dispersed within the alumina matrix. Moreover, the comparative analysis of the nano-/microsized Al₂O₃/OFA composites shows that the mechanical and thermal properties were improved in nanosized alumina composites.     

Enhancement of Thermoelectric Performance in Hierarchical Mesoscopic Oxide Composites of Ca3Co4O9 and La0.8Sr0.2CoO3

The natural contradiction in enhancing electrical conductivity and thermopower in thermoelectric oxides makes it hard to improve the performance of a single thermoelectric oxide material. We report a facile method to construct a unique architecture of thermoelectric oxides that is promising to realize a simultaneous improvement of overall electrical conductivity and thermopower. Here, a series of two‐phase nanocomposites comprising of Ca₃Co₄O₉ (CCO) and La_0.8Sr_0.2CoO₃ (LSCO) has been synthesized through ball milling followed by spark plasma sintering (SPS) method. The electron microscope images reveal that the two constituents form the unique composites while retaining their individual crystalline and morphological identities. Owing to the hierarchical mesoscopic structure with nanoscale particles and submicrometer scale grain boundaries, an external strain is induced into the CCO grains by the LSCO nanoparticles to enhance the thermopower. The mesoscopic structure is also favorable for improving the electrical conductivity. Moreover, the long‐wavelength phonons can be scattered effectively from LSCO nanoparticles and the thermal conductivity is further suppressed. With compromises between power factor and thermal conductivity, the largest ZT achieved is up to 0.41 at 1000 K for the composites with 25 wt% of LSCO.     

A molybdenum dithiolene complex as a potential photosensitiser for photoelectrochemical cells

Molybdenum dithiolene complexes with the general formula [MoTp*(NO)(L)], where Tp* = tris(3,5-dimethylpyrazolyl)hydroborate and L = toluene-3,4-dithiolate (L1), 1,2-benzenedithiolate (L2), or 3,6-dichloro-1,2-benzenedithiolate (L3), were found to exhibit the chemical and physical properties required for a photosensitiser in a photoelectrochemical cell. These complexes were characterised using micro-elemental, spectroscopic (IR and UV–vis) and electrochemical analyses. Cyclic voltammetry (CV) was used to determine the oxidation/reduction potentials and to calculate the energy band gap. All of the complexes had an energy band gap in the range 1.45–1.48 eV, which extends far into the visible light region. A TiO₂ thin film to be used as a photoanode for photoelectrochemical cells was prepared using the paste technique on a Fluorine-doped Tin Oxide (FTO) plate and characterised using scanning electron microscope (SEM) and X-ray diffractometer (XRD). The [MoTp*(NO)(L)]-doped TiO₂ photoanodes were analysed photochemically in a 1.0 M NaOH electrolyte solution using SCE reference and platinum counterelectrodes. The [MoTp*(NO)(L3)]-doped TiO₂ photoanode exhibited an increased photoinduced current compared with the undoped TiO₂ photoanode. The Cl atoms on the dithiolene group offered a better interaction between the photosensitiser molecule and the TiO₂ photocatalyst by providing a means for halogen atom-induced chemical bonding. Based on the band edge calculations and the subsequent photocurrent results, these complexes may be potential photosensitisers for use in the preparation of photoelectrodes for photoelectrochemical cells.     

Dielectric Constant,Metallization Criterion and Optical Properties of CuO Doped TeO2–B2O3 Glasses

Journal of Inorganic and Organometallic Polymers and Materials - Copper oxide doped TeO2–B2O3 glass system with empirical formula;...