Look ahead job demanding for improving job shop performance

In this paper a new coordination approach for decentralized job shop scheduling rules is presented and analyzed in a simulation study. The coordination is based on look ahead information and contains a mechanism for demanding and supplying jobs. The simulation experiments show that the performance of conventional scheduling rules is significantly improved using the coordination mechanism.     

Salinity-Induced Density Stratification in Near-Laminar Open-Channel Flows

Salt tracer experiments are a cost-effective tool widely used in studies of flow and transport in free surface flows. Whereas in a large majority of rivers and streams, fully turbulent conditions achieve rapid vertical mixing of injected tracers, this is not necessarily the case with very low Reynolds number flows as encountered e.g., in wetland ponds. There, often laminar to near-laminar transitional flow regimes prevail, and the fact that solutions of elevated salinity are distinctly heavier than water may result in the development of stable density layers, trapping part of the salt tracer and distorting the breakthrough curve recorded at the outlet. In this study, the conditions under which density stratification develops due to salt injection are analyzed, and a criterion is presented which permits an intended salt tracer experiment to be judged at the planning stage already.     

Metabolic profiling of glucuronides in human urine by LC-MS/MS and partial least-squares discriminant analysis for classification and prediction of gender

Mass spectrometry (MS) is increasingly being used for metabolic profiling, but detection modes such as constant neutral loss or multiple reaction monitoring have not often been reported. These modes allow focusing on structurally related compounds, which could be advantageous for situations in which the trait under investigation is associated with a particular class of metabolites. In this study, we analyzed endogenous glucuronides excreted in human urine by monitoring characteristic transitions of putative steroid glucuronides by LC-MS/MS for discrimination of females from males. Two methods for data extraction were used: (i) a manual procedure based on visual inspection of the chromatograms and selection of 23 peaks and (ii) a software-supported method (MarkerView) set to extract 100 peaks. Data from 10 female and 10 male students were analyzed by principal component analysis (PCA) and partial least-squares discriminant analysis (PLS-DA) using software SIMCA. With PCA, only the manual peak selection resulted in clustering males and females. With PLS-DA, the manual method provided full separation on the basis of one single discriminant; the software-supported approach required a two-component model for complete separation. Loading plots were analyzed for their ability to reveal peaks with high discriminating power, that is, potential biomarkers. The PLS-DA models were validated with urine samples collected from five new females and five new males. Gender was correctly assigned for all. Our results indicate that inclusion of biological criteria for variable selection coupled to class-specific MS analysis and data extraction by appropriate software may constitute a valuable addition to the methods available for metabolomics.     

Morphosynthesis and morphology characterization of aniline and aniline/Laponite films

We report on morphosynthesis techniques that have been employed to tune polyamine film nanoarchitectures and on their resulting morphologies. Specific layers discussed include films of aniline/Laponite clay and aniline solution processed with V₂O₅ catalyst. Synthesis approaches examined include films generated in-situ (glass templating), solution based drop casting, and mechanochemical grinding. Surface topography results suggest that these approaches provide dimensionality control of the polyaniline morphology. Surface images of the mechanochemically ground polyaniline/Laponite nanocomposite layer reveal interfacial contact which is promising for potential heterojunction solar cell designs.     

Abstract processes of place/transition systems

A well-known problem in Petri net theory is to formalise an appropriate causality-based concept of process or run for place/transition systems. The so-called individual token interpretation, where tokens are distinguished according to their causal history, giving rise to the processes of Goltz and Reisig, is often considered too detailed. The problem of defining a fully satisfying more abstract concept of process for general place/transition systems has so-far not been solved. In this paper, we recall the proposal of defining an abstract notion of process, here called BD-process, in terms of equivalence classes of Goltz-Reisig processes, using an equivalence proposed by Best and Devillers. It yields a fully satisfying solution for at least all one-safe nets. However, for certain nets which intuitively have different conflicting behaviours, it yields only one maximal abstract process. Here we identify a class of place/transition systems, called structural conflict nets, where conflict and concurrency due to token multiplicity are clearly separated. We show that, in the case of structural conflict nets, the equivalence proposed by Best and Devillers yields a unique maximal abstract process only for conflict-free nets. Thereby BD-processes constitute a simple and fully satisfying solution in the class of structural conflict nets.     

Downhole Upgrading of Extra-heavy Crude Oil Using Hydrogen Donors and Methane Under Steam Injection Conditions

An extra-heavy crude oil underground upgrading process is described which involves the downhole addition of a hydrogen donor additive under steam injection conditions (280-315°C and residence times of at least 24-h). Laboratory experiments showed a 4° increase in the API gravity (from 9 to 12°) of the upgraded product, a two-fold reduction in the viscosity and, an approximately 8% decrease in the asphaltene content with respect to the original crude. Further increases on the temperature led to products with improved properties reaching 15°API at 315°C. It was found that the presence of the natural formation (catalysts) and methane (natural gas) is necessary to enhance the properties of the upgraded crude oil. From GC and GC-MS results a reaction pathway is proposed that involves hydrogen transfers from tetralin to the extra-heavy crude oil resulting in the formation of 1,2-dihydronaphthalene. This compound is then transformed into naphthalene, further upgrading of crude oil through hydrogen donation. The results of the experiments carried out in the presence and absence of the mineral formation and with an inert solid (SiC) strongly indicate that the former acts as a catalyst and not as a heat transfer matrix. Isotopic labeling studies (CD₄ and ¹³CH₄) give evidences that, most probably, methane is involved in the upgrading reactions.