外加剂混凝土动态与静态坍落度损失的流变特性

本文对动、静态下混凝土坍落度损失的规律进行了研究,并从流变学的角度分析了外加剂对动、静态下混凝土坍落度损失的影响坍落度损失存在差别的原因.     

特征X射线能谱法测定Fe^＋注入小麦种子的深度

用１１０ｋｅＶ Ｆｅ＾＋离子束垂直注入小麦种胚后，在扫描电子显微镜上沿种子纵沟剖面，在不同深度上测量Ｆｅ元素被激发出的特征Ｘ射线强度分布，结果表明分布呈指数衰减，与晶体中的热扩散分布相类似，并对此进行了讨论。     

Temperature dependence of hydrogenated amorphous silicon thin-film transistors

The temperature dependence characteristics of hydrogenated amorphous silicon thin-film transistors were investigated. The results indicate that as the temperature was increased, the threshold voltage and the field-effect mobility were first increased, and then decreased, which may be controlled by different mechanisms at low and high temperatures. In addition, if the temperature was higher than 420 K, the Fermi level was promoted to the degenerate-like states, the current channel always existed due to the temperature effect, and the threshold voltage became negative.     

Total transfer capability computation for multi-area power systems

This paper presents a method for multi-area power system total transfer capability (TTC) computation. This computation takes into account the limits on the line flows, bus voltage magnitude, generator reactive power, voltage stability, as well as the loss of line contingencies. The multi-area TTC problem is solved by using a network decomposition approach based on REI-type network equivalents. Each area uses REI equivalents of external areas to compute its TTC via the continuation power flow (CPF). The choice and updating procedure for the continuation parameter employed by the CPF is implemented in a distributed but coordinated manner. The proposed method leads to potential gains in the computational efficiency with limited data exchanges between areas. The developed procedure is successfully applied to the three-area IEEE 118-bus test system. Numerical comparisons between the integrated and the proposed multi-area solutions are presented for validation.     

Effect of polymerization conditions on o‐phenylenediamine and o‐phenetidine oxidative copolymers

A series of new o‐phenylenediamine (OPD)/o‐phenetidine (PHT) copolymers with partly phenazine‐like structures has been successfully synthesized at three polymerization temperatures by chemically oxidative polymerization in four different polymerization media. The molecular structures and properties of the resulting OPD/PHT polymers were investigated by IR, UV–vis and high‐resolution ¹H NMR spectroscopies, and DSC, in order to ascertain the effect of reaction temperature, comonomer ratio and acid medium. The copolymerization mechanism of OPD with PHT monomers has been proposed. It is found that the statistical OPD/PHT copolymer obtained at a temperature of 118 °C has a higher degree of polymerization than that obtained at 12–17 °C. The OPD content in the copolymers calculated from NMR spectroscopic analysis is higher than that in the feed OPD content, whereas the OPD content calculated from element analysis is slightly lower than the feed OPD content. It can be predicted that denitrogenation takes place in the OPD units during the polymerization process at OPD/PHT molar ratios of 90/10 and 100/0. These OPD/PHT copolymers exhibit a much better solubility than the OPD homopolymer, hence suggesting an incorporation of PHT units into the phenazine structure of the homopolymer. The thermal behavior of the copolymers was also studied. Copyright © 2004 Society of Chemical Industry     

Monoalkyl Esters of Isoalkylphosphonic Acid as Extractants in Rare Earth Separation

Four monoalkyl esters of isoalkylphosphonic acids have been studied for the chromatographic separation ofrare earths (RE).The relationship between distribution ratios and acid concentration of the eluants forsamarium and ytterbium has been explored.The characteristics of these extractants loaded onto macroreticularpoly (methyl methacrylate) resin beads for the separation of lanthanum,cerium,praseodymium and neodymiumhave been compared.Among the extractants studied,mono(1-methylheptyl) ester of isooctylphosphonic acidwas found to be the best for RE separation.The acidity for separation is lower than any known P-containingextractants for the same purpose.For instance,with 1.73 mol·L~(-1) nitric acid as eluent,thulium,ytterbium andlutetium can be separated quantitatively.The extractant-loaded resins possess high column efficiency with goodkinetic characteristics.The extraction mechanism was also explored.     

Application of artificial neural networks to the analysis of two‐dimensional fluorescence spectra in recombinant E coli fermentation processes

A two‐dimensional (2D) spectrofluorometer was used to monitor various fermentation processes with recombinant E coli for the production of 5‐aminolevulinic acid (ALA). The whole fluorescence spectral data obtained during a process were analyzed using artificial neural networks, ie self‐organizing map (SOM) and feedforward backpropagation neural network (BPNN). The SOM‐based classification of the whole spectral data has made it possible to qualitatively associate some process parameters with the normalized weights and variances, and to select some useful combinations of excitation and emission wavelengths. Based on the classified fluorescence spectra a supervised BPNN algorithm was used to predict some of the process parameters. It was also shown that the BPNN models could elucidate some sections of the process's performance, eg forecasting the process's performance. Copyright © 2005 Society of Chemical Industry     

Stability analysis of regional and national voting schemes by a continuous model

The previous discrete-model-based stability analysis of regional and national voting has been extended to a continuous-model-based analysis in the simultaneous presence of white and concentrated components of noise, reconfirming the previous conclusion that regional voting with smaller sized regions always demonstrates an improved stability over those with larger sized regions, including the national voting in its limiting case in particular. The conclusion remains valid as long as the weak distribution assumption is valid.