高强混凝土受火后力学性能变化规律的研究

对受火后的混凝土试件进行了抗压强度、抗折强度和劈裂抗拉强度试验,讨论了温度、强度等级、试件尺寸、含水量对其高温后力学性能的影响。研究表明,受火后,抗折强度较抗压强度下降更快;高强度的混凝土在600℃前抗压强度下降不多;大尺寸混凝土试件较小尺寸混凝土试件的残余抗压强度下降慢;混凝土试件的含水率越高,相对残余抗压强度越低。采用超声波速度法和质量损失法对火灾高温后混凝土内部结构的变化进行了探讨。     

Phase behavior and density of polysulfone in binary fluid mixtures of tetrahydrofuran and carbon dioxide under high pressure: Miscibility windows

Mixtures of tetrahydrofuran (THF) and carbon dioxide (CO₂) were identified as new solvent systems for polysulfone. The miscibility and density of polysulfone in binary fluid mixtures of THF and CO₂ were investigated from 300 to 425 K at pressures up to 70 MPa. The influence of the CO₂ and polysulfone concentrations was studied, with the concentrations of the other two components kept constant. At a 4.5 wt % polymer concentration, the demixing pressures in a 10 wt % CO₂ and 90 wt % THF mixture increased with temperature (310–425 K) from 15 to 40 MPa. With increasing CO₂ concentration (from ca. 10 to 14 wt %), a significant increase (from 15 to 70 MPa at 310 K) was observed in the demixing pressures. Furthermore, with an increasing amount of CO₂, the nature of the phase boundary shifted from lower critical solution temperature behavior to upper critical solution temperature behavior. The influence of the polymer concentration was studied in the 0–5 wt % range at two CO₂ levels, with solvent compositions of 10 wt % CO₂ and 90 wt % THF and 13 wt % CO₂ and 87 wt % THF. The system with a higher level of CO₂ (13 wt %) showed highly unusual phase behavior: on pressure–composition and temperature–composition diagrams, the system displayed two distinct regions of miscibility. In the system with 10 wt % CO₂, the distinct regions of miscibility that were observed in the system with 13 wt % CO₂ partially overlapped and led to a W‐shape phase boundary. The densities of the polymer solutions were measured from the one‐phase region through the demixing point into the two‐phase region at a constant temperature. No significant change in density was found around the phase boundary; this indicated that the coexisting phases had similar densities, as is often the case with liquid–liquid phase separation in polymer solutions under high pressure. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 2357–2362, 2002     

Ultrasonic oscillations effect on rheological and processing properties of metallocene‐catalyzed linear low density polyethylene

The effects of ultrasonic oscillations and die materials on die pressure, productivity of extrusion, melt viscosity of metallocene‐catalyzed linear low density polyethylene (mLLDPE), as well as their mechanism were studied in a special ultrasonic oscillations extrusion system developed in our lab. Die materials used in our experiment included steel, brass, and polytetrafluoroethylene (PTFE)_. The experimental results showed that ultrasonic oscillations as well as die materials have great influence on the rheological and processing behavior of mLLDPE. Ultrasonic oscillations can greatly increase the productivity of mLLDPE melt extruded through different dies, and can decrease the die pressure and the melt viscosity of mLLDPE. Compared with steel or brass die, mLLDPE melt extruded through PTFE die is more sensitive to ultrasonic oscillations. A possible mechanism for the improved processability of mLLDPE is proposed in this article. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1873–1878, 2003     

三羟甲基丙烷三丙烯酸酯的制备

介绍了一种制备三羟甲基丙烷三丙烯酸酯（ＴＭＰＴＡ）的方法──酰氯法。用本法可得纯度＞９９．９％、收率＞９８％的题示产物。原理简单，途径简捷，无需阻聚剂，大大简化了后处理工艺，成本降低。     

Nanocrystalline CeO2 in SBA-15: Performance of Pt/CeO2/SBA-15 Catalyst for Water-gas-shift Reaction

CeO₂ particles confined within the pores of an SBA-15 mesoporous silica host were prepared by incipient wetness impregnation (IMP) and deposition precipitation (DP) methods. The materials were characterized by XRD, N₂-adsorption and temperature programmed reduction (TPR) to evaluate the structure, texture, and redox properties. The preparation procedure had significant impact on the assembling mode of CeO₂ inside the SBA-15 mesopores. A high dispersion of CeO₂ particles was achieved via DP, whereas the dispersion of CeO₂ prepared by IMP was found to be inhomogeneous and CeO₂ partially blocked the pores. The CO conversion in the water-gas-shift reaction was enhanced over 1 wt% Pt supported on CeO₂-modified SBA-15 obtained by DP.     

High temperature swelling of coal/tetralin mixtures in a high pressure microdilatometer

High pressure microdilatometer experiments were performed on a subbituminous (Wyodak) and a bituminous (Illinois no. 6) coal in helium and hydrogen atmospheres with and without added tetralin. Wyodak coal samples showed no swelling but contractions ranging between 24 and 40 vol% upon heating at 20 and 100 °C min^{− 1} under helium or hydrogen pressures between 150 and 1000 psig (˜1.0–6.9 MPa). Under the same conditions, Illinois no. 6 coals displayed contractions (25–60 vol%) prior to swelling up to 117 vol%. Upon tetralin addition (at 35–190 wt% of the coal), Wyodak coal samples did not swell but showed an increasing contraction with increasing helium or hydrogen pressure due to a slight softening and fusion of the coal particles. In contrast, addition of tetralin at much lower concentrations (5–35 wt%) had a marked effect on the contraction and swelling behaviour of Illinois no. 6. A maximum swelling of 200 vol% was obtained at a tetralin addition of 30 wt%. The increased swelling results from more extensive softening and fusion of coal particles in the presence of tetralin. Both coals showed a decreasing char yield with increasing tetralin concentration. The substantially lower extent of interaction observed between Wyodak coal samples and tetralin compared to Illinois no. 6 coal can be attributed to the differences in pore structure and/or chemical constitution of the two coal samples. Examination of the resultant solids by optical microscopy revealed the microstructural changes produced by thermal treatment in dilatometer experiments.     

一种基于ZigBee的分布式井盖监控系统

随着我国现代经济发展水平的不断提高,城市井盖数目逐渐增加。由于较多井盖被盗,致使路面形成陷阱,危害到过往车辆和行人安全。本文提出了一种基于ZigBee无线网络的智能安全监控系统,解决分布式布控困难、不能实时监控、成本较高的问题。融合GPRS网络,设计相应的嵌入式网关和Web服务器,实现了对缺失井盖的精确定位、自动报警功能。     

计算机网络系统可靠性分析及在矿山的应用

随当前我国计算机网络技术的不断快速发展,以及全球信息化的发展趋势日渐成型,人们对于信息的需求也愈发地渴望.正是基于此时代背景,以信息作为传输载体的计算机网络系统也应势而起,并且其可靠性、安全性也更加受到让人们的关注.本文中研究了计算机网络系统可靠性,比较了存在的优劣问题,并探讨其应用于矿山计算机系统的可行性.     

有机-无机复混肥料的肥料效应初探

选取鸡粪为有机原料 ,进行发酵与不发酵两种前处理 ,设计 0、30 %、4 0 %、6 0 %和 10 0 % 5种有机氮水平 ,在水稻上连续两年试验。结果表明 ,在 4 0 %水平以下 ,作物产量随有机氮的增加而增加 ,超过 6 0 %产量下降 ,但有后效。氮素表观利用率与有机氮成正相关 ,当有机氮达到 10 0 %时 ,氮素利用率达到 5 3.4 %。随有机氮的增加 ,作物吸收养分向子粒中转移的比例也相应增加     

高职院校软件教学体系研究

本文在概述软件教学体系及其理论的基础上,结合软件教学的特点,阐述了软件教学体系的结构、应用环境以及在教学中将遇到的问题和解决对策,并描述了＂软件教学资源网系统＂建立的目的、设计方案、功能及开发环境。