In Situ Topochemical Transformation of ZnIn2S4 for Efficient Photocatalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran

Photocatalytic selective oxidation of 5-hydroxymethylfurfural (HMF) coupled H₂ production offers a promising approach to producing valuable chemicals. Herein, an efficient in situ topological transformation tactic is developed for producing porous O-doped ZnIn₂S₄ nanosheets for HMF oxidation cooperative with H₂ evolution. Aberration-corrected high-angle annular dark-field scanning TEM images show that the hierarchical porous O-ZIS-120 possesses abundant atomic scale edge steps and lattice defects, which is beneficial for electron accumulation and molecule adsorption. The optimal catalyst (O-ZIS-120) exhibits remarkable performance with 2,5-diformylfuran (DFF) yields of 1624 µmol h⁻¹ g⁻¹ and the selectivity of >97%, simultaneously with the H₂ evolution rate of 1522 µmol h⁻¹ g⁻¹. Mechanistic investigations through theoretical calculations show that O in the O-ZIS-120 lattice can reduce the oxidation energy barrier of hydroxyl groups of HMF. In situ attenuated total reflection surface-enhanced infrared absorption spectroscopy (ATR-SEIRAS) results reveal that DFF^* (C₄H₂(CHO)₂O^*) intermediate has a weak interaction with O-ZIS-120 and desorb as the final product. This study elucidates the topotactic structural transitions of 2D materials simultaneously with electronic structure modulation for efficient photocatalytic DFF production.     

Finite-Sized Atom Reconstruction Enhanced High-Frequency Multi-Domain Magnetic Response

The technological advances in wearable electronics and military stealth have spawned extensive research into electromagnetic wave absorbents. Despite the rapid progress in the geometrical modulation of magnetic absorbents, the engineering strategy of microwave-responsive magnetic domains is underdeveloped and the response dynamics remain unclear. Herein, a surface finite-sized atom reconstruction procedure is proposed to accurately modulate the local magnetic topological domains, dramatically enhancing the magnetic loss capacity. Due to the selectivity of atom reconstruction, vortex and stripe domains are controllably hybridized around the porous surface to broaden the interactive domain region, significantly intensifying energy absorption of the microwave field. Meanwhile, the amorphous/crystalline interfaces around atom reconstruction regions can induce interfacial polarization, enabling the optimization of dielectric loss capacity. Therefore, a satisfactory magnetic–dielectric synergy is realized to demonstrate the strong absorption intensity of −31.2 dB and the broad absorption bandwidth of 5.9 GHz. Furthermore, the surface-based magnetic domain transformation and microwave energy attenuation mechanisms are thoroughly revealed to break the black box of structure–function through electron holography and micromagnetic simulation. These achievements demonstrate a promising solution to improve high-frequency magnetic properties and provide a feasible route to interpret the structure-relevant magnetic loss capacity.     

无线通信信道技术的研究

无线信道中最为复杂的是电波的传播特性,这些传播特性主要有中波、长波地表面波传播、电离层反射传播、还有各种散射波的传播等等。无线信道的干扰形式颇为繁多、它的特征十分复杂,本文主要针对无线通信信道技术的特点、分类、基本特征和发展现状,做出相应的研究。     

Implementation of a High Throughput 3GPP Turbo Decoder on GPU

Turbo code is a computationally intensive channel code that is widely used in current and upcoming wireless standards. General-purpose graphics processor unit (GPGPU) is a programmable commodity processor that achieves high performance computation power by using many simple cores. In this paper, we present a 3GPP LTE compliant Turbo decoder accelerator that takes advantage of the processing power of GPU to offer fast Turbo decoding throughput. Several techniques are used to improve the performance of the decoder. To fully utilize the computational resources on GPU, our decoder can decode multiple codewords simultaneously, divide the workload for a single codeword across multiple cores, and pack multiple codewords to fit the single instruction multiple data (SIMD) instruction width. In addition, we use shared memory judiciously to enable hundreds of concurrent multiple threads while keeping frequently used data local to keep memory access fast. To improve efficiency of the decoder in the high SNR regime, we also present a low complexity early termination scheme based on average extrinsic LLR statistics. Finally, we examine how different workload partitioning choices affect the error correction performance and the decoder throughput.     

InAs Wires on InP (001)

在分子束外延生长的InAs/In0.52Al0.48As/InP异质结体系中,形成InAs量子线.这些InAs量子线在生长和结构方面有一些独到的特性,并介绍了本实验室在研究InAs量子线的生长和结构方面所做的工作.     

光脉动法颗粒粒径测量中的消光系数曲线拟合研究

消光系统在光脉动法颗粒粒径测量技术中是一个十分重要的物理量,但现有的消光系数处理方法有许多不完善的地方。本文用分段最小二乘法拟合消光系数曲线,给出相应的分段表达式。该方法简化了消光系统的计算过程,能够满足工程测量的精度要求,有助于光脉动法在线测量的实现。     

采用模块化固态调制器对单级振荡式雷达整机性能改善的分析

介绍了一种通用型雷达发射机模块化固态调制器,分析了单级振荡式雷达采用模块化固态调制器后整机性能的改善,并给出了试验数据及结果.     

一种基于三阶统计量的基音周期检测新方法

本文利用小波变换和三阶统计量的基本特性,提出了一种小波变换与三阶统计量结合的基音周期检测新方法;在低信噪比的基音周期检测中,本方法可以获得比其它基音周期检测法更精确的结果文中还分析了压扩因子和门限因子K的选择,实验表明,K在一定范围内取值时对基音周期检测结果影响不大.     

大时带积非线性调频脉压信号及其性能分析

采用多种频域窗函数综合出了一组大时带积非线性调频脉冲压缩信号,其中一些窗函数的应用尚未见类似的研究报道.本文模拟分析了这类信号的分辨力和多普勒响应性能,并与实验结果进行分析比较,总结了设计大时带积非线性调频脉压信号窗函数的选择原则.该组信号应用于远程警戒雷达可收到增加检测目标动态范围而不降低作用距离的实效.     

Design of coating for broadband polarization- independent beam splitters and analysis of its optical performance

Thebeamsplitters(BS)havedemonstratedwideap plicationinmanyopticalsystemsandplayakeyrolein interferometryandholography[1].ThemechanismofBScanbedividedintotwocategories:oneutilizesthereflec tionandrefractionontheinterfacebetweentwodielec tricmedia;theotheru…