Energy conversion at liquid/liquid interfaces: artificial photosynthetic systems

This chapter focuses on multielectron reactions in organized assemblies of molecules at the liquid/liquid interface. We describe the thermodynamic and kinetic parameters of such reactions, including the structure of the reaction centers, charge movement along the electron transfer pathways, and the role of electric double layers in artificial photosynthesis. Some examples of artificial photosynthesis at the oil/water interface are considered, including water photooxidation to the molecular oxygen, oxygen photoreduction, photosynthesis of amphiphilic compounds and proton evolution by photochemical processes.     

Wide-angle X-ray scattering studies on polyethylene at low temperatures

Summary Linear polyethylene (Lupolen 6041 D) and a polyethylene fraction (PE 2000) were investigated by WAXS at temperatures 8 K相似文献   

Determination of absolute emission cross sections for electron-impact-induced line radiation in the vacuum ultraviolet

A method and an experimental setup have been developed for measuring absolute photoemission cross sections for electron-impact-induced line radiation in the vacuum ultraviolet (VUV). Unparalleled low uncertainties for the cross sections were achieved mainly from the use of the Berlin electron storage ring as a primary standard source in the VUV for the determination of the responsivity of the spectrometer-detector system used and from the use of a spinning rotor gauge as a secondary standard for the determination of the target gas density. As the first result we present a photoemission cross section for the Ar II 3s3p(6)(2)S(?)-3s(2)3p(5)(2)p?(3/2) transition at 91.98 nm for 2-keV electron-impact energy of 1.167 × 10(-18) cm(2) with a relative uncertainty of 4.4% (√3σ value). This low uncertainty demonstrates the suitability of the setup for further cross-section measurements.     

Two-dimensional Kerr-Fourier imaging of translucent phantoms in thick turbid media

Translucent scattering phantoms hidden inside a 5.5-cm-thick Intralipid solution were imaged as a function of phantom scattering coefficients by the use of a picosecond time- and space-gated Kerr-Fourier imaging system. A 2-mm-thick translucent phantom with a 0.1% concentration (scattering coefficient) difference from the 55-mm-thick surrounding scattering host can be distinguished at a signal level of ~10(-10) of the incidence illumination intensity.