Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).     

油气田在用燃气轮机系统的热力学分析及改进建议

目前油气田在用的燃气轮机系统实际运行指标（热效率及火用效率）与设计数值相差很大，使燃气轮机系统的性能未能得到充分发挥，达不到预期的经济效益，限制了燃气轮机在油气田的进一步推广。为此，对油气田在用燃气轮机的运行特性进行分析，其主要问题是余热锅炉运行时间短、负荷率低。根据燃气轮机热电联产系统特点，给出了热力学分析（能量平衡分析和火用分析）方法、评价准则及计算公式。利用实测运行参数，对一油气田在用燃气轮机系统进行了运行工况下的热力学分析。测算分析结果表明，该系统运行效率偏离设计值较远，运行效率较低。在各子系统的能量损失分布中，余热锅炉能损系数最大；火用损分布中，燃烧室火用损系数最大，其次为余热锅炉，表明燃气轮机的燃烧室和余热锅炉为系统能量利用的薄弱环节，为重点改造对象。建议扩大集中供热范围、采用余热发电和循环蒸气回注等提高运行效率的措施。     

多测井曲线的综合处理合成

测井曲线是地质分层的基础，但在利用单一测井曲线解决复杂地质问题时也存在多解性和局限性。为克服多解性，人们采用多种测井曲线进行地质分层，提高了分层的精度。本文在此基础上提出把多条曲线分别赋予不同的加权因子，然后进行归一化处理，形成一条标准综合参数测井曲线。此综合参数曲线突出了所选的多条测井曲线的公共信息，减少或削弱了单一测井曲线中的偶然误差，提高了综合后测井资料的可信度。该方法可应用于地质分层、岩性分析、含油气预测等诸多领域。应用时要注意，并非所选择的测井曲线种类越多越好，而是要选择那些最能反映地层单元特征信息的测井曲线。     

重油催化裂化装置的环保对策

对重油催化裂化过程中的环境影响因素、硫分布状况及硫平衡等进行了分析，指出了重油催化裂化过程中的环境污染问题；从对装置污染源的分析出发，提出了相关的治理措施。     

Preparation of CeO2-ZrO2 mixed oxide with high surface area and high thermal stability

Ceria-zirconia solid particles have been recognized as a key material of the automotive exhaust catalysts since they can release and uptake oxygen owing to the rapid reversible oxidation states of cerium between Ce³⁺ and Ce⁴⁺. Several methods have recently been described to prepare the CeO₂-ZrO₂ solid particles used in the catalysts. In this paper, a new coprecipitation method is used to prepare the CeO₂-ZrO₂ solid particles. The Ce-Zr alcogel is dried and calcined in flowing N₂ not in flowing air under atmospheric pressure. The results show that the ceria-zirconia sample calcined at 650 °C has high surface area over 90 m²g⁻¹, which drops to 40 m²g⁻¹ following treatment at 900°C.     

分置式牛津型斯特林制冷机的数值分析与实验验证

对分置式牛津型斯特林制冷机进行了数值计算 ,介绍了计算模型考虑到的众多不可逆因素。通过对计算结果与实验结果的对比 ,验证了本文数值计算的准确性 ,说明本文计算模型与数值处理方法是切实可行的     

光纤荧光传感器衰减寿命的加权对数拟合法

荧光寿命的检测是荧光光学传感器的核心内容，国际上尝试了多种方法来拟合这种理论上为单指数衰减信号的荧光衰减曲线。这些方法包括非线性函数标准拟合方法。即Levenburg-Marquardt方法，以及Prony方法、FFT方法，对数拟合法等等。为了克服在实际应用中发生的信号退化，需要在测量信号衰减寿命的同时测量信号的初始强度。文章介绍了一种加权的对数拟合法，经计算机仿真及实际数据测试均可以得到和Levenburg-Marquardt方法非常接近的结果，且拟合时间大大缩短，测量稳定性大大提高。仿真测试及具体实验测试结果显示了这种方法的有效性。该方法不仅与Levenburg-Marquardt方法的偏差曲线非常相似，而且实验测得的荧光寿命与Levenburg-Marquardt方法偏差在0．2％以内。     

就地补偿在动力厂水泵电机上的应用实例

就我公司动力厂给水车间155kW水泵电机无功就地补偿的可行性及经济效益进行了分析和研究，对工厂用电如何节能降耗有一定的参考价值。     

环境友好水基润滑添加剂的研究

在脂肪酸分子中引入硼和氮，合成了一种环境友好水基润滑添加剂BNR，并利用红外光谱对其主要官能团进行了表征。通过四球试验机考察了BNR添加剂在水中的抗磨性能与极压性能，用X射线光电子能谱仪对磨痕表面元素进行了分析，探讨了该类添加剂的极压抗磨作用机理。结果表明：硼氮化水基润滑添加剂BNR在水中具有优良的抗磨和减摩性能；其润滑作用机理是由于长链脂肪酸分子的载体作用、硼的缺电子性、氮的高反应活性以及三者的协同作用与摩擦金属表面形成了一层高强度的吸附膜和／或摩擦化学反应膜。     

Position synchronization of multiple motion axes with adaptive coupling control

A new control approach to position synchronization of multiple motion axes is developed, by incorporating cross-coupling technology into adaptive control architecture. The control strategy is to stabilize position tracking of each axis while synchronizing its motion with other axes’ motions so that differential position errors amongst axes converge to zero. The proposed adaptive controller and parameter estimator employ coupling control by feeding back position errors and differential position errors, and have been realized to guarantee asymptotic convergence to zero of both position and synchronization errors. Simulations conducted on a multi-axis motion control system demonstrate the effectiveness of the method.