Structure evolution of conductive polymer composites revealed by solvent vapor induced time-dependent percolation

The authors of this paper synthesized a series of amphiphilic triblock copolymers of polystyrene-b-poly(ethylene glycol)-b-polystyrene (PS-PEG-PS) having different PEG/PS ratios with nearly identical molecular weights of the entire copolymers. The interfacial interactions in the composites consisting of carbon black and the copolymers can thus be tailored. When these conducting composites are exposed to certain solvent vapors, their electrical resistances greatly increase, showing the gas sensitivity. The present work indicated that this switching behavior is controlled by the structural relaxation of the composites because matrix swelling acts as the main mechanism. The response time has been correlated with absolute temperature by Arrhenius equation, and the estimated activation energy reflects mobility of the fillers involved in the solvent induced expansion of the surrounding polymer. Therefore, by using the gas sensibility of the conductive composites, the structure evolution of the composite materials in solid state and the effect of filler/matrix interfacial interaction on the relaxation property of the matrix polymer has been inspected. It was found that lower activation energy represents stronger interfacial interaction in case good solvent of the matrix was used for the test.     

High-k材料MOS器件的PISCES-II模拟

High-k材料是指介电常数k高于SiO2的材料。使用high-k材料做栅绝缘层,是减小MOS器件栅绝缘层直接隧道击穿(DirectTunneling,DT)电流的有效方法。文章在二维器件模拟软件PISCES-II中添加了模拟以high-k材料为栅绝缘层的MOS器件模型,并对SiO2和high-k材料的MOS晶体管器件特性进行了模拟比较,成功地验证了所加high-k材料MOS器件模型的正确性。改进后的PISCES-II程序,可以方便地对以各种high-k材料为栅绝缘层的器件性能进行模拟。     

Photocatalytic degradation of 2,2‐bis(4‐hydroxy‐3‐methylphenyl) propane (BPP) based on molecular recognition interaction

BACKGROUND: Endocrine disruptors in the aquatic environment and their potential adverse effects are currently issues of concern. One of these endocrine disruptors is 2,2‐bis(4‐hydroxy‐3‐methylphenyl)propane (BPP). In this work the molecular recognition interaction of BPP with β‐cyclodextrin (β‐CD) was studied using IR spectroscopy and steady state fluorescence spectroscopy, and the photocatalytic degradation behaviour of BPP based on molecular recognition interaction was investigated in a TiO₂/UV–visible (λ_max = 365 nm) system. This might provide a new method for the treatment of some organic pollutants in wastewater. RESULTS: β‐CD reacts with BPP to form a 1:1 inclusion complex, the formation constant of which is 4.94 × 10³ L mol^?1. The photodegradation rate constant of BPP after molecular recognition by β‐CD showed a 1.42‐fold increase in the TiO₂/UV–visible (λ_max = 365 nm) system. The photodegradation of BPP depended on the concentration of β‐CD, the pH value, the gaseous medium and the initial concentration of BPP. The photodegradation efficiency of BPP with molecular recognition was higher than that without molecular recognition. After 100 min of irradiation the mineralisation efficiency of BPP after molecular recognition by β‐CD reached 94.8%, whereas the mineralisation efficiency of BPP before molecular recognition by β‐CD was only 40.6%. CONCLUSION: The photocatalytic degradation of BPP after molecular recognition by β‐CD can be enhanced in the TiO₂/UV‐visible (λ_max = 365 nm) system. This enhancement is dependent on the enhancement of the adsorption of BPP, the moderate inclusion depth of BPP in the β‐CD cavity and the increase in the frontier electron density of BPP after molecular recognition. Copyright © 2008 Society of Chemical Industry     

绿色理念的内涵拓展与绿色图书馆建设

绿色图书馆是图书馆学的一个新的研究方向和发展趋势.文章首先深刻挖掘绿色内涵的本质,阐述正确理解绿色图书馆的含义,接着探讨了绿色图书馆建设的要素取向,从而明确了现阶段发展绿色图书馆的必要性.     

Km高温抗蚀耐磨涂料在省煤器中的应用

锅炉省煤器磨损一直是困绕锅炉稳定运行的主要因素之一。本介绍了Km高温抗蚀耐磨涂料的性能、特点，以及在实际生产中的使用情况，通过实践充分肯定了Km高温抗蚀耐磨涂料的可行性、可靠性和经济性。     

小容量机组保护监控一体化

以数字信号处理器(DSP)和复杂可编程逻辑器件(CPLD)为硬件平台,研制了新一代面向中、小型水电站的综合自动化模块.充分发挥MB40智能可编程逻辑控制器(iPLC)及MB100系列保护测控系统的技术优势,将小型水电站的保护装置做成模块插件,融入监控系统,降低了小型水电站自动化设备的成本,为推出真正意义上的面向小型水电站的"五合一"产品打下坚实的基础.     

对油田企业建设和执行内部控制体系的思考

内部控制是一个由企业董事会、管理层和其他员工实施的,为实现企业经营的效果和效率目标、财务报告的可靠性目标和舍规性目标提供合理保证的过程。有效地建设以及有力地执行内控制度,对石油企业发展过程中有效地避免风险的发生起着非常重要的作用。但是,由于种种原因,油田企业目前的内部控制体系还不成熟,还存在着一些建设上的不足和执行上的不力。同时,企业员工普遍对内部控制还存在着一些认识误区,这就要求我们必须努力学习内控知识,加强内控知识培训,充分调动企业全体员工建设和雏护内部控制体系的积极性和自觉性,使得内控可以真正发挥其防范风险的作用。     

用热分析法研究硝化棉的熔化过程

用ＭＤＳＣ，显微镜温台熔点测定仪和固体原位反应池／快速扫描傅立叶变换红外光谱联用装置考察了硝化棉的熔化过程。ＭＤＳＣ曲线表明吸热过程是可逆的，它系由ＮＣ和部分分解凝聚相产物的混合物的固液相变所引起。由ＮＣ的ＭＤＳＣ曲线得到的熔点，熔化含，熔化熵，分解含和分解反应热温熵分别为４７６．８４Ｋ，２０５．６Ｊ．ｇ＾－１，０．４３１２Ｊ．ｇ＾－１．Ｋ＾－１，－２４７５．０Ｊ．ｇ＾－１，－５．２４２Ｊ．ｇ＾－     

利用计算机进行油气资源评价和勘探决策

本文着重介绍了构成《现代勘探决策理论系统》的5个主要计算机模块,即:生油岩热演化处理、求任意曲边形面积、数学模拟预测资源量、勘探经济评价分析及决策、辅助处理等模块。该系统曾在塔里木盆地和准噶尔盆地的油气资源评价和勘探决策中发挥了作用,受到了专家和用户的好评。     

高层结构几何非线性分析的QR法

本文利用ＱＲ法分析高层建筑结构几何非线性问题，建立了新的计算格式。该法不仅未知量的数目少，精度高，而且输入简单，计算速度快，可以用微机分析复杂问题。