Electrochemical properties of some cobalt antimonides as anode materi-als for lithium- ion batteries

Some cobalt antimonides have been prepared and studied as the candidate anode materials for lithium ion batter-ies. Reversible capacities of 424,423 and 546 mA·h·g-1 were measured at the first cycle for as-solidified CoSb2, CoSb3 and annealed CoSb3 respectively. A low lithium ions diffusion coefficient in the order of 10-16 m2·s-1 was estimated from the coulometric titration measurements in the annealed CoSb3 electrode. It was found that the electrochemical properties of fine powders are significantly better than coarse powders. However the SEM picture shows that the nano-sized CoSb3 powders gathered to larger granules, which worsens somewhat the capacity retention of the nano-sized materials, although the volume capacities of the annealed and ball milled CoSb3 remain near twice of that of graphite after 50 cycles.     

Preparation and characterization of TiO2 photoelectrode codoped with aluminum and boron and its application in dye-sensitized solar cell

Nanocrystalline titania films codoped with aluminum and boron were prepared by cathodic vacuum arc deposition. In the process, titanium alloy target was used under an O2/Ar atmosphere, and sensitization of films were carried out by natural dye-sensitized complex in anhydrous ethanol. The structure, surface morphology and UV-vis spectra of titania films codoped were measured by X-ray diffraction analysis, scanning electron microscopy and ultraviolet-visible spectrometer. Theas-deposited films are found to be amorphous. The films annealed were examinedto be of anatase structure with orientation along the (101) planes, the averagecrystal size is in the range between 41 and 45 nm. SEM results show that thereare some pores in the codoped titania films, the optical properties of the dye-sensitized films were also measured which reveals that the spectral responses of films shift to the visible region. Under simulated sunlight illumination, the overall energy conversion efficiency of dye-sensitized nanocrystalline solar cell is 0.9%.     

双端制动器惯性试验台的设计

随着我国汽车工业的迅猛发展,汽车产量不断增多,车速越来越高,对汽车制动性能要求也越来越高。汽车制动器是汽车上的重要设备,其质量的好坏影响着行车的安全。电惯量模拟是近几年兴起的一种比较先进的负载模拟方法,文章就制动器惯性试验台系统结构以及电惯量模拟的方法进行了比较详细的说明。     

CA6140车床数控改造中机械装置设计技巧

介绍了普通车床数控改造中机械装置的几个独特设计，使得数控车床纵向进给系统结构更简单、性能更可靠、装拆更方便。     

钻柄温挤成形及模具设计

介绍了钻柄温挤成形工艺及其模具设计。     

水电站大坝安全等级评定中边坡因素的影响剖析

基于我国水电站大坝安全定期检查的长期实践经验,分析了运行水电站边坡失稳对大坝运行安全的主要影响后果,归纳了边坡稳定状况评价的主要工作和原则,提出了边坡安全级别确定的原则。     

分布式光纤测温技术在冻结修复工程中的应用

针对采用冻结法进行成井井壁修复工程的特殊性,在进行常规水文孔、测温孔监测的同时,增加新型检测手段,利用分布式光纤测温技术检测每个冻结器的纵向温度,通过数据分析,为指导冻结施工安全顺利进行提供依据。详细介绍了修复工程的概况和分布式光纤测温系统的原理、组成、检测方法及测温光缆结构。给出了现场实测数据,与常规测温孔数据相比,数据量大,能全面、直观地反映冻结壁实际发展状况。系统结构简单,机动灵活,检测方法具有一定的推广价值。     

不一致决策表规则获取的粒计算方法

针对不一致决策表的规则获取,从属性多粒度角度考虑,按粒度由粗到细将决策表划分成不同的粒度空间,通过定义相容粒关系矩阵和不相容粒关系矩阵,并充分挖掘隐含在矩阵中的启发式信息,实现对不同粒度空间确定性规则和不确定性规则的获取.最后,从实例分析以及UCI测试对算法进行验证,并与现有算法进行实验对比,实验结果与分析表明了所提出算法的可行性和有效性,而且按此方法获取的规则集的泛化能力更强.     

两个公钥加密方案的安全性分析

广播加密和基于属性加密是两种重要的公钥加密方案,可将加密内容同时传送给多个用户,在付费电视、数字版权管理和资源访问控制等领域有重要应用。对一个基于身份广播加密方案进行了分析,表明攻击者只要得到某个用户的私钥,就可以计算其他任何用户的私钥。研究了一个基于属性加密方案,该方案并不能真正地隐藏访问结构,攻击者仅由密文就能得到对应的访问结构。