Microstructure,Thermal Conductivity,and Electrical Properties of In Situ Pressureless Densified SiC–BN Composites

The microstructure, thermal conductivity, and electrical properties of pressureless densified SiC–BN composites prepared from in situ reaction of Si₃N₄, B₄C, and C were systematically investigated, to achieve outstanding performance as substrate materials in electronic devices. The increasing BN content (0.25–8 wt%) in the composites resulted in finer microstructure, higher electrical resistivity, and lower dielectric constant and loss, at the expense of only slight degradation of thermal conductivity. The subsequently annealed composites showed more homogeneous microstructures with less crystal defects, further enhanced thermal conductivities and electrical resistivities, and reduced dielectric constants and losses, compared with the unannealed ones. The enhanced insulating performance, the weakened interface polarization, and the reduced current conduction loss were explained by the gradual equalization of dissolved B and N contents in SiC crystals and the consequent impurity compensation effect. The schottky contact between graphite and p‐type SiC grains presumably played a critical role in the formation of grain‐boundary barriers. The annealed composites doped with 8 wt% BN exhibited considerably high electrical resistivity (4.11 × 10¹¹ Ω·cm) at 100 V/cm, low dielectric constant (16.50), and dielectric loss (0.127) at 1 MHz, good thermal conductivity [66.06 W·(m·K)^?1] and relatively high strength (343 MPa) at room temperature.     

Evaluation of high temperature polymers in nanolayered films and gradient refractive index (GRIN) lenses

A new polymer nanolayer gradient refractive index (GRIN) system with more robust thermal stability because of incorporation of a high glass transition temperature polyester, OKP4HT, was demonstrated. A combination of extruded nanolayered GRIN film systems, comprised of five unique polymer materials, were combined to produce laminate optics comprised of a large internal refractive index gradient distribution, n = 1.445 – 1.630, without degradation of optical transmissive properties. The optical performance of a series of varied magnitude GRIN lenses, ranging from Δn = 0 to 0.185, was evaluated. Increasing the lens refractive index range resulted in decreased optic sphericalaberrations that followed analytical predictions. An analytical approach was reported to correlate the polymer material upper service temperature (UST) to the onset of polymer material loss modulus as measured by DMTA. Thermo‐optical interferometry measurements of irreversible lens deformation confirmed the lenses UST at 125°C for the OKP4HT/PC system as compared to 75°C for a PMM/SAN17 system. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42741.     

Far‐Red‐Emitting BiOCl:Eu3+ Phosphor with Excellent Broadband NUV‐Excitation for White‐Light‐Emitting Diodes

Rare‐earth ion‐doped semiconducting phosphor has attracted extensive attention due to the ability to achieve efficient luminescence through the host sensitization. Here, we present a new type red‐emitting Eu³⁺ ‐doped BiOCl phosphors possessing a broad excitation band in the near‐ultraviolet (NUV) region. Experimental measurements and theoretical calculations confirm that Eu³⁺ ion dopants result in forming impurity energy level near valence band, and the excellent broadband NUV‐exciting ability of Eu³⁺ ion is due to the electronic transitions of BiOCl band gap. Moreover, the highest emission intensity of the phosphors is from the ⁵D₀ → ⁷F₄ transition of Eu³⁺ around 699 nm (far‐red) through whether host excitation or direct Eu³⁺ ions excitation, which lie in the particular structure of BiOCl crystals. Our results indicate that the Eu³⁺ ‐doped BiOCl crystals show great potential as red phosphors for white‐light‐emitting diodes.     

单因子老化中定子线棒等温松弛电流的研究

为研究电机定子线棒老化后的绝缘特性,制备了按实际线棒尺寸比例缩小的线棒试样,并对其进行了单独的热、电老化实验,后测量了不同老化程度线棒试样的等温松弛电流,并基于等温松弛理论研究分析了线棒绝缘内的陷阱分布变化。结果表明:线棒绝缘在冷热循环老化过程中存在"后固化"的现象,绝缘内陷阱密度先增加后减小;而在电老化过程中,试样绝缘内浅能级陷阱密度增加。根据不同极化过程对等温松弛电流的贡献,建立了定子线棒等温松弛电流的三阶指数衰减模型。研究表明,电机线棒老化的主要表现是环氧树脂和云母之间界面中缺陷的增加,而三指数衰减模型对等温松弛电流数据的拟合结果也足够准确。     

一种新型的同塔双回输电线路工频阻抗参数测量方法

基于输电线路三相不平衡及感应电压干扰在短时间不变的前提,提出了一种新型的同塔双回输电线路工频阻抗参数测量方法。该方法采用单相电源多变换接入的方式对不对称线路进行分相解耦测量,通过建立数学模型、数据拟合和矩阵变换,从而获得单回或两回线路的序阻抗及各序之间的耦合阻抗。该方法克服了高感应电压及三相不平衡对线路参数测试的影响,具有简单、精确、稳定等特点,测试结果表明了本文方法的有效性。     

基于自适应控制电路实现的宽带高性能频率源

基于自适应控制技术,在宽带捷变频频率合成器的设计方案中同时引入自动调节滤波电路和带温度预校准功能的自动电平控制电路,有效降低了输出信号杂散,提高了输出信号的功率平坦度, 相比传统的利用分段滤波方式实现的宽带频率源,减小了模块体积。文中不仅详细介绍了这2个电路的实现过程,还从易于工程实现的角度出发,着重介绍了一些能有效降低调试工作量的方法。设计所得的频率合成器输出频率1 000 MHz~1 900 MHz,步进2 MHz,在–45 ℃~ +85 ℃的温度范围内,实现了杂散抑制优于–70 dBc,输出功率10 dBm±0.3 dBm的技术指标。