Polarity Effect in a Sn3Ag0.5Cu/Bismuth Telluride Thermoelectric System

This study investigates electromigration in Bi₂Te₃ thermoelectric (TE) material systems and the effectiveness of the diffusion barrier under current. The Peltier effect on the interfacial reaction was decoupled from the effect of electromigration. After connecting p- and n-type Bi₂Te₃ to Sn3Ag0.5Cu (SAC305) solders, different current densities were applied at varying temperatures. The Bi₂Te₃ samples were fabricated by the spark plasma sintering technique, and an electroless nickel-phosphorous (Ni-P) layer was deposited at the solder/TE interfaces. The experimental results confirm the importance of the Ni diffusion barrier in joint reliability. Intermetallic compound layers (Cu,Ni)₆Sn₅ and NiTe formed at the solder/Ni-P and Ni-P/substrate interfaces, respectively. The experimental results indicate that the mechanism of NiTe and (Cu,Ni)₆Sn₅ compound growth was dominated by the Peltier effect at high current density. When the current density was low, the growth of NiTe was affected by electromigration but the changes of thickness for (Cu,Ni)₆Sn₅ were not obvious.     

Gasoline permeation resistance of the as‐blow‐molded and annealed polyethylene,polyethylene/polyamide,and polyethylene/modified polyamide bottles

An investigation of the gasoline permeation resistance of the as‐blow‐molded and annealed polyethylene, polyethylene (PE)/polyamide (PA), and polyethylene/modified polyamide (MPA) bottles is reported. The gasoline permeation resistance improves dramatically after blending PA and MPA barrier resins in PE matrices during blow‐molding, and the order of barrier improvement corresponds to the order of barrier improvement of the barrier resins added in PE. Somewhat unexpectedly, the gasoline permeation rates of the annealed PE and/or PE/PA bottles annealed at 90°C or higher temperatures increase significantly with the annealing temperature and time. On the contrary, the gasoline permeation resistance of the annealed PE/MPA bottles increase significantly as the annealing temperature and/or time increase. For instance, the gasoline permeation rate of the PE/MPA bottle annealed at 120°C for 32 h is about 190 times slower than that of the as‐blow‐molded PE bottle. Further investigations found that, after blending the MPA and PA barrier resins in PE matrices, the relatively nonpolar hydrocarbon components present in the gasoline fuels were significantly blocked, without permeation during the permeation tests, in which the as‐blow‐molded PE/MPA bottle inhibited the permeation of hydrocarbon components more successfully than did the as‐blow‐molded PE/PA bottle. In contrast, the amounts of polar components that permeated through the as‐blow‐molded PE/PA and PE/MPA bottles were very small and about the same as the amount that permeated through the as‐blow‐molded PE bottle. Possible mechanisms accounting for these interesting behaviors are proposed in this study. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 2827–2837, 2001     

Hydrothermal catalytic production of fuels and chemicals from aquatic biomass

One of the promising avenues for biomass processing is the use of water as a reaction medium for wet or aquatic biomass. This review focuses on the hydrothermal catalytic production of fuels and chemicals from aquatic biomass. Two different regimes for conversion of aquatic biomass in hydrothermal conditions are discussed in detail. The first is hydrothermal liquefaction, and the second is hydrothermal gasification. The goals of these processes are to produce liquid‐fuel‐range hydrocarbons and methane or hydrogen, respectively. The catalytic upgrading of biocrude resulting from noncatalytic liquefaction and the stability and degradation of catalysts in high temperature water are also discussed. The review concludes with a brief discussion of the outlook for and opportunities within the field of hydrothermal catalytic valorization of biomass. Copyright © 2012 Society of Chemical Industry     

Estimation of deuterium recovery from the separation of water isotopes in thermal-diffusion columns of a countercurrent-flow frazier scheme with optimal plate aspect ratio

The effect of plate aspect ratio on the performance of deuterium recovery from the separation of water–isotope mixture in thermal-diffusion columns of a countercurrent-flow Frazier scheme was investigated. The equations for the optimal plate aspect ratios and the corresponding maximum recovery and maximum production rate were derived. Considerable improvement in performance is obtained when thermal-diffusion columns are operated at the optimal plate aspect ratio. Further improvement can be achieved if the scheme is connected and operated in countercurrent flow, instead of concurrent flow.     

Adjustment behaviour of capital structure over the business cycles: evidence from the construction industry of Taiwan

Prior studies have found that firms may deviate from the target capital structure in the short run and adjust towards the target in the long run. However, little attention has been given to the adjustment behaviour of capital structure in the construction industry over the business cycles, in particular within the context of emerging markets. The partial adjustment model with the GMM (i.e. generalized method of moments) estimation is used to examine the adjustment behaviour of capital structure in the construction industry within the context of Taiwan during the period 1982 to 2007. The results suggest that, first, the average rate of adjustment is 26.3% of the adjustment gap between the target debt ratios and the previous debt ratios for firms in the construction industry of Taiwan. However, the average rate of adjustment towards the target debt ratios has slowed down after the Asian financial crisis of 1997. Secondly, firms with the financial constraint of over‐leverage relative to the target debt ratios have lower debt ratios than those firms with the financial constraint of under‐leverage. In addition, the difference in debt ratios between firms with the financial constraint of over‐leverage and under‐leverage has become narrower after the Asian financial crisis. Lastly, the findings suggest that macroeconomic conditions do not have a significant, negative effect on debt ratios.     

Structural color of polymeric physical gels

In this study, the coloration mechanism of isotactic poly(1-butene) (iPB) in o-xylene and o-xylene/ethyl alcohol mixture gels were carried out. iPB gel becomes yellow because of transmitted light or blue because of reflected light. Changing the temperature, solvent composition, or even the thickness of samples of this gel continuously changes its color to blue, violet, purple, red, and yellow. Structural characterization, electron microscopy, and transmittance measurements were carried out for iPB dissolved in o-xylene to form a three-dimensional sponge-like network with different mesh sizes under various conditions. Subsequently, the relative refractive index between the solvent and gel network produces incoherent Tyndall blue scattering. Finally, color change due to variations in solvent composition or temperature contributes to the interplay between the refractive index of network structure n_network and solvent n_s. For a Tyndall medium with n_s/n_network >1, normal reflection creates a blue gel; when n_s/n_network ≒1, strong transmittance of light passing through the medium leads to a yellowish gel. This is the first report on the concept of structural color for polymeric physical gel systems.     

Effects of excess boron on combustion synthesis of alumina–tantalum boride composites

TaB- and TaB₂–Al₂O₃ in situ composites were fabricated by thermite-incorporated combustion synthesis from the powder mixtures of different combinations, including Ta₂O₅–Al–B, Ta₂O₅–Al–B₂O₃–B, and Ta₂O₅–B₂O₃–Al. Effects of excess boron were studied on the combustion dynamics and phase constituents of final products. For the B₂O₃-containing samples, the reaction was less exothermic and aluminothermic reduction of Ta₂O₅ and B₂O₃ was less complete, resulting in the deficiency of boron and the presence of TaO₂ and Ta. For the samples containing elemental boron, the occurrence of borothermic reduction of Ta₂O₅ also caused the loss of boron. Experimental evidence showed that boron in excess of the stoichiometric amount substantially enhanced the formation of tantalum borides, which in turn facilitated the reduction of Ta₂O₅ by Al. Consequently, the samples rich with boron in the molar proportions of Ta₂O₅:Al:B=3:10:9 and 3:10:16 (i.e., B/Ta=1.5 and 2.67) were found to be the optimum stoichiometries of producing TaB- and TaB₂–Al₂O₃ composites through a self-sustaining combustion process.     

Oxygen depletion properties of glucose-grafted polyethylene resins filled with sodium ascorbate/modified iron compounds

Oxygen scavenging plastic can react with oxygen that was trapped in the packaging materials or permeated into the packages, and then, extend the shelf life of food contained in packages. Sodium ascorbate (SA) and modified iron (MFe) compounds were chosen as the main components of oxygen scavengers to prepare the oxygen scavenging LDPE plastics. However, the widely used hydrophobic LDPE packaging material will slow down the oxygen depletion rate of these oxygen scavenger compounds. So glucose was used to modify the hydrophobic property of LDPE to improve the oxygen depletion properties of LDPE oxygen scavenging plastic. The oxygen depletion efficiency of L₉₅[SA_x(MFe)_y]₅ series samples improved initially as the weight ratios of SA/MFe increase, and reached the best as the weight ratios of SA/MFe approach 7/3. After modifying LDPE with glucoses, the oxygen depletion efficiency of each ML₉₅[SA_x(MFe)_y]₅ specimen improved even better than that of the corresponding L₉₅[SA_x(MFe)_y]₅ specimen with the same loading of oxygen scavenger compound, wherein the oxygen depletion efficiency of ML₉₅[SA_x(MFe)_y]₅ series specimens reached the best as the weight ratios of SA/MFe approach 1/9. In consistent with the oxygen depletion properties found in the previous section, the peroxide values of modeled food samples tested in the airtight flask with L₉₅[SA_x(MFe)_y]₅ and ML₉₅[SA_x(MFe)_y]₅ series samples reduce consistently as their oxygen depletion properties improve. In order to understand the interesting oxygen depletion properties of L₉₅[SA_x(MFe)_y]₅ and ML₉₅[SA_x(MFe)_y]₅ series samples, Fourier transform infrared spectroscopy, scanning electron microscope and energy dispersive X-rays analysis of these samples were performed.     

Improved shape evolution of copper interconnects prepared by jet-stream etching

In the preparation of copper interconnects in the conductor pattern of a printed circuit board (PCB), wet etching processes are commonly adopted for creating patterns of high-density interconnects. Currently available techniques of immersion and spray etching could lead to poorly shaped wires due to complex flow fields or the disturbing puddling effect. A modified technique of arrayed jet-stream etching was developed in this work, aiming at producing well-defined copper interconnects on a PCB in a significantly shorter time. The results were appealing in that copper interconnects of 35/140 μm (thickness/width) exhibiting etching factors of greater than 6 were obtained in 20 s, much better than the conventional ones with etching factors of 3 to 5 and etching times of at least 2 min. In addition, uniformly etched copper interconnects with less than 20 μm undercuts were observed on one etching line. One additional point to note is that no banking agents or inhibitors as commonly seen in conventional etching techniques were needed in this new processing method.