Polynuclear aromatic hydrocarbon and particulate emissions from two-stage combustion of polystyrene: the effects of the secondary furnace (afterburner) temperature and soot filtration

Laboratory experiments were conducted in a two-stage horizontal muffle furnace in order to monitor emissions from batch combustion of polystyrene (PS) and identify conditions that minimize them. PS is a dominant component of municipal and hospital waste streams. Bench-scale combustion of small samples (0.5 g) of shredded styrofoam cups was conducted in air, using an electrically heated horizontal muffle furnace, kept at Tgas = 1000 degrees C. Upon devolatilization, combustion of the polymer took place in a diffusion flame over the sample. The gaseous combustion products were mixed with additional air in a venturi and were channeled to a secondary muffle furnace (afterburner) kept at Tgas = 900-1100 degrees C; residence time therein varied between 0.6 and 0.8 s. At the exits of the primary and the secondary furnace the emissions of CO, CO2, O2, NOx, particulates as well as volatile and semivolatile hydrocarbons, such as polycyclic aromatic hydrocarbons (PAH), were monitored. Online analyzers, gravimetric techniques, and gas chromatography coupled to mass spectrometry (GC-MS) were used. Experiments were also conducted with a high-temperature barrier filter, placed just before the exit of the primary furnace to prevent the particulates from entering into the secondary furnace. Results demonstrated the beneficial effect of the afterburner in reducing PAH concentrations, including those of mutagenic species such as benzo[a]pyrene. Concentrations of individual PAH exhibited a pronounced after burner temperature dependence, typically ranging from a small decrease at 900 degrees C to a larger degree of consumption at 1100 degrees C. Consumption of PAH was observed to be the dominant feature at 900 degrees C, while significant quantities of benzene and some of its derivatives, captured by means of carbosieve/Carbotrap adsorbents, were formed in the afterburner at a temperature of 1000 degrees C. In the primary furnace, about 30% of the mass of the initial polystyrene was converted into soot, while the total mass of PAH represented about 3% of the initial mass of combustible. The afterburner reduced the particulate (soot) emissions by only 20-30%, which indicates that once soot is formed its destruction is rather difficult because its oxidation kinetics are slow undertypical furnace conditions. Moreover, increasing the afterburnertemperature resulted in an increasing trend of soot emissions therefrom, which might indicate competition between soot oxidation and formation, with some additional formation occurring at the higher temperatures. Contrary to the limited effect of the afterburner, high-temperature filtration of the combustion effluent prior to the exit of the primary furnace allowed for effective soot oxidation inside of the ceramic filter. Filtration drastically reduced soot emissions, by more than 90%. Limited soot formation in the afterburner was again observed with increasing temperatures. The yields of both CO and CO2 were largely unaffected by the temperature of the afterburner but increased at the presence of the filter indicating oxidation therein. A previously developed kinetic model was used to identify major chemical reaction pathways involving PAH in the afterburner. The experimental data at the exit of the primary furnace was used as input to these model computations. A first evaluation of the predictive capability of the model was conducted for the case with ceramic filter and a temperature of 900 degrees C. The afterburner was approximated as a plug-flow reactor, and model predictions at a residence time of 0.8 s were compared to experimental data collected at its exit. In agreement with the experimental PAH concentration, only a minor impact of the afterburner treatment was observed for most species at 900 degrees C. OH was deduced to be the major reactant with a mole fraction about 4 orders of magnitudes higher than that of hydrogen radicals. Evidence for the need of further work on the quantitative assessment of oxidation of PAH and their radicals is given.     

Effects of dissolved carbonates and carboxylates on the sorption of thiuram disulfide pesticides on humic acids and model surfaces

The sorption of a hydrophobic pesticide, thiram, on humic acid (HA) occurs via a specific pH-dependent binding of thiram at the deprotonated carboxylates of humic acid, forming a species thiram-[HACOO-] with K = 0.69. Similarly, thiram was sorbed by two model polycarboxylate-{SiO2COOH} materials via the formation of a surface species thiram-{SiO2COO-} with K = 0.45 between thiram and the eprotonated carboxylates grafted on SiO2 particles. In all cases, allowance of presence of bicarbonate at natural concentration caused severe inhibition of thiram's sorption. Oxalate and formate mimic the inhibitive effect of bicarbonate. Theoretical fit of the data showed that the inhibitive effect of HCO3- is due to the formation of the anionic species [thiram-HCO3](-1) (with K = 0.90) which is water soluble and competes with the bound species thiram-{HACOO-}. The same phenomena were observed for the sorption of disulfiram. The specific interaction phenomena reported here bear relevance to the sorption properties of thiram and disulfiram on real soils and, therefore, may determine their environmental fate.     

Contribution of the solar energy in the sustainable tourism development of the Mediterranean islands

The purpose of this work is to examine specific features of thermal and photovoltaic solar systems and their contribution to the sustainable tourism development of Mediterranean islands. In doing so, the best practices are studied and the factors which influence the transfer of these practices in other geographic regions are examined. We take under consideration the sensitiveness of many islander Mediterranean regions in relation to the climate changes and the perspective of their economic development through thematic tourism forms and differentiated tourism products and services. At a further step, we present currently developed innovative applications which are specially adapted to the needs identified within this research and we propose marketing strategies for their further expansion. The marketing approach followed is based on an innovative concept, which suggests that solar energy systems could constitute a driver for the development of specific forms of tourism. These systems are mainly the ICS solar water heaters, the coloured flat plate-collectors, the CPC collectors and the hybrid PV/T collectors. Apart from these, the use of booster reflectors that achieve a higher energy output in all cases of the above mentioned collectors is also suggested. We conclude that turning solar energy systems into a driver for specific types of tourism development and consequently of a local economic development is possible, if we take into consideration specific social needs and aspirations.     

Reliability and economic evaluation of small autonomous power systems containing only renewable energy sources

Evaluation of reliability performance in every power system has to be done within a cost–benefit framework. This approach, however, is a very time consuming task, especially for systems that contain a large number of possible configurations, so simpler techniques referred to the calculation of reliability indices are used. In small autonomous power systems (SAPSs), such an evaluation uses mainly deterministic criteria. This approach, however, cannot be applied in SAPS that contain only renewable energy sources, due to the intermittent nature of the provided energy. In this paper, a complete reliability cost and worth analysis is implemented for these systems, combined with the calculation of some basic probabilistic indices, in order to discover their performance and propose the appropriate of them as a criterion of optimal system configuration. This paper proposes that normalized energy reliability indices as system minutes and energy index of unavailability can be used as adequate criteria of system's optimal performance. This conclusion is validated through a large number of sensitivity analysis studies that are based on different maximum annual loads and different mix of load types.     

Response of an Elastic Structure Subject to Air Shock Considering Fluid-Structure Interaction

Shock-wave interaction with an elastic structure is investigated using a coupled numerical analysis approach, which considers solid-fluid interaction within an arbitrary Lagrangian-Eulerian framework. The analysis is performed considering a compressive shock wave, where the shock front is followed by constant pressure. An analysis procedure, which considers the change in the fluid domain due to the deformation of the solid and changes in the overpressure due to the movement of the elastic structure, is developed. Approximate numerical procedures for solving the Riemann problem associated with the shock are implemented within the Godunov finite volume scheme for the fluid domain. The influences of parameters such as structural stiffness and mass of the system on the displacement, velocity, and energy of the elastic structure following the shock-wave incidence are investigated. Immediately after the contact of the shock wave with the solid surface the pressure at the face of the elastic solid rises to a value which is equal to that obtained off of a fixed rigid wall. Subsequently, the motion of the piston produces changes in the applied pressure. The overpressure applied to the elastic system does not have a fixed profile but it depends on its elastic stiffness and structure mass. It is shown that there is a continuous exchange of energy between the air and the moving elastic structure, which produces a damped motion of the solid. The effect of damping is considerable for the cases of low elastic stiffness and low structural mass, where the resulting motion of the solid is nonoscillatory. The conventional analysis procedure, which ignores the energy exchange between the air and the moving solid, predicts an undamped oscillatory response of the structure for all cases considered. It is shown that neglecting the interaction between the air and solid can produce significant error in the total energy of the structure and the dynamic load factor when the resulting motion is nonoscillatory.     

Molecular Detection of Two Potential Probiotic Lactobacilli Strains and Evaluation of Their Performance as Starter Adjuncts in Yogurt Production

A molecular method for efficient and accurate detection and identification of two potential probiotic lactobacilli strains isolated from fermented olives, namely Lactobacillus pentosus B281 and Lb. plantarum B282, was developed in the present study. Random Amplified Polymorphic DNA (RAPD) analysis was performed, and strain specific primers were designed and applied in a multiplex polymerase chain reaction (PCR) assay. The specificity of the assay was tested and successfully confirmed in 27 and 22 lactobacilli strains for Lb. pentosus B281 and Lb. plantarum B282, respectively. Moreover, the two strains were used as starter cultures in yogurt production. Cell enumeration followed by multiplex PCR analysis demonstrated that the two strains were present in yogurt samples at levels ≥6 log CFU/g even after 35 days of storage at 4 °C. Microbiological analysis showed that lactobacilli and streptococci were present within usual levels, whereas enterobacteriaceae and yeast/mold counts were not detected as expected. Although the pH values of the novel products were slightly lower than the control ones, the yogurt containing the probiotic cultures scored similar values compared to the control in a series of sensory tests. Overall, these results demonstrated the possible use of the two strains as starter adjuncts in the production of yogurt with potential probiotic properties.