Enhanced storage/operation stability of small molecule organic photovoltaics using graphene oxide interfacial layer

Graphene and graphene oxide (GO) have been applied in flexible organic electronic devices with enhanced efficiency of polymeric photovoltaic (OPV) devices. In this work, we demonstrate that storage/operation stability of OPV can be substantially enhanced by spin-coating a GO buffer layer on ITO without any further treatment. With a 2 nm GO buffer layer, the power conversion efficiency (PCE) of a standard copper phthalocyanine (CuPc)/fullerene (C₆₀) based OPV device shows about 30% enhancement from 1.5% to 1.9%. More importantly, while the PCE of the standard device drop to 1/1000 of its original value after 60-days of operation-storage cycles; those of GO-buffered device maintained 84% of initial PCE even after 132-days. Atomic force microscopy studies show that CuPc forms larger crystallites on the GO-buffered ITO substrate leading to better optical absorption and thus photon utilization. Stability enhancement is attributed to the diffusion barrier of the GO layer which slow down diffusion of oxygen species from ITO to the active layers.     

Asymptotic Analysis of Spatially Correlated MIMO Multiple-Access Channels With Arbitrary Signaling Inputs for Joint and Separate Decoding

While the capacity of a single-user, point-to-point, multiple-input multiple-output (MIMO) channel has been well known, the achievable capacity of a MIMO channel in the presence of other co-channel users is much less understood. One such important scenario is the multiple-access (MA) channel where communication occurs from many uncoordinated mobile users to a common base station receiver (i.e., multipoint-to-point). Unlike previous studies whose emphases were on the idealized spatially uncorrelated channels with Gaussian signaling inputs from users, this paper derives a general analytical expression for the asymptotic (in the sense of large-system limit) sum-rate of a MIMO-MA system where the transmitters and the receiver can have different spatial correlations, and the users' inputs are not necessarily Gaussian. In addition to the sum-rate formula that assumes optimal joint decoding at the base station, we also derive the asymptotic sum-rate of a more practical system which performs separate decoding (multiuser detection followed by a bank of temporal error-correction decoders). Our analytic formulae are important in that they reveal the sum-rate one's system can achieve given the spatial correlation structures at the transmitters and receiver, and the input signal distributions. For special cases that users are homogeneous or users have Gaussian inputs, our results degenerate to previously published results. Furthermore, through computer simulations, we see that the proposed asymptotic solution gives good estimates for the ergodic sum-rate of the systems even with only a few antenna elements at each transmitter and receiver     

A 1-V 86-mW-RX 53-mW-TX Single-Chip CMOS Transceiver for WLAN IEEE 802.11a

A 1-V WLAN IEEE 802.11a CMOS transceiver integrates all building blocks on a single chip including a transformer-feedback VCO and a stacked divider for the frequency synthesizer and 8-bit IQ ADCs and 8-bit IQ DACs. Fabricated in a 0.18-mum CMOS process and operated at a single 1-V supply, the receiver and the transmitter consume 85.7 mW and 53.2 mW, including the frequency synthesizer, respectively. The total chip area with pads is 12.5 mm².     

Broad-band dual-polarized single microstrip patch antenna with highisolation and low cross polarization

This paper presents a new design of a broad-band dual-polarized single microstrip patch antenna with highly decoupled input ports and low cross-polarization (XP) radiation. A prototype of the proposed antenna with center frequency at 1800 MHz is presented. Both the dual linear polarizations have 10-dB return-loss impedance bandwidths greater than 14% and high decoupling between the two input ports (S₂₁ less than -40 dB across the entire bandwidths) is obtained. Moreover, the XP radiation in the principal planes of the dual linear polarizations is seen to be less than -20 dB     

Holography-Inspired Screens for Sub-Wavelength Focusing in the Near Field

Inspired by the principle of holography we present a concept for making simple transmission screens that can focus an incident wave into a sub-wavelength spot in the near field. The screen is made out of closely spaced, unequal slits cut on a metallic sheet. Fullwave simulations are presented for an example screen that focuses an incident plane wave down to a spot having a peak-to-null beamwidth equal to lambda/10 .     

Phase-matched four-wave mixing between pumps and signals in a copumped Raman amplifier

We observe four-wave mixing (FWM) between copropagating pumps and signals in a Raman amplifier when the zero-dispersion wavelength of the transmission fiber lies symmetrically between the pump and the signal wavelengths. The resultant FWM products, which grow as they experience Raman gain along the fiber, can degrade the signal's optical signal-to-noise ratio by as much as 10 dB for a Raman ON-OFF gain of 15 dB.     

Minimizing hydrogen content in silicon oxynitride by thermal oxidation of silicon-rich silicon nitride

This work reports a detailed study of the re-oxidation effects on the hydrogen content and optical properties of silicon oxynitride films grown by plasma enhanced chemical vapor deposition (PECVD) with N₂O, NH₃ and SiH₄ as the precursors. Results showed that the silicon oxynitride deposited with gas flow rates of NH₃/N₂O/SiH₄ = 20/500/20 (sccm) has favorable properties for integrated waveguide applications. The refractive index of this layer is about 1.57 at 632.8 nm wavelength and the layer has a comparative low density of NH bonds. With a high temperature re-oxidation of the as-deposited film, the hydrogen content of the oxynitride film was reduced from 2.255 × 10²² to 6.98 × 10²⁰ cm⁻³ which is attributed to the removal of excess silicon oxidation and hydrogen bonds.     

Multi-objective module placement for 3-D system-on-package

System-on-package (SOP) is a viable alternative to system-on-chip (SOC) for meeting the rigorous requirements of today's mixed-signal system integration. Thermal integrity is arguably the most crucial issue in three-dimensional (3-D) SOP due to the compact nature of the 3-D integration. In addition, the power supply noise issue becomes more serious as the supply voltage continues to decrease while the number of active devices consuming power increases. We propose a 3-D module and decap (decoupling capacitance) placement algorithm that evenly distributes the thermal profile and reduces the power supply noise. In addition, we allocate white spaces around the modules that require decaps to suppress the power supply noise while minimizing the area overhead. In our experimentation, we achieve improvements in both maximum temperature and decap amount with only small increase in area, wirelength, and runtime.     

Fast-polarization-hopping transmission diversity to mitigate prolonged deep fades in indoor wireless communications

Fast-polarization-hopping (FPH) transmission diversity is herein proposed to mitigate prolonged deep fades at the mobile receiver in, for example, the indoor propagation environment. Even if the individual multipaths are each sufficiently strong for detection, deep fades may occur due to the multipath signals' destructive summation at the receiver. The relative immobility of the transmitter, the propagation environment, and the receiver in the indoor environment means that a deep fade may last for a very long duration, dropping calls or severing links. By rapidly hopping the transmission polarization (say, alternating transmission between a vertically-polarized-dipole antenna and a horizontally-polarized-dipole antenna - or between two "X"-oriented dipoles), the effective propagation channel experiences consecutive polarization modes (each involving a different multipath summation), all within the duration allowed by the channel-coder's interleaving depth. This scheme is usable for either frequency-shift keying (with incoherent demodulation), or for channel-coded phase-shift keying (with differential coding, or with pilot-symbol phase synchronization). This scheme requires no change in the mobile receiver (which does not need to be dual polarized). The base station also needs no spatially separated antenna array, nor any other additional hardware, no mechanical movement of the transmitting antenna(s), and no sophisticated signal processing (such as channel estimation or closed-loop feedback) nor any additional software. The proposed scheme's cost - relative to using antenna arrays at the base station and/or the mobile - is a potentially doubling of the transmission bandwidth. The proposed scheme's potential is illustrated by limited computer simulations using CINDOOR, a polarization-sensitive indoor wireless-propagation ray-tracing simulation software package based on geometrical optics and the uniform theory of diffraction (GO/UTD).     

Web cache replacement policies: a pragmatic approach

Research involving Web cache replacement policy has been active for at least a decade. In this-article we would like to claim that there is a sufficient number of good policies, and further proposals would only produce minute improvements. We argue that the focus should be fitness for purpose rather than proposing any new policies. Up to now, almost all policies were purported to perform better than others, creating confusion as to which policy should be used. Actually, a policy only performs well in certain environments. Therefore, the goal of this article is to identify the appropriate policies for proxies with different characteristics, such as proxies with a small cache, limited bandwidth, and limited processing power, as well as suggest policies for different types of proxies, such as ISP-level and root-level proxies.