Super porous α-, β-, γ-cyclodextrin cryogels with high active agent loading and controllable release profiles

Cyclodextrins (CDs) are truncated cone-like structures that are natural cyclic oligosaccharides. Here, a simple preparation method for super porous poly(α-CD), poly(β-CD), and poly(γ-CD) cryogels crosslinking with divinyl sulfone at 150%, 100% and 125% mole ratios with respect to the α-CD, β-CD, and γ-CD molecules, respectively, under cryogenic conditions, is reported. The interconnected homogeneous pore distribution of CD-based cryogels with pore sizes in the range of 5–100 μm is confirmed by SEM analysis. The CD-based cryogels weighing 10 mg are determined as hemocompatible with <1% hemolysis ratios and >79% blood clotting indexes; whereas the same materials weighing 1 mg are biocompatible with >75% cell viability on L929 fibroblasts. Additionally, active agent adsorption/delivery efficiencies of CD-based cryogels utilizing two active agents, Bisphenol A (BPA, a carcinogenic compound) and Curcumin (CUR, a polyphenolic compound), are individually evaluated. It was revealed that p(γ-CD) cryogels exhibited the highest active agent loading capacity for BPA, 87 ± 13 mg/g, whereas p(α-CD) cryogels showed the highest loading capacity for CUR, 136 ± 4 mg/g. Moreover, the active agent release from p(α-CD), p(β-CD), and p(γ-CD) cryogel networks at pH 7.4 and 37°C were determined as 40.6 ± 2, 35.3 ± 2, and 34 ± 1 mg/g for BPA, and 1.07 ± 0.2, 1.27 ± 0.1, and 1.37 ± 0.1 mg/g for CUR, respectively, within 96 h.     

The effect of recycling number on the mechanical,chemical, thermal,and rheological properties of PBT/PC/ABS ternary blends: With and without glass‐fiber

The recycling possibilities of poly(butylene terephthalate)/polycarbonate/acrylonitrile–butadiene–styrene (PBT/PC/ABS) ternary blend with and without glass‐fiber content were investigated using repeated injection molding process. In this study, PBT/PC/ABS ternary blends were reprocessed at five times and the results were presented after each recycling process. The recycling possibility of PBT/PC/ABS ternary blend was evaluated by measuring the mechanical, chemical, thermal, and rheological properties. Mechanical properties were determined by the tensile strength, yield strength, strain at break, elastic modulus, impact strength, flexural strength, and flexural modulus. Chemical and thermal properties were evaluated by Fourier transform infrared spectroscopy, differential scanning calorimetry, thermal gravimetric analysis, and scanning electron microscopy. Rheological properties of the ternary blends were studied by melt flow index measurement. From the results, it was found that mechanical properties of recycled composites were better than virgin PBT/PC/ABS ternary blends. POLYM. COMPOS., 35:2074–2084, 2014. © 2014 Society of Plastics Engineers     

Evaluation of surface settlements in the Istanbul metro in terms of analytical, numerical and direct measurements

In urban areas, the use of pre-support in shallow tunnels is increasing in order to improve the excavation stability and reduce ground settlements induced by the tunneling. This paper describes the effects of pipe roofing on surface settlements and evaluates the settlements associated with the twin tunnels in the Istanbul metro in terms of numerical, semi-empirical and measured values. FLAC3D was used for the numerical modeling and the method suggested by Herzog for the semi-empirical solution. The numerical results indicate that the tunnel roof formed by the pipe roofing provides a restraining effect, reducing deformation and ground surface settlement by up to 65?%. Herzog’s model yields higher maximum surface settlements than those observed. When modified to include the effect of pipe roofing and the distance between the pipes however, there is good agreement between the direct measurements and the values predicted by the numerical and modified Herzog models.     

Planar shape representation and matching under projective transformation

This paper introduces a new representation for planar objects which is invariant to projective transformation. Proposed representation relies on a new shape basis which we refer to as the conic basis. The conic basis takes conic-section coefficients as its dimensions and represents the object as a convex combination of conic-sections. Pairs of conic-sections in this new basis and their projective invariants provides the proposed view invariant representation. We hypothesize that two projectively transformed versions of an object result in the same representation. We show that our hypothesis provides promising recognition performance when we use the nearest neighbor rule to match projectively deformed objects.     

Predictors of attitudinal and behavioral outcomes in mobile advertising: A field experiment

The study examines consumer responses to SMS-based mobile advertising campaigns using a field experiment with actual behavioral responses. Specifically, the effects of message characteristics (i.e., incentives and prior permission) and individual differences of message recipients (i.e., content involvement, prior experience with the mobile medium, and medium-fit perceptions) on the attitudinal and behavioral outcomes of such campaigns are investigated. Perceived intrusiveness of the message and attitude toward the campaign are conceptualized as key attitudinal reactions triggered by a mobile advertising message, which in turn influence the behavioral responses generated by the campaign. Findings suggest that, in comparison to permission and incentive, individual differences are stronger determinants of responses to mobile advertising campaigns. Additionally, intriguing insights with respect to the effectiveness of different types of incentives are provided.     

Failure Analysis of a Location Axle in Tracked Tractor

In this study, a failure analysis was performed on the location axle (brace axle) of a blade on a tracked tractor used in agricultural areas. The analysis included evaluation of the macrostructure of the damage and the microstructure of the material, as well as a chemical analysis of the material. A commercial finite element method software package was used to determine the behavior of the location axle under the defined boundary conditions. After all the examination steps were completed, the main reason for the damage was determined to be manufacture and material error despite the presence of fatigue tracks in the damaged area. In addition, a heat treatment was carried out with the specimens taken from the damaged area and microstructure was re-examined. The experimental and simulation evaluation results provide a technical basis for suggestions to prevent future damage to the location axle.     

Lateral Weir Flow Model using a Curve Fitting Analysis

A numerical approach is considered for flow over side weirs as a substantial part of distribution channels in irrigation systems and treatment units. The model is based on the energy principle and a curve-fitting technique. For this purpose, the side weir was divided into elementary strips to develop generalized equations for discharge and surface profile. The change in water surface elevation towards the weir crest and the inclination of the deflected flow over the weir were also taken into account. Dimensionless parameters were used and the normalized equations solved to obtain the hydraulic parameters of side weirs. The results were plotted to determine general relationships based on the curve-fitting technique. A practical application of the derived equations to obtain hydraulic parameters of side weirs is performed using literature data.     

Effect of Lateral Water Surface Profile on Side Weir Discharge

The average water surface slope in the lateral direction is taken into account as a local parameter ψ to study flow over a side weir. It was later shown that for smaller side weir lengths and side weir portions with no entrance and exit transition effects, ψ can be obtained from a numerical integral and also from the measurements of water surface elevations in the lateral direction. The effect of elemental weir length was further determined. Dividing the weir length into smaller computational segments has the effect of lowering the water surface to approach the measured profile, the downstream ends being coincident. The model was verified using experimental data.