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131.
This paper deals with the non-steady-state kinetics of direct thermal initiated polymerization. The initiation is assumed to be a bimolecular reaction of the monomer. The relationship between the radical concentration and the monomer conversion is rigorously derived. In further treatment a few very close approximations are introduced based on the fact that the number of monomer molecules reacting in the initiation step is much less than that consumed in the propagation step for a process producing high polymer, and the value of the rate constant for propagation or chain transfer is much lower than that for chain termination. Expressions for various molecular parameters, such as molecular weight distribution, number-average and weight-average degrees of polymerization, and dispersity, are given. Several numerical examples are provided. 相似文献
133.
The aim of this study was to determine the actual prevalence of diabetes mellitus and to investigate the contribution of various risk factors to the diabetes mellitus among the population in a methyl mercury polluted area. The study was a population based cross sectional mass screening survey. A case-control study was designed to estimate the role of various risk factors including methyl mercury exposure for diabetes mellitus. The study was confined to a small rural town 10 km north of Minamata City; 1,087 persons older than 40 years were examined. Measurement of glucose metabolism was made on the basis of urine and haematological examinations. Data on risk factors were collected by questionnaire, and by measurement of body height and weight (obesity). The prevalence rate of the diabetes mellitus was 8.4% in males and 5.3% in females. The odds ratio of family history was significantly higher, 4.63. The odds ratio of residential history in a methyl mercury high polluted area was 0.58. The prevalence of the diabetes mellitus in this methyl mercury polluted area was not increased, contrary to what was expected based on the pathological findings. 相似文献
134.
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136.
Fatigue behavior and morphology of long glass fiber reinforced semicrystalline polyamide (nylon 6,6) and amorphous polycarbonate (PC) composites were investigated. The fiber length distribution in the molded samples was calculated by image analyzer. The tension-tension fatigue loading tests at various levels of stress amplitudes were studied. The two-parameter Weibull distribution function were applied to obtain the statistical probability distribution of experimental data. A good correlation existed between the experimental data and the Weibull distribution curves. Straight line S? N curves of long glass fiber reinforced semicrystalline polyamide and amorphous polycarbonate composites at various probabilities were established. The stiffness of the composite under tension-tension fatigue loading was measured. The thermal stress history was also investigated by thermo-imaging techniques during fatigue life testing. Further, failure morphology was examined by scanning electron microscopy (SEM). The results showed that the fracture behavior of the ductile damage in polyamide is different from the brittle damage in polycarbonate. 相似文献
137.
The authors present a method for solving a class of optimization problems with nonsmooth constraints. In particular, they apply the method to the design of narrowband minimum-power antenna array processors which are robust in the presence of errors such as array element placement, look direction misalignment, and frequency offset. They first show that the constrained minimum power problem has a unique global minimum provided that the constraint set is nonempty. Then it is shown how the design problem derived directly from considerations of the sensitivity of the antenna array processor to errors can be transformed into a quadratic programming problem with linear inequality constraints which can be solved efficiently by the standard active set strategy. They also present numerical results for two types of nonsmooth constraints developed to provided robustness. These results confirm the effectiveness of the method 相似文献
138.
三氯乙烯与糠醛水溶液的液液平衡及萃取模拟计算 总被引:3,自引:0,他引:3
本文采用液液平衡釜了糠醛水溶液与三氯乙烯的液液平衡数据,用UNIQUAC方程关联糠醛-水-三氯乙烯体系的液液平衡数据,以UNIQUAC方程的模型,采用液液萃取法模拟计算糖醛和水的分离结果。 相似文献
139.
GaN的MOVPE生长和m-i-n型蓝光LED的试制 总被引:1,自引:0,他引:1
利用自行研制的常压MOVPE设备和全部国产MO源,采用低温生长缓冲层技术,在蓝宝石(α-Al2O3)衬底上获得了高质量的GaN外延层。未掺杂的GaN外延层的室温电子迁移率已达114cm2/V.s,载流于浓度为2×1018。77K光致发光谱近带边发射峰波长为365nm,其线宽为4DmeV。X射线双晶衍射回摆曲线的线宽为360arcsec。用Zn掺杂生长了绝缘的i-GaN层。在此基础上研制了m-i-n型GaN的LED,并在室温正向偏压下发出波长为455nm的蓝光。 相似文献
140.
Circuit sensitivity to interconnect variation 总被引:1,自引:0,他引:1
Lin Z. Spanos C.J. Milor L.S. Lin Y.T. 《Semiconductor Manufacturing, IEEE Transactions on》1998,11(4):557-568
Deep submicron technology makes interconnect one of the main factors determining the circuit performance. Previous work shows that interconnect parameters exhibit a significant amount of spatial variation. In this work, we develop approaches to study the influence of the interconnect variation on circuit performance and to evaluate the circuit sensitivity to interconnect parameters. First, an accurate interconnect modeling technique is presented, and an interconnect model library is developed. Then, we explore an approach using parameterized interconnect models to study circuit sensitivity via a ring oscillator circuit. Finally, we present an alternative approach using statistical experimental design techniques to study the sensitivity of a large and complicated circuit to interconnect variations 相似文献