超塑性Y-TZP增韧陶瓷超细粉末的研究

用化学共沉淀法制备了3mol％Y_2O_3-ZrO_2超细粉末。利用热分析,x射线,透射电镜,颗粒粒度分析仪分析了粉料的相组成;颗粒形貌、大小;粉料的团聚状态;化学组成的均一性以及其烧结性能,并结合烧结试样的显微结构和力学性能对粉末的性能做出了评价。实验表明,所制备的粉料组成较为均匀;粒度分布窄;团聚体尺寸小,烧结活性高;颗粒粒度约为200(?)。粉料的相组成主要为四方相和约26％的单斜相。3Y-TZP陶瓷材料三点弯曲强度达1479.14MPa,断裂韧性为13.2MPa·m~(1/2),超塑性压缩变形达190％。     

1-H苯并三氮唑乙酸酯的合成、表征及其摩擦学性能

苯并三氮唑具有良好的摩擦学性能, 但在矿物油中的溶解性较差.为提高其在矿物油中的溶解性,采用1-H苯并三氮唑与氯乙酸酯进行取代反应,合成了3种1-H苯并三氮唑乙酸酯新型润滑油添加剂,用IR、UV、1H NMR、13C NMR、MS和元素分析对其结构进行了分析表征,确证了其结构.利用四球试验机考察了其在液体石蜡中的最大无卡咬负荷值.结果表明:合成的3种化合物均能溶于大部分有机溶剂而难溶于水;热失重分析结果表明,第一分解温度均高于218 ℃,能适应一般工况条件的要求;3种化合物在液体石蜡中有良好的极压抗磨作用,最大无卡咬负荷值可达862 N,与二烷基二硫代磷酸锌(ZDDP)相当.     

Preloading using fill surcharge and prefabricated vertical drains for an airport

This paper presents the field measurements and analysis of a preloading project with the installation of prefabricated vertical drains (PVDs) in Wenzhou, China. At the site, PVDs were installed to a depth of 22?m from the ground surface with a spacing of 1.5?m in a triangular pattern. The preloading fill thickness was 6?m with a unit weight of approximately 18 kN/m³. After a total elapsed time of 310 days, approximately 3?m thick fill was removed. The measured preloading settlement was approximately 1.5?m. The measurements and analytical results indicated that the soil layer with PVD improvement reached almost 100% primary consolidation when part of the fill was removed. After partial unloading, the PVD-improved zone was in an over-consolidated state. After the runway was opened for traffic, a settlement increment of approximately 7?mm was monitored over a period of 11 months. Analysis indicated that the settlement was mainly due to the consolidation of soil layers below the PVD-improved zone and post-surcharge secondary consolidation of the PVD-improved zone. The values of the parameters related to PVD improvement were back-estimated from the field measurements. These findings can be used to guide the design of PVDs improvement along the east coast of China.     

Effect of surcharge loading rate and mobilized load ratio on the performance of vacuum–surcharge preloading with PVDs

The results from three laboratory model tests performed under various vacuum and surcharge loads with PVDs are reported. Different SLRs were adopted to investigate the effect on the consolidation of dredged soil. To measure the lateral displacement, a refitted inclinometer was developed and tested. In the tests, the settlement, lateral displacement, and vane shear strength were measured, and the degree of consolidation (DOC), horizontal coefficient of consolidation (C_h), and bearing capacity were calculated. The results indicate that larger SLR values promote consolidation. The largest vane shear strength, settlement, and C_h values were all obtained under the highest SLR, and the bearing capacity under this SLR was more than double that under the lowest SLR. The DOC was found to increase with the growth of the SLR. However, considering the vacuum pressure was higher in Case-III, the influence of SLR on reinforcement effect may not be so significant.     

一种全新的弧面凸轮廓面修形方法

针对现有弧面凸轮廓面修形方法存在的不足，提出了一种全新的弧面凸轮廓面修形方法，并对该修形方法进行了理论分析与加工实践。采用弧面凸轮非工作面避让原则以防止分度段凹槽两侧廓面同时与滚子啮合，加厚分度停歇段凸脊以消除轴承与滚子内游隙，多滚子啮合时使压力角小的滚子优先参与啮合以提高传动效率，通过以上措施，有效地保证了孤面凸轮分度段的实际工作廓面与理论设计廓面、实际中心距与理论设计中心距的一致性，改善了弧面凸轮机构的装配性能、分度精度与传动效率，有效地消除了弧面凸轮机构可能存在的干涉现象。     

饱和土中单排弹性桩对平面S波的屏蔽

基于饱和土弹性波动方程,考虑土体和水耦合作用的影响,分析了全空间均质饱和土中弹性排桩对入射平面S波的散射。将入射波和散射波的势函数展开成Fourier-Bessel函数的无穷级数的形式,利用一组圆柱坐标系统和加法转换定理,通过施加桩土界面处的连续条件,求解出待定散射系数,进而得到饱和土体中任意点的位移和应力。根据算例考察了饱和土的渗透系数、桩数量和桩间距等对排桩屏蔽效果的影响,并和单相弹性土体中排桩的屏蔽效果作了对比,得出了一些有意义的结论。     

Ni2P/TiO2的制备、表征及其加氢脱硫反应性能

利用程序升温还原方法合成了Ni2P／TiO2催化剂,采用H2-TPR、XRD、XPS等技术对样品的结构和性质进行了表征,研究了催化剂对噻吩的常压加氢脱硫反应性能。结果表明,在TiO2为载体的负载型催化剂上,Ni2P为主要活性相,无明显的单质Ni相;与Ni2P／SiO2相比,Ni2P／TiO2催化剂对噻吩常压加氢脱硫反应有较高的转化率以及良好的稳定性,噻吩稳定转化率达到了36％左右。     

螺带式混凝土搅拌机混合特性及DEM模拟

采用离散单元法模拟新拌混凝土于搅拌机中的混合过程,研究了双筒螺带式混凝土搅拌机的混合效率。 用Hertz-Mindlin with JKR接触方法建立新拌混凝土离散元模型,模拟了坍落度实验、L箱实验和流变仪实验,将模拟结果与实验结果进行对比,校准模型参数,采用混合系数定量研究了不同初始装填方式下搅拌机的混合效率。结果表明,采用上下装填方式时搅拌机混合效率较高;对任一初始装填方式,左部区域与右部区域、前部区域与后部区域间混合效率无明显差别,而上部区域混合效率比底部区域高,底部出料口处存在搅拌盲区,采用舍弃初始出料的方法可提高新拌混凝土性能。转速较高时混合效率较高,相同旋转圈数时,混合效率基本相同。     

基于迟滞阈值分割的瓶口缺陷检测方法

随着工业机器人和现代化工业的快速发展,人们对工业机器人的性能要求越来越高,为了提高工业生产的效率和产品的质量,智能、高速、高精度是工业机器人的必备要求。国内基于机器视觉的智能啤酒瓶口缺陷检测方法中,高速、高精度仍是一个亟待解决的问题。为此,提出了一种基于随机圆拟合评估的四圆周定位法,大大提高了瓶口检测区域的定位精度,并提出了基于投影特征的分区域磁滞阈值分割的智能瓶口缺陷检测方法。对采集的488幅灰度图像进行测试,检测正确率为99.4%,检测平均速度为38 ms,算法的检测速度快,检测精度高,可以很好地应用到高速、高精度的现代化工业机器人中。     

Synthesis and magnetic property of FeMoO4 nanorods

Monoclinic FeMoO₄ nanorods have been prepared by the hydrothermal method in an acid aqueous solution. Scanning electron microscopy, transmission electron microscopy, X-ray diffraction spectrum, X-ray photoelectron spectra and differential scanning calorimetry are used to characterize the structure, morphology and composition of the sample. The FeMoO₄ nanorods exhibit a ferromagnetic property at room temperature with the coercivity of 31.1 Oe and remnant magnetization of 4.09 × 10⁻³ emu/g, respectively. The magnetic mechanism has been discussed according to the calculated results of electron density of states for FeMoO₄ with consideration of oxygen vacancies by using the Vienna ab initio simulation package.