结焦抑制剂N-360在乙烷炉上的应用

中国石化扬子石油化工股份有限公司烯烃厂1号乙烯装置两台乙烷炉运行周期一直偏低,辐射段炉管使用寿命较短,并影响急冷油减粘系统的稳定运行。应用结焦抑制剂N-360后,乙烷炉运行周期与辐射段炉管使用寿命大幅延长,并且能耗下降、产品收率提高。     

基于回归模型的CPU超频仿真软件设计

为了帮助认识CPU超频问题并熟悉超频设置操作,进行CPU超频仿真软件设计的全面研究。分析CPU超频的影响因素,介绍超频的方法和操作流程;讨论软件的功能模块结构、模块的运行流程和样本数据的存储方法;重点研究CPU超频后的性能测试结果估计问题,并为此提出了建立回归模型的解决之道;详细探讨了VB.NET与Matlab混合编程的接口与实现途径,并以此种方式完成了程序代码的编写。试用表明,该软件功能完整、界面直观、使用简便,能够为理解超频理论和熟悉超频操作提供有效帮助。     

Biomimetic strain hardening in interpenetrating polymer network hydrogels

In this paper, we present the systematic development of mechanically enhanced interpenetrating polymer network (IPN) hydrogels with Young's moduli rivaling those of natural load-bearing tissues. The IPNs were formed by synthesis of a crosslinked poly(acrylic acid) (PAA) network within an end-linked poly(ethylene glycol) (PEG) macromonomer network. The strain-hardening behavior of these PEG/PAA IPNs was studied through uniaxial tensile testing and swelling measurements. The interaction between the independently crosslinked networks within the IPN was varied by (1) changing the molecular weight of the PEG macromonomer, (2) controlling the degree of PAA ionization by changing pH, and (3) increasing the polymer content in the PAA network. Young's moduli and the maximum stress-at-break of the swollen hydrogels were normalized on the basis of their polymer content. Strain hardening in the IPNs exhibited a strong dependence on the molecular weight of the first network macromonomer, the pH of the swelling buffer, as well as the polymer content of the second network. The results indicate that the mechanical enhancement of these IPNs is mediated by the strain-induced intensity of physical entanglements between the two networks. The strain can be applied either by mechanical deformation or by changing the pH to modulate the swelling of the PAA network. At pHs below the pK_a of PAA (4.7), entanglements between PEG and PAA are reinforced by interpolymer hydrogen bonds, yielding IPNs with high fracture strength. At pHs above 4.7, a “pre-stressed” IPN with dramatically enhanced modulus is formed due to ionization-induced swelling of the PAA network within a static PEG network. The modulus enhancement ranged from two-fold to over 10-fold depending on the synthesis conditions used. Variation of the network parameters and swelling conditions enabled “tuning” of the hydrogels' physical properties, yielding materials with water content between 58% and 90% water, tensile strength between 2.0 MPa and 12.0 MPa, and initial Young's modulus between 1.0 MPa and 19.0 MPa. Under physiologic pH and salt concentration, these materials attain “biomimetic” values for initial Young's modulus in addition to high tensile strength and water content. As such, they are promising new candidates for artificial replacement of natural tissues such as the cornea, cartilage, and other load-bearing structures.     

氟化改性丙烯酸树脂的合成及在飞机蒙皮涂料中的应用

合成了氟化改性羟基丙烯酸树脂,用HDI三聚体为固化剂,配制双组分聚氨酯丙烯酸飞机面漆,介绍了配方设计、性能检测及其在飞机上的使用效果。     

Studies on the semirigid chain polyamide—poly(1,4-phenyleneterephthalamide)

In this article, the polycondensation of terephthaloyl chloride and p-phenylenediamine was systematically studied, including the liquid–crystalline state of the solution and the spinning of poly(1,4-phenyleneterephthalamide) (PPTA). High-molecular-weight PPTA with ε_inh = 5–7 was prepared and the main factors influencing the solution polycondensation of 1,4-phenylenediamine with terephthaloyl chloride were studied in detail. Experimental results showed that the water content of the reaction system, reactant concentration, and volume ratio of mix solvents have a great influence on the inherent viscosity of the poly(1,4-phenyleneterephthalamide) obtained. The highest ε_inh was obtained at 0.3M/liter reactant concentration in a mixed solvent ratio HMPA/DMAC of 4/1 (by volume), at 0.35M/liter reactant concentration in a mixed solvent of HMPA/NMP = 7/3, and at 0.5M/liter of reactant concentration in a mixed solvent of HMPA/THF = 9/1. The water content must be controlled to less than 100 ppm in the polymerization system. In the early stage of the polycondensation process, the ε_inh of the polymer obtained increased rapidly with time. The system gelled within 2 or 3 min, while the monomer conversion reached about 100%. However, the reaction of polycondensation continued after gelation and the ε_inh of the polymer increased appreciably. We have studied the viscosity behavior at 20–155°C for the anisotropic solution of PPTA in 100% sulfuric acid (ε_inh of PPTA 2.5–4.9). Experimental results showed that, at low concentrations the viscosity of isotropic solution increases with the increase of polymer concentration to reach a maxium near the critical polymer concentration, beyond which the solution changes to an anisotropic liquid–crystalline solution. The appropriate spinning region was obtained as shown in the phase diagram determined by viscosity, degree of depolarization anisotropy, and region of thermal depolymerization. Fibers of PPTA with high modulus and high tenacity were obtained by dry-jet wet spinning. The fibers obtained have a tenacity of ～22 g/denier, a modulus of ～600 g/denier, and elongation at break ～3.5%.     

基于蜂群算法任意平面阵最大信干噪比研究

针对复杂战场环境下超短波电台天线接收低信噪比信号能力弱和易受定向干扰的缺陷,结合战场超短波电台不规则分布和位置不能任意改变的特点,提出任意结构天线阵信号接收模型,采用蜂群算法优化阵元相位使得天线阵输出信干噪比最大。假设信噪比为0 dB,干噪比为60 dB,且在平面内随机选取8个阵元,采用蜂群算法优化后输出信干噪比为8.633 dB。与改进差分进化算法、遗传算法和粒子群优化算法相比,分别提高了0.577 dB、1.124 dB和1.543 dB。研究成果可为超短波电台组阵通信提供参考。     

具有自适应噪声边界的Tube可达集鲁棒预测控制

针对过程噪声设定边界与真实噪声边界失配的有界干扰离散线性不确定系统,提出一种具有自适应噪声边界的Tube可达集鲁棒模型预测控制方法.首先,该算法引入基于MIT规则的自适应集员滤波在线估计系统状态和噪声边界.其次,基于估计值,通过迭代自适应集员滤波的时间更新部分计算出预测时域内闭环不确定系统状态的可达集.最后,用可达集代替不变集并根据Tube鲁棒模型预测控制策略,给出了实际不确定系统的控制律,确保系统状态鲁棒渐近稳定,并收敛于终端干扰不变集.仿真结果验证了该控制方法的有效性.     

用烧结刚玉研制再结合刚玉砖

介绍了以烧结刚玉和板状刚玉为原料试制再结合刚玉砖的生产工艺。同时，研究了不同原料、氧化铝微粉、外加物及工艺条件对制品性能的影响。     

基于“二叉决策树”模型的嵌入式软件调试

在嵌入式软件开发过程中,软件不可避免地会出现各种错误,因此调试是软件生命周期中一个非常重要的环节。针对嵌入式软件开发的流程和特点,对其调试部分进行较为深入具体的研究和探索,提出基于调试器的"二叉决策树"调试模型。该模型描述了嵌入式软件调试的一般过程、调试对象和常用方法。实践表明"二叉决策树"调试模型具有较好的实用性和扩展性。     

4-乙酰氧基氮杂环丁酮的合成工艺研究

以6-氨基青霉烷酸(6-APA)为原料,经溴代、酯化、格氏反应、还原、羟基保护、开环、氧化断裂等步骤得到目标产物,反应总收率达27.9%。