Novel blood-compatible waterborne polyurethane using chitosan as an extender

A series of novel block polymers of polyurethane (PU) and chitosan have been prepared in two steps. The first step is the preparation of PU prepolymer, obtained from polytetramethylene oxide glycol (PTMO, M_n = 1000), isophrone diisocyanate (IPDI), and 2,2′-dimethylol propionic acid (DMPA), followed by ionizing PU prepolymer with triethylamine (TEA). The second step involves PU chain-extended by water-soluble chitosan of low molecular weight (M_n = 5000) by self-emulsion polymerization method. The sizes of the latex particles, morphology, and copolymer architecture have been characterized by dynamic light scattering (DLS), general tensile test, infrared spectroscopy (IR), surface contact angle measurement, and transmission electron microscopy (TEM). Furthermore, it shows that the addition of chitosan remarkably increases anticoagulative property of PU elastomers confirmed by the recalcification time. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Preparation and Characterization of Carboxymethyl Chitosan and β-Cyclodextrin Microspheres by Spray Drying

Three kinds of carboxymethyl chitosan/β-cyclodextrin microspheres loaded with theophylline were prepared by spray drying intended for pulmonary delivery. Mucociliotoxicity, permeation rate, and drug release characteristics of the product were investigated. The microspheres obtained by spray drying were found to be spherical with smooth or wrinkled surfaces. The mean particle size was between 3.39 and 6.06 µm. The microspheres demonstrated high product yield (43.7-50.2%), high drug loading (13.7-38.1%), and high encapsulation efficiency (86.9-92.8%). FT-IR indicated that there were interactions of theophylline with carboxymethyl chitosan matrix. Further studies on mucociliotoxicity and permeation confirmed that microspheres had better adaptability and high permeation rate. In vitro drug release from the microspheres was not related to the drug/polymer ratios.     

尼龙6/改性双马来酰亚胺共混物的制备

将尼龙6与改性双马来酰亚胺熔融共混形成合金以提高其热稳定性能.用转矩流变仪考察了尼龙6/改性双马来酰亚胺共混体系熔融反应过程中的流变行为,用TG-DSC测试了共混物的热性能.结果表明:熔融共混时,2组分间的化学反应进行很快,改性双马来酰亚胺用量增加,共混物的熔融粘度增大,温度或转速升高,平衡转矩降低;改性双马来酰亚胺可明显改善尼龙6的高温热稳定性能,当尼龙6与改性双马来酰亚胺的质量比为20/1时,共混物在236-340℃温度范围内有很好的热稳定性.     

Matlab软件在分形几何上的应用

以Koch曲线和塞尔平斯基三角形为例,介绍了Ma tlab软件在分形几何方面,对不规则图形进行直观描绘的方法。     

杀菌剂异螺环-4-烯-2,3-5''''-氯-吲哚的合成

研究了以薯蓣皂素(diosgenin)为原料,根据活性叠加原理,在分子中引入一个新的活性基团吲哚环,合成了全新化合物异螺环-4-烯-2,3-5'-氯-吲哚.杀菌药效试验结果表明:所设计的全新目标化合物具有原料所没有的杀菌活性.     

电荷灵敏放大器不用反馈高值电阻的新方法

本文提出了一种电荷灵敏放大器不用反馈高值电阻的新方法。对这种方法作了电路分析以及对实际电路的测量结果作了介绍。     

石匣小流域坡地水土流失监测系统的建立及应用

以石匣小流域为坡地水土流失监测试点,以遥感及地理信息系统技术为手段,以坡地径流小区定位观测为依据,建立石匣小流域坡地水土流失监测系统,定位、定性、定量监测各种坡地类型的水土流失量、污染物流失量,为水土流失监测预报提供数据,为全市山区水土流失监测预报工作提供经验及方法,为制定水土流失防治方针政策及水土流失生态环境建设提供依据.     

10MeV中子引起的~（238）U，~（209）Bi，Fe和~9Be的次级中子

１０ＭｅＶ中子引起的￣（２３８）Ｕ，￣（２０９）Ｂｉ，Ｆｅ和￣９Ｂｅ的次级中子双微分截面测量祁步嘉，唐洪庆，周祖英，周陈维，沈冠仁，柯尊建，孙振强，夏海鸿（中国原子能科学研究院核物理所，北京２７５－４６信箱，１０２４１３）次级中子双微分截面是核工程设...     

抽取式文本摘要新闻文本分类

采取TF-IDF、LDA、位置权重指派与MMR相结合的方式,对不同的句子分配不同的权重.结合Word Embedding模型,分析了在BERT、RoBERTa-wwm-ext等模型测试的分类效果.