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排序方式: 共有636条查询结果,搜索用时 31 毫秒
41.
Nor Azah Yusof Nor Dyana Zakaria Nor Amirah Mohd Maamor Abdul Halim Abdullah Md. Jelas Haron 《International journal of molecular sciences》2013,14(2):3993-4004
Molecularly imprinted polymers (MIPs) were prepared by bulk polymerization in acetonitrile using 2,4-dinitrophenol, acrylamide, ethylene glycol dimethacrylate, and benzoyl peroxide, as the template, functional monomer, cross-linker, and initiator, respectively. The MIP membrane was prepared by hybridization of MIP particles with cellulose acetate (CA) and polystyrene (PS) after being ground and sieved. The prepared MIP membrane was characterized using Fourier transform infrared spectroscopy and scanning electron microscopy. The parameters studied for the removal of 2,4-dinitrophenol included the effect of pH, sorption kinetics, and the selectivity of the MIP membrane. Maximum sorption of 2,4-nitrophenol by the fabricated CA membrane with MIP (CA-MIP) and the PS membrane with MIP (PS-MIP) was observed at pH 7.0 and pH 5.0, respectively. The sorption of 2,4-dinitrophenol by CA-MIP and PS-MIP followed a pseudo–second-order kinetic model. For a selectivity study, 2,4-dichlorophenol, 3-chlorophenol, and phenol were selected as potential interferences. The sorption capability of CA-MIP and PS-MIP towards 2,4-dinitrophenol was observed to be higher than that of 2,4-dichlorophenol, 3-chlorophenol, or phenol. 相似文献
42.
The electrokinetic chromatographic separation of a series of inorganic and organic anions was achieved by utilizing an electrolyte system comprising a cationic soluble polymer (poly(diallydimethylammonium chloride, PDDAC) and a neutral beta-cyclodextrin (beta-CD) as pseudostationary phases. The separation mechanism was a combination of electrophoresis, ion-exchange (IE) interactions with PDDAC, and hydrophobic interactions with beta-CD. The extent of each chromatographic interaction was independently variable, allowing for control of the separation selectivity of the system. IE interactions could be varied by changing either the PDDAC concentration or the concentration of a competing ion (e.g., chloride) in the BGE, while the hydrophobic interactions could be varied by changing the concentration of beta-CD. The separation system was very robust, with the reproducibility of the migration times being <0.7% RSD. A mathematical model that predicted the mobilities of analytes under varying experimental conditions was derived and was shown to give good correlation (r2 = 0.9804) between predicted and experimental migration times. Parameters derived from the model were in good agreement with the ion-exchange and hydrophobic characteristics of the analytes. The model was also applied successfully to the optimization of conditions for the separation of a mixture of analytes or for conditions under which particular analytes migrated in a desired order. That is, the opportunity to tune the separation selectivity has been demonstrated. 相似文献
43.
44.
Plasticized polymer electrolytes composed of poly(methylmethacrylate) (PMMA) as the host, propylene carbonate (PC) or ethylene carbonate (EC) as a plasticizer and LiX (X: CF3SO3− or N(CF3SO2)2−) as a salt were prepared by the solution cast technique. Impedance spectroscopy was performed in the temperature range between 303 and 383 K. In this paper, we report the electrical properties of polymer electrolytes with different lithium salts and plasticizers. The polymer electrolytes investigated exhibited high ionic conductivity at room temperature in the range of 10− 6 to 10− 4 S cm− 1. The temperature dependence studies showed that the samples were ionic conductors and seemed to obey the Vogel-Tamman-Fulcher (VTF) rule. FTIR spectroscopy studies confirmed the polymer-salt interaction. 相似文献
45.
Zhaofei Wen Guofan Shao Zakaria A. Mirza Jilong Chen Mingquan Lü 《International journal of remote sensing》2013,34(16):4195-4212
The presence of shadows in optical satellite images limits the application of remote-sensing technology. It is important to restore shadow radiance information for improving information extraction from remote-sensing images. Several shadow-restoration methods have been developed using complex statistical relationships between shadowed areas and their nearby sunlit areas. In this study, a simple shadow-restoration approach was proposed based on the surface reflectance equality relationship (RER) under the assumption that the surface reflectance of a feature in the shadowed area is equal to that of the same feature in the nearby sunlit area. This approach reduces the number of parameters, thus reducing the error propagated by the uncertainties of extra parameters. The new RER method was tested with three multispectral images with different shadow features. By comparing RER with the widely used mean and variance transformation, the RER was shown to be capable of restoring the image colours, texture, tone, and brightness of the shadowed areas to a visually satisfactory level. Quantitative analysis suggests that RER can help to restore the reflectance of shadow features accurately and has robust performance for a variety of land-surface types. Moreover, RER can be effectively used to restore the spectral shape information of shadow features, which is particularly important when applying RER to the restoration of multispectral imagery for the purpose of image classification. 相似文献
46.
Quan Z. Sheng Sherali Zeadally Zongwei Luo Jen-Yao Chung Zakaria Maamar 《Information Systems Frontiers》2010,12(5):485-490
After over a half century of development, radio-frequency identification (RFID) is beginning to move into mainstream applications for automatic identification. RFID is widely seen today as one of the key enabling technologies of the “Internet of Things”. However, many challenges still need to be addressed before we can fully benefit from this nascent and ubiquitous technology. In this paper, we present the state of the art of RFID technology and discuss the challenges and open issues in developing next generation RFID applications. 相似文献
47.
H. Md. Azamathulla Chun Kiat Chang Aminuddin Ab. Ghani Junaidah Ariffin Nor Azazi Zakaria Zorkeflee Abu Hasan 《Journal of Hydro》2009,3(1):35-44
A total of 346 sets of bed-load data obtained from the Kinta River, Pari River, Kerayong River and Langat River were analyzed using four common bed-load equations. These assessments, based on the median sediment size (d50), show that the existing equations were unable to predict the measured bed load accurately. All existing equations over-predicted the measured values, and none of the existing bed-load equations gave satisfactory performance when tested on local river data. Therefore, the present study applies a new soft computing technique, i.e. an adaptive neuro-fuzzy inference system (ANFIS), to better predict measured bed-load data. Validation of the developed network (ANFIS) was performed using a new set of bed-load data collected at Kulim River. The results show that the recommended network can more accurately predict the measured bed-load data when compared to an equation based on a regression method. 相似文献
48.
Oi Wei Mak Nursyafikah Seman Nor Hamizah Harun Rusnah Syahila Duali Hussen Nasrulzamani Mohd Rodzi Thorsten Heidelberg 《Journal of surfactants and detergents》2015,18(6):973-980
A biantennary surfactant based on a synthetic C16‐maltoside was chosen to prepare vesicles for a potential vesicular drug delivery system. The synthesis comprised of three stages: Initial synthesis of β‐d ‐maltose octaacetate was followed by glycosidation of 2‐hexyl‐decanol and final glycolipid deacetylation. Both α‐ and β‐anomers were prepared and their anomeric purity was evaluated by 1H NMR. Owing to the low water solubility of the glycolipid, addition of ionic co‐surfactants was believed to promote the surfactant distribution, thus leading to smaller and more uniform vesicles. The assembly behavior of the surfactant systems was studied by contact penetration under an optical polarizing microscope, while interfacial properties were determined by surface tension measurements. Vesicles were prepared by injection of an ethanolic solution into bulk water and investigated by dynamic light scattering and field emission scanning electron microscopy. Contact of the surfactant mixtures with water indicated a high tendency to exhibit the lamellar phase and confirmed the expected low molecular solubility. These findings suggest a potential of the surfactant to form stable vesicles. Injection of an ethanolic surfactant solution into bulk water gave sub‐micrometer sized vesicles with a narrow size distribution. Application of ionic co‐surfactants reduced the vesicle size. In particular ~20 % of anionic SDS proved highly effective, lowering the vesicle size by nearly one decade, thus accessing nano‐sized vesicles. Encapsulation of a water‐soluble drug was achieved in a 76 ± 10 % efficiency. 相似文献
49.
C.Y. Haw F. Mohamed C.H. Chia S. Radiman S. Zakaria N.M. Huang H.N. Lim 《Ceramics International》2010
Magnetite (Fe3O4) nanoparticles prepared using hydrothermal approach were employed to study their potential application as magnetic resonance imaging (MRI) contrast agent. The hydrothermal process involves precursors FeCl2·4H2O and FeCl3 with NaOH as reducing agent to initiate the precipitation of Fe3O4, followed by hydrothermal treatment to produce nano-sized Fe3O4. Chitosan (CTS) was coated onto the surface of the as-prepared Fe3O4 nanoparticles to enhance its stability and biocompatible properties. The size distribution of the obtained Fe3O4 nanoparticles was examined using transmission electron microscopy (TEM). The cubic inverse spinel structure of Fe3O4 nanoparticles was confirmed by X-ray diffraction technique (XRD). Fourier transform infrared (FTIR) spectrum indicated the presence of the chitosan on the surface of the Fe3O4 nanoparticles. The superparamagnetic behaviour of the produced Fe3O4 nanoparticles at room temperature was elucidated using a vibrating sample magnetometer (VSM). From the result of custom made phantom study of magnetic resonance (MR) imaging, coated Fe3O4 nanoparticles have been proved to be a promising contrast enhanced agent in MR imaging. 相似文献
50.
Jatropha curcas L. has recently been hailed as the promising feedstock for biodiesel production as it does not compete with food sources. Conventional production of biodiesel from J. curcas L. seeds involve two main processing steps; extraction of oil and subsequent esterification/transesterification to fatty acid methyl esters (FAME). In this study, the feasibility of in situ extraction, esterification and transesterification of J. curcas L. seeds to biodiesel was investigated. It was found that the size of the seed and reaction period effect the yield of FAME and amount of oil extracted significantly. Using seed with size less than 0.355 mm and n-hexane as co-solvent with the following reaction conditions; reaction temperature of 60 °C, reaction period of 24 h, methanol to seed ratio of 7.5 ml/g and 15 wt% of H2SO4, the oil extraction efficiency and FAME yield can reached 91.2% and 99.8%, respectively. This single step of reactive extraction process therefore can be a potential route for biodiesel production that reduces processing steps and cost. 相似文献