Optimum Arrangement of Tube Coil in Radiation Type of Tubular Furnace

Tube coil arrangement dominantly influences the thermal-hydraulics characteristics of furnace and its economy. The presented method is based on standard long-used design methods (Lobo-Evans method, Belokon method). It is shown how these standard global design methods can be (for common-operating conditions) suitably generalized and simplified. It allows (for the purpose of optimum design of coil arrangement) to arrange the basic heat transfer equation for radiant chamber. In connection with investment cost relations for individual furnace subsystems (tube coil, burners, lining, etc.) and operating cost relations (fuel consumption, fluid pumping cost), the final objective function of total cost can be obtained. This objective function then allows finding the optimum coil arrangement from minimum total cost point of view. Moreover, the obtained results allow one to formulate some general recommendations suitable for furnace designers. The developed method can be used for the individual solution of a radiation-type of tubular furnaces and also for the first (preliminary) design stage usually connected with a proposal for the customer when only basic process and furnace design data are known. The developed method can be also used for the effective solution of the integration of radiation furnaces into processes. The application of the developed method is demonstrated through a case study—the optimum arrangement of coil in a gas plant regeneration furnace.     

Compound Size Effect in Composite Beams with Softening Connectors.?I: Energy Approach

The size effect on the nominal strength of steel-concrete composite beams caused by shear failures of connectors such as welded studs is analyzed by two different approaches: (1) In this paper (Part I) by a fracture type analysis of the energy release caused by propagation of the zone of failed connectors along the beam; and (2) in a companion paper (Part II) by a direct solution of the load-deflection diagrams from the differential equations of beam bending theory. The former can capture the large size asymptotic size effect and yields simple formulas suitable for design, whereas the latter can provide the solution for small beam sizes for which the connector failure zone is not much shorter than the span. The force-slip diagram of the connectors exhibits postpeak softening, which engenders an energetic size effect on the nominal strength of the connector. If the connectors are geometrically scaled with the beam, the size effect in the shear failure of connectors (mesoscale) is superimposed on the size effect due to propagation of the zone of connector failures along the beam (macroscale), producing in the beam as a whole a compound size effect that is stronger than in linear elastic failure mechanics. If the connector sizes and the interface area per connector are not scaled with the overall dimensions of the composite beam, the size effect law proposed by Ba?ant in 1984 is applicable. Comparisons with available test results are presented in Part II.     

Fracture Mechanics of ASR in Concretes with Waste Glass Particles of Different Sizes

Using waste glass as an aggregate in concrete can cause severe damage because of the alkali-silica reaction (ASR) between the alkali in the cement paste and the silica in the glass. Recent accelerated 2-week tests, conducted according to ASTM C 1260, revealed that the damage to concrete caused by expansion of the ASR gel, which is manifested by strength reduction, depends in these tests strongly on the size of the glass particles. As the particle size decreases, the tensile strength first also decreases, which is expected because of the surface-to-volume ratio of the particles, and thus their chemical reactivity increases. However, there exists a certain worst (pessimum) size below which any further decrease of particle size improves the strength, and the damage becomes virtually nonexistent if the particles are small enough. The volume dilatation due to ASR is maximum for the pessimum particle size and decreases with a further decrease of size. These experimental findings seem contrary to intuition. This paper proposes a micromechanical fracture theory that explains the reversal of particle size effect in the accelerated 2-week test by two opposing mechanisms: (1) The extent of chemical reaction as a function of surface area, which causes the strength to decrease with a decreasing particle size; and (2) the size effect of the cracks produced by expansion of the ASR gel, which causes the opposite. The pessimum size, which is about 1.5 mm, corresponds to the case where the effects of both mechanisms are balanced. For smaller sizes the second mechanism prevails, and for sizes <0.15 mm no adverse effects are detectable. Extrapolation of the accelerated test (ASTM C 1260) to real structures and full lifetimes will require coupling the present model with the modeling of the reaction kinetics and diffusion processes involved.     

Continuous Relaxation Spectrum for Concrete Creep and its Incorporation into Microplane Model M4

Efficient numerical finite-element analysis of creeping concrete structures requires the use of Kelvin or Maxwell chain models, which are most conveniently identified from a continuous retardation or relaxation spectrum, the spectrum in turn being determined from the given compliance or relaxation function. The method of doing that within the context of solidification theory for creep with aging was previously worked out by Ba?ant and Xi in 1995 but only for the case of a continuous retardation spectrum based on the Kelvin chain. The present paper is motivated by the need to incorporate concrete creep into the recently published Microplane Model M4 for nonlinear triaxial behavior of concrete, including tensile fracturing and behavior under compression. In that context, the Maxwell chain is more effective than the Kelvin chain, because of the kinematic constraint of the microplanes used in M4. The paper shows how to determine the continuous relaxation spectrum for the Maxwell chain, based on the solidification theory for aging creep of concrete. An extension to the more recent microprestress-solidification theory is also outlined and numerical examples are presented.     

Cohesive Crack Model with Rate-Dependent Opening and Viscoelasticity: II. Numerical Algorithm, Behavior and Size Effect

In the preceding companion paper (Bažant and Li, 1995), the solution of an aging viscoelastic law was structure containing a cohesive crack with a rate-dependent stress-displacement softening law was reduced to a system of one-dimensional integro-differential equations involving compliance functions for points on the crack faces and the load point. An effective numerical algorithm for solving these equations, which dramatically reduces the computer time compared to the general two-dimensional finite element solution, is presented. The behavior of the model for various loading conditions is studied. It is shown that the model can closely reproduce the available experimental data from fracture tests with different loading rates spanning several orders of magnitude, and tests with sudden changes of the loading rate. Influence of the loading rate on the size effect and brittleness is also analyzed and is shown to agree with experiments. This revised version was published online in July 2006 with corrections to the Cover Date.     

Effect of noble metals in the decomposition of nitrous oxide over Fe-ferrierites

The decomposition of nitrous oxide was studied over Fe-ferrierite, Me-ferrierites and Fe/Me-ferrierites (Me: Pt, Rh and Ru). Flow as well as batch experiments were carried out and showed a synergy between Fe and Me ions. Ions of noble metals in Fe-ferrierite increased the catalytic activity in the sequence Pt < Rh ≅ Ru. Addition of NO substantially decreased the decomposition of N₂O over Rh/ferrierite and Ru/ferrierite, but not over bimetallic ferrierites. NO _x species created during the decomposition of nitrous oxide alone as well as with addition of NO, and employment of nitrous oxide labeled with ¹⁸O allowed us to assume a changing decomposition mechanism in the presence of Me ions in Fe-ferrierites.     

Mechanics of Progressive Collapse: Learning from World Trade Center and Building Demolitions

Progressive collapse is a failure mode of great concern for tall buildings, and is also typical of building demolitions. The most infamous paradigm is the collapse of the World Trade Center towers. After reviewing the mechanics of their collapse, the motion during the crushing of one floor (or group of floors) and its energetics are analyzed, and a dynamic one-dimensional continuum model of progressive collapse is developed. Rather than using classical homogenization, it is found more effective to characterize the continuum by an energetically equivalent snap-through. The collapse, in which two phases—crush-down followed by crush-up—must be distinguished, is described in each phase by a nonlinear second-order differential equation for the propagation of the crushing front of a compacted block of accreting mass. Expressions for consistent energy potentials are formulated and an exact analytical solution of a special case is given. It is shown that progressive collapse will be triggered if the total (internal) energy loss during the crushing of one story (equal to the energy dissipated by the complete crushing and compaction of one story, minus the loss of gravity potential during the crushing of that story) exceeds the kinetic energy impacted to that story. Regardless of the load capacity of the columns, there is no way to deny the inevitability of progressive collapse driven by gravity alone if this criterion is satisfied (for the World Trade Center it is satisfied with an order-of-magnitude margin). The parameters are the compaction ratio of a crushed story, the fracture of mass ejected outside the tower perimeter, and the energy dissipation per unit height. The last is the most important, yet the hardest to predict theoretically. It is argued that, using inverse analysis, one could identify these parameters from a precise record of the motion of floors of a collapsing building. Due to a shroud of dust and smoke, the videos of the World Trade Center are only of limited use. It is proposed to obtain such records by monitoring (with millisecond accuracy) the precise time history of displacements in different modes of building demolitions. The monitoring could be accomplished by real-time telemetry from sacrificial accelerometers, or by high-speed optical camera. The resulting information on energy absorption capability would be valuable for the rating of various structural systems and for inferring their collapse mode under extreme fire, internal explosion, external blast, impact or other kinds of terrorist attack, as well as earthquake and foundation movements.     

Mathematical Modeling of Drying Processes of Selected Fruits and Vegetables

This study investigates the behavior of fruit and vegetable samples during drying. The experimental data are fitted to several different thin-layer drying models. Regression analysis is used to determine model parameters, while statistical indicators serve to evaluate the goodness of fit. The power function model gives the best fit for all examined samples. Based on this model, different drying and heat storage technologies can be combined to ensure that the required residual moisture content of an agricultural product is reached. It is demonstrated on the case of a specific Togolese processing plant that under favorable conditions, fossil fuel consumption can be decreased by 33 %.     

A New,Thorough Look on Unusual and Neglected Group III-VI Compounds Toward Novel Perusals

The attention on group III-VI compounds in the last decades has been centered on the optoelectronic properties of indium and gallium chalcogenides. These outstanding properties are leading to novel advancements in terms of fundamental and applied science. One of the advantages of these compounds is to present laminated structures, which can be exfoliated down to monolayers. Despite the large knowledge gathered toward indium and gallium chalcogenides, the family of the group III-VI compounds embraces several other noncommon compounds formed by the other group III elements. These compounds present various crystal lattices, among which a great deal is offered from layered structures. Studies on aluminium chalcogenides show interesting potential as anodes in batteries and as semiconductors. Thallium (Tl), which is commonly present in the +1 oxidation state, is one of the key components in ternary chalcogenides. However, binary Tl–Q (Q = S, Se, Te) systems and derived films are still studied for their semiconducting and thermoelectric properties. This review aims to summarize the biggest features of these unusual materials and to shed some new light on them with the perspective that in the future, novel studies can revive these compounds in order to give rise to a new generation of technology.