An analysis of students’ spontaneous computer-mediated help seeking: A step toward the design of ecologically valid supporting tools

This study analyzes middle school students’ spontaneous mathematics-related help-seeking behavior, in view of making ecologically valid recommendations for the design of supporting tools or “help systems”. Our aim was to investigate the content of students’ help-seeking messages – Are there different forms of help-seeking messages and do they evolve with age? We used the archives of a French forum that provides students with free individualized help in mathematics. The data consisted of 206 messages sent by French middle school students over a period of 42 months. The constituent categories of the messages were identified. The results showed that not all middle school students use the same help-seeking “format”. Compared to sixth graders, ninth graders wrote messages containing more constituent categories, i.e., they provided the online expert with more kinds of information. A detailed analysis of the categories further showed that older students’ messages more often contained explicit help requests and contextual information than did younger students’ messages. Thus, the messages of the oldest students (age 15) were both cognitively more understandable and socially more acceptable than those of the youngest students (age 11). The interpretation of these findings and their implications for designing help systems are discussed.     

A survey of Irish fruit and vegetable waste and by-products as a source of polyphenolic antioxidants

In this study, fruit and vegetable by-product and waste sources in Ireland were tested for their antioxidant activity and polyphenol content. The highest levels of antioxidants measured by both ferric reducing antioxidant power (FRAP) and diphenyl-picrylhydrazyl (DPPH) assays, were detected in whole kiwifruit. Of the vegetable by-products, broccoli stems showed the best antioxidant potential. The level of polyphenols as assessed by the Folin–Ciocalteu Reagent (FCR) was significantly correlated with the level of polyphenols by HPLC–DAD (r = 0.93). The level of polyphenols assessed by HPLC–DAD was not significantly correlated with the antioxidant assays. Apple pomace and vegetable by-products were found to be good sources of both polyphenols and antioxidants and due to their abundance may be exploitable resources to use as food ingredients.     

Efficiency and stability of transition metal electrocatalysts for the hydrogen evolution reaction using ionic liquids as electrolytes

Different electrodes (nickel, molybdenum, and iron alloys containing chromium, manganese, and nickel) were tested as cathodes for the hydrogen evolution reaction (HER) using 1-n-butyl-3-methylimidazolium tetrafluoroborate (BMI.BF₄) ionic liquid (IL) as the electrolyte. HERs were conducted at room temperature, at a cathodic potential of −1.7 V (PtQRE) using 10 vol.% aqueous BMI.BF₄ solutions. Reactions performed in a thermostated Hoffman cell gave current densities between 14.6 and 77.5 mA cm⁻² and efficiencies in the range 97.0–99.2%. Mo electrocatalysts in IL have been shown to be better than Pt, contrary to the classic behavior observed in an aqueous KOH medium. The electrochemical properties of molybdenum, as well as its resistance to corrosion (studied by Tafel plots and observed using SEM) indicate the potential use of this material as a cathode in an IL medium, which can lead to many attractive technological applications.     

Low-frequency scattering from perfectly conducting spheroidal bodies in a conductive medium with magnetic dipole excitation

Inductive electromagnetic means that are currently employed in the exploration of the Earth’s subsurface and embedded voluminous bodies often call for an intensive use, primary at the modeling stage and later on at the inversion stage, of analytically demanding tools of field calculation. Under the aim of modeling implementation, this contribution is concerned with some interesting aspects of the low-frequency interaction of arbitrarily orientated (i.e. three-dimensional) time-harmonic magnetic dipoles, with 3-D perfectly conducting spheroidal bodies embedded in an otherwise homogeneous conductive medium. For many practical applications involving buried obstacles such as Earth’s subsurface electromagnetic probing at low-frequency or any other physical cases (e.g. geoelectromagnetics), non-axisymmetric spheroidal geometry approximates sufficiently such kind of metallic shapes. On the other hand, our analytical approach deals with prolate spheroids, since the corresponding results for the oblate spheroidal geometry can be readily obtained through a simple transformation. The particular physical model concerns a solid impenetrable (metallic) body under a magnetic dipole excitation, where the scattering boundary value problem is attacked via rigorous low-frequency expansions for the incident, scattered and total electric and magnetic fields in terms of positive integral powers of (ik), that is (ik)ⁿ for n ? 0, where k stands for the complex wavenumber of the exterior medium. The purpose of the modeling is to contribute to a simple yet versatile tool to infer information on an unknown body from measurements of the three-component electric and magnetic fields nearby. Our goal is to obtain the most important terms of the low-frequency expansions of the electromagnetic fields, that is the static (for n = 0) and the dynamic (n = 1, 2, 3) terms. In particular, for n = 1 there are no incident fields and thus no scattered ones, while for n = 0 the Rayleigh electromagnetic expression is easily obtained in terms of infinite series. Emphasis is given on the calculation of the next two non-trivial terms (at n = 2 and at n = 3) of the aforementioned fields. Consequently, those are found in closed form from exact solutions of coupled (at n = 2, to the one at n = 0) or uncoupled (at n = 3) Laplace equations and they are given in compact fashion, as infinite series expansions for n = 2 or finite forms for n = 3. Nevertheless, the difficulty of the Poisson’s equation that has to be solved for n = 2 is presented, whereas our analytical approach demands the use of the well-known cut-off method in order to obtain an analytical closed solution. Finally, this research adds useful reference results to the already ample library of scattering by simple shapes using analytical methods.     

Pulsed Laser Deposition of Zr1-xCexO2 and Ce1-xLaxO2-x/2 for Buffer Layers and Insulating Barrier in Oxide Heterostructures

We have studied the pulsed laser deposition (PLD) of Zr_1-xCexO₂ and Ce_1-xLa_xO₂-x/2 initially to grow buffer layers for perovskite films deposited on Si, LaAlO₃, SrTiO₃ and MgO and then to produce tunneling barriers for cuprate or manganite heterostructures. On (1 0 0) Si, the deposition of Zr_1-xCexO₂ (x = 0.12) produces a smooth epitaxial layer (R _RMS = 0.25/1m²), which allows the further deposition of high quality YBa₂Cu₃O₇ (Tc 88 K) and La_0.7Sr_0.3MnO₃ films. On the other hand, the use of Ce_1-xLa_xO_2-x/2 (0le" align="MIDDLE" BORDER="0"> x le" align="MIDDLE" BORDER="0"> 0.4) makes it possible to match the YBa₂Cu₃O₇ and La_0.7Sr_0.3MnO₃ layers to various substrates. The buffer layers are epitaxially grown with a 45° rotation of the in-plane axes with respect to those of the substrate, and the smoothness is high (R _RMS = 0.25/1m²). In the case of an ultra-thin barrier (2.5 nm) of Ce_1-xLa_xO_2-x/2 sandwiched in a La_0.7Sr_0.3MnO₃, the out-of-plane mismatch of 2 induces distortions at the interface steps, which propagate into the topmost La_0.7Sr_0.3MnO₃ layer. This is in contrast to the case of SrTiO₃ barriers where an ideal crystal continuity in the growth direction is observed.     

Numerical studies in high Reynolds number aerodynamics

Two numerical approaches are presented for the computation of viscous compressible flows at high Reynolds' numbers. In the first approach, named global approach, the whole flow field, which includes viscous and inviscid regions, is determined as the solution of a single set of equations, which may be the full Navier-Stokes equations, or some approximate form of these equations. The second approach, named coupling approach, consists in solving two different sets of equations in their respective domains simultaneously; one of the two sets governs an inviscid flow whose boundary conditions are provided by the viscous effects, determined by the other set.The discussion of the global approach is centred on two particular features of the finite-difference method used: a discretization technique, directly in the physical plane with arbitrary meshes: and a mesh adaptation technique, which combines a coordinate transformation to fit the mesh system to particular lines in the flow, and a technique of dichotomy for mesh refinement. Numerical results are presented for an axisymmetric compression corner and a shock-boundary layer interaction on a flat plate, both in supersonic regime, and for a transonic nozzle flow.For the coupling approach, emphasis is given firstly to the improvement resulting from an interacting analysis where the viscous and inviscid computations are matched, and not only patched. It is shown that the parabolic problems associated with simple viscous theories are always replaced by elliptic problems, even for supersonic flows, and that “supercritical interactions” or “critical points”, as defined by Crocco-Lees, are removed. Secondly, a new coupling method, fully automatized and capable of solving directly a well-posed problem for supersonic flow, is illustrated by examples involving shock wave-boundary layer interactions and reverse flow bubbles; they concern flows over symmetrical transonic airfoils and supersonic compression ramps.     

EUROPEAN BREWERY CONVENTION—HAZE AND FOAM GROUP AMINO ACID COMPOSITION OF THE BEER HAZE COMPONENTS RETAINED BY INORGANIC ADSORBENTS

The amino acid composition of the substances retained by bentonite, Stabifix and Stabiquick on addition to filtered Pilsner beers was determined by ion-exchange chromatography. The results indicate large differences between the 3 adsorbents. Stabifix is the most selective, for the amino acid composition of the adsorbed substances is very similar to that of the chill hazes of the E.B.C. The prolamin content is high. Bentonite adsorbs proportionally more salt-soluble proteins. Stabiquick, in agreement with its composition, is less selective than Stabifix, but adsorbs proportionally more prolamins than bentonite. The difference between the adsorbents was also confirmed by solubility measurements in the solvents most commonly used in this laboratory for the extraction of the prolamins. The desorption of the nitrogenous substances decreases from Stabifix to Stabiquick and from Stabiquick to bentonite. A comparison by Sephadex G-25 and G-50 chromatography of the beers before and after treatment indicated that in addition to the nitrogenous substances other components are retained by the adsorbents.     

Fast Theta-Subsumption with Constraint Satisfaction Algorithms

Relational learning and Inductive Logic Programming (ILP) commonly use as covering test the -subsumption test defined by Plotkin. Based on a reformulation of -subsumption as a binary constraint satisfaction problem, this paper describes a novel -subsumption algorithm named Django,¹ which combines well-known CSP procedures and -subsumption-specific data structures. Django is validated using the stochastic complexity framework developed in CSPs, and imported in ILP by Giordana et Saitta. Principled and extensive experiments within this framework show that Django improves on earlier -subsumption algorithms by several orders of magnitude, and that different procedures are better at different regions of the stochastic complexity landscape. These experiments allow for building a control layer over Django, termed Meta-Django, which determines the best procedures to use depending on the order parameters of the -subsumption problem instance. The performance gains and good scalability of Django and Meta-Django are finally demonstrated on a real-world ILP task (emulating the search for frequent clauses in the mutagenesis domain) though the smaller size of the problems results in smaller gain factors (ranging from 2.5 to 30).