以水玻璃和硫酸铝为原料合成T型沸石的研究

以工业水玻璃和硫酸铝为原料,于K2O-Na2O-SiO2-Al2O3-H2O体系中水热合成制得不同晶粒度的T型沸石.晶化温度在85～135℃可得到晶相纯的T型沸石;搅拌晶化能有效减小T型沸石的晶粒度,但搅拌速度在200～800 r/min内对晶粒大小的影响不明显;凝胶n(SiO2)/n(Al2O3)在16～32可合成出结晶度高、晶相纯的T型沸石,但大于32时晶化产物中出现钙十字沸石杂晶;凝胶n(SiO2)/n(Al2O3)改变对T型沸石产物硅铝比基本无影响.水玻璃合成体系晶化诱导期短.产物中n(K+)/n(Na+)比值远大于起始凝胶中两者的比值,这可能是由于钾离子在T型沸石晶化中起主要的结构导向作用.     

甲磺酸伊马替尼的合成

以4-甲基-3-硝基苯胺为起始原料,经过缩合、还原、环合等反应制得抗肿瘤药物甲磺酸伊马替尼。并分别讨论了采用无水碳酸钾代替二异丙基乙胺、水合肼和普通催化剂代替铂炭催化剂以及采用异戊醇作为溶剂的优点。最终反应总收率超过50%,用高效液相色谱分析产品纯度在99.5%以上。     

新型有机磷系阻燃剂的热稳定性

利用STA490C热分析仪对8种新型有机磷系阻燃剂的热失重过程进行测定和对比,结果表明磷杂螺环阻燃剂3,9-二羟基-2,4,8,10-四氧杂-3,9-二磷杂螺环[5,5]十一烷-3,9-二氧化物和苯基次膦酸类阻燃剂4-甲氧基羟甲基苯基次膦酸热稳定性较好。     

基于活动区域的移动无线传感器网络路由协议

为了解决移动无线传感器网络中能量效率问题,提出了一种基于活动区域的移动无线传感器网络（WSN）路由协议。本方法使用源和sink节点相对位置来形成路由的活动区域,网络中的移动节点使用睡眠唤醒模式来节约能源。移动向量信息（如当前位置、方向和速度）以及节点的剩余能量,用于选择能够提供最大连接保留时间的邻居,移动向量信息也被用来唤醒活动区域中的移动节点。实验表明,与其他路由协议进行比较,该方法在分组传输过程中具有更高的可靠性。     

PbNb2O6基压电陶瓷的高温介电性能研究

本文在PbNb2O6基础上采用Ba^2＋取代Pb^2＋离子,并通过添加Cr2O3、Y2O3、Sm2O3、Nd2O3和CeO2等氧化物进行掺杂改性,研究不同掺杂剂对PbNb2O6陶瓷材料结构的影响,寻找提高压电性能及居里温度的途径.试验结果表明,掺杂后的偏铌酸铅显微结构发生了变化,适量的掺杂可获得压电性能和工艺稳定性能很好,且居里温度较高（420℃～600℃）的改性PbNb2O6系压电陶瓷,可分别满足350℃和500℃以上高温应用环境的要求.     

A GPU-based parallel method for evolutionary tree construction

Evolutionary trees are widely applied in various applications to show the inferred evolutionary relationships among species or entities. Neighbor-Joining is one solution for data-intensive and time-consuming evolutionary tree construction, with polynomial time complexity. However, its performance becomes poorer with the growth of massive datasets. Graphics Processing Units (GPUs) have brought about new opportunities for these time-consuming applications. Based on its high efficiency, a GPU-based parallel Neighbor-Joining method is proposed, and two efficient parallel mechanisms, data segmentation with asynchronous processing and the minimal chain model with bitonic sort, are put forward to speed up the processing. The experimental results show that an average speedup of 25.1 is achieved and even approximately 30 can be obtained with a sequence dataset ranging from 16,000 to 25,000. Moreover, the proposed parallel mechanisms can be effectively exploited in some other high performance applications.     

LLDPE在振动剪切复合场中挤出成型的流变行为

利用振动剪切挤出装置研究了线性低密度聚乙烯(LLDPE)在振动与旋转剪切复合力场中挤出成型时的流变行为。结果表明:LLDPE熔体在复合力场中的表观黏度受振动频率、振幅、剪切速率等影响很大。在复合力场中存在使黏度降低最大的振动频率和剪切速率的最佳搭配。     

Thermooxidative degradation of natural rubber/clay composite

The clay is treated with a reducing agent and an acid so as to obtain a clay containing various metal components with a variable‐valence state. Then, the clay is coprecipitated with natural rubber (NR) latex to prepare a vulcanized NR/clay composite. The degradation process of the NR/clay composite under hot air condition was studied dynamically by using a Fourier transform infrared spectrometer attaching an in situ sample cell and was also investigated using the TGA method. The test result obtained from the infrared spectrometry indicated that under low decomposition temperature, the decomposition products of the test samples mainly are ethylene, low molecular olefinic hydrocarbon, and carbonyl compounds. As the decomposition temperature rises, the low molecular olefinic hydrocarbon content decreases, the olefine with longer chain is formed, and a lot of alkane decomposition products are formed at the same time. When the content of the metal components with a variable‐valence state in clay such as Cu, Mn, Co, and Fe increases, the oxidation products containing the carbonyl group, the olefinic hydrocarbon, and CO₂ in the decomposition product of the test sample also increase. The TGA result clearly shows a shoulder peak that appears by the side of the main peak on the DTG curve of NR/clay composite. With the increase in the content of metal components with variable‐valence state in clay, the initial degradation temperature of the test sample (T₀), the degradation peak temperature (T_p1), and the final degradation temperature (T_f1) in first‐stage reaction, as well as the degradation peak temperature (T_p2) and the last final degradation temperature (T_f) in second‐stage reaction of all the test samples more or less shift to the direction of low temperature; besides, the activation energy (E) of the reaction of the test samples more or less decreases. This means that the metal components with variable‐valence state promote the oxidative degradation of the clay–rubber masterbatch. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3809–3815, 2006     

云环境下基于Canopy聚类的FCM算法研究

FCM算法是目前广泛使用的算法之一。,针对FCM聚类质量和收敛速度依赖于初始聚类中心的问题,结合Canopy聚类算法能够粗略快速地对数据集进行聚类的优点,提出了一种基于Canopy聚类的FCM算法。该算法通过将Canopy算法快速获取到的聚类中心作为FCM算法的输入来加快FCM算法收敛速度。并在云环境下设计了其MapReduce化方案,实验结果表明,MapReduce化的基于Canopy聚类的FCM算法比MapReduce化的FCM聚类算法具有更好的聚类质量和运行速度。     

跨组织数据的软件成本估算方法

软件成本估算一直是软件项目管理的重要部分。经过半个多世纪的研究和工业实践,成本估算方法、模型得到了极大的丰富。这些方法、模型也衍生出了各种成本估算工具。但是,成本估算方法和模型的基础是历史项目数据。没有历史项目数据的公司和组织只能利用其他公司或组织的数据来进行自己项目的成本估算。如何利用跨组织数据进行有效的成本估算成为更具现实意义的问题。针对这一问题,提出了一种有效利用跨组织数据进行成本估算的方法,并通过实验说明了方法的有效性。