Thermal stability is a critical criterion for assessing the long-term stability of perovskite solar cells (PSCs). Here, it is shown that un-encapsulated co-evaporated MAPbI3 (TE_MAPbI3) PSCs demonstrate remarkable thermal stability even in an n-i-p structure that employs Spiro-OMeTAD as hole transport material (HTM). TE_MAPbI3 PSCs maintain over ≈95% and ≈80% of their initial power conversion efficiency (PCE) after 1000 and 3600 h respectively under continuous thermal aging at 85 °C. TE_MAPbI3 PSCs demonstrate remarkable structural robustness, absence of pinholes, or significant variation in grain sizes, and intact interfaces with the HTM, upon prolonged thermal aging. Here, the main factors driving TE_MAPbI3 stability are assessed. It is demonstrated that the excellent TE_MAPbI3 thermal stability is related to the perovskite growth process leading to a compact and almost strain-stress-free film. On the other hand, un-encapsulated PSCs with the same architecture, but incorporating solution-processed MAPbI3 or Cs0.05(MA0.17FA0.83)0.95Pb(I0.83Br0.17)3 as active layers, show a complete PCE degradation after 500 h under the same thermal aging condition. These results highlight that the control of the perovskite growth process can substantially enhance the PSCs thermal stability, besides the chemical composition. The TE_MAPbI3 impressive long-term thermal stability features the potential for field-operating conditions. 相似文献
Software‐defined networking (SDN) is a new network paradigm that is separating the data plane and the control plane of the network, making one or more centralized controllers to supervise the behaviour of the entire network. Different types of SDN controller software exist, and research dealing with the difficulties of consistently integrating these different controller types has mostly been declared future work. In this paper, the Domino framework is proposed, a pluggable SDN framework for managing heterogeneous SDN networks. In contrast to related work, the proposed framework allows research into SDN networks controlled by different types of SDN controllers attempting to standardize the northbound API of them. Domino implements a microservice plugin architecture where users can link different SDN networks to a processing algorithm. Such an algorithm allows for, eg, adapting the flows by building a pipeline using plugins that either invoke other SDN operations or generic data processing algorithms. The Domino framework is evaluated by implementing a proof‐of‐concept implementation, which is tested on the initial requirements. It achieves the modifiability and the interoperability with an average successful exchange ratio of 99.99%. The performance requirements are met for the frequently used commands with an average response time of 0.26 seconds, and the framework can handle at least 72 plugins simultaneously depending on the available amount of RAM. The proposed framework is evaluated by means of the implementation of a shortest path routing algorithm between heterogeneous SDN networks. 相似文献
A small percentage of the population is afflicted by what is called an orphan or a rare disease. All over the world, there are about several thousand of these diseases. When adding up together all the individuals who are affected, it amounts for up to 10% of the US population. Scientific works on these diseases are often poorly financed due to the lack of potential markets for a treatment, which means for patients and clinicians a very limited and scattered access to vital information. To contribute addressing this issue, we present in this paper a new software tool for automating the extraction of information related to rare diseases from scientific publications. More precisely, our contribution consists in a new method of extracting automatically symptoms of these diseases from research papers exploiting a Named Entity Recognition (NER) algorithm based on the numerical statistic Term Frequency - Inverse Document Frequency (TF-IDF). The proposed tool has been tested using PubMed Central (PMC) database.
This paper presents an active method for reducing the radar cross section (rcs) of a perfectly conducting cone-cylinder. The active elements are four microstrip patch antennas located symmetrically along the conecylinder axis. These elements radiate a field which permit the total scattered field in the direction of the receiver to be close to zero. In each time step, the hoarded system should determine some parameters of the incident wave: the incident direction, its frequency, amplitude, and phase. Then when antennas are fed with currents of suitable amplitude and phase, they radiate an electromagnetic field in the direction of the receiver that has the same amplitude but is opposite in phase compared to the scattered field, without feeding patches. Then the total field vanishes in the direction of the receiver. 相似文献
Today’s analog/RF design and verification face significant challenges due to circuit complexity, process variations and short
market windows. In particular, the influence of technology parameters on circuits, and the issues related to noise modeling
and verification still remain a priority for many applications. Noise could be due to unwanted interaction between the circuit
elements or it could be inherited from the circuit elements. In addition, manufacturing disparity influence the characteristic
behavior of the manufactured circuits. In this paper, we propose a methodology for modeling and verification of analog/RF
designs in the presence of noise and process variations. Our approach is based on modeling the designs using stochastic differential
equations (SDE) that will allow us to incorporate the statistical nature of noise. We also integrate the device variation
due to 0.18μm fabrication process in an SDE based simulation framework for monitoring properties of interest in order to quickly detect
errors. Our approach is illustrated on nonlinear Tunnel-Diode and a Colpitts oscillator circuits. 相似文献
Scanning Spreading Resistance Microscopy electro-mechanical nanocontacts are nowadays well understood and numerous influent parameters have been identified (bias, load, surface state sample, radius of curvature of the tip). Despite several simulation and modelization possibilities, calibration curves are required to ensure reliable electrical characterizations. In this paper, we bring, through nanostructural studies (Scanning Transmission Electron Microscopy) of surface state of both SSRM tips and doped silicon surface a new understanding of tip-sample interaction during SSRM measurements. As a result of load, a nanometric residual amorphous silicon layer was observed which thickness depends on applied force and might be due to as well to the plastic transformation (Si to β-tin phase) as to plough-effect residues resulting from the tip indentation into the sample. It appears thus important in a failure analysis process to find the best compromise between stable electrical SSRM response and sample/tip surface degradation. 相似文献
Label-free DNA detection plays a crucial role in developing point-of-care biochips. Capacitance detection is a promising technology for label-free detection. However, data published in literature often show evident time drift, large standard deviation, scattered data points, and poor reproducibility. To address these problems, mercapto-hexanol or similar alkanethiols are usually considered as blocking agents. The aim of the present paper is to investigate new blocking agents to further improve DNA probe surfaces. Data from AFM, SPR, florescence microscopy, and capacitance measurements are used to investigate new lipoate and ethylene-glycol molecules. The new surfaces offer further improvements in terms of diminished detection errors. Film structures are investigated at the nano-scale to justify the detection improvements in terms of probe surface quality. This study demonstrates the superiority of lipoate and ethylene-glycol molecules as blocking candidates when immobilizing molecular probes onto spot surfaces in label-free DNA biochip. 相似文献
In this paper we show that thiolated self-assembled monolayers (SAMs) can be used to anchor source–drain gold electrodes on the substrate, leading to excellent electrical performances of the organic field-effect transistor (OFET) on a par with those using a standard electrode process. Using an amorphous semiconductor and a gate dielectric functionalized with SAMs bearing different dipole moments, we demonstrate that we can tune the threshold voltage alone, while keeping nearly unchanged the other electrical properties (hole carrier mobility, Ion/Ioff ratio, subthreshold swing). This differs from previous studies for which SAMs functionalization induced significant changes in all the OFET electrical performances. This result opens doors to design organic circuits using reproducible amorphous semiconductor based OFETs for which only the threshold voltage can be tuned on demand. 相似文献
We report the use of a new precursor, trisneopentylgallium (NPG) for the growth of GaAs by atomic layer epitaxy (ALE). In
contrast to most other alkyl gallium precursors such as triethylgallium, which decompose via a β-hydride elimination mechanism,
this compound undergoes homolysis similar to that of trimethylgallium (TMGa), the normal choice as an ALE precursor. Clear
self-limiting growth behavior similar to that of TMGa was observed over a reasonably wide range of growth conditions (430–500°C).
Carbon incorporation was not significantly reduced compared with TMGa suggesting that the adsorbed neopentyl radicals undergo
decomposition to result in a methyl terminated surface identical to that obtained for growth with TMGa. 相似文献