竹红菌甲素和吲哚类化合物的相互作用

本文利用吸收光谱,荧光光谱研究了竹红菌甲素(以下简称HA)和吲哚类化合物的相互作用。发现HA和吲哚类化合物在一定条件下可形成复合物。这种复合物带有电荷转移性质。吲哚环上带有给电子取代基,位阻小,溶剂的极性大和溶液呈中性有利于该复合物的形成。     

选煤是控制煤中有毒元素排放的有效方法

<正> 因为环保涉及到安全利用煤炭问题,选煤对环境的贡献就变得更为重要。公众和环保方面更为关心的是有毒元素的排放。大量研究工作发现,元素砷、镉、铅、铜、汞、镍、硒、锰和锌对人类的健康和环境构成潜在的严重威胁。一、微量元素在煤中的含量在美国,煤炭里微量元素含量随着煤田不同有相当大的变化,包括北部大平原、洛基山脉、内陆盆地、海湾和阿巴拉契亚山脉煤田,表1列举了本文所涉及到的9种微量元素在各煤田的平均含量。表1 数据表明,锰和锌元素的含量最高,其次是铜、砷、铅和镍,再次是镉和硒,汞最少。一般说来,阿巴拉契亚山脉、内陆盆地和     

Metalloorganic solution deposition of ferroelectric PZT films

The metallo-organic solution deposition (MOSD or sol-gel) technique can be used for preparing lead zirconate titanate (PZT) ceramics with a wide range of compositions and crystal structures for electrooptical applications. Film morphology is affected by the stoichiometry of the film, hydrolysis and polymerization of the sol-gel solution, and thermal treatment of the deposited material. The lattice parameter decreases with the amount of titanium in the PZT, in agreement with ceramic data. A slight initial excess of lead in the coating solution is found to improve film morphology. Unlike traditional powder ceramic processing techniques, MOSD permits the growth of small uniform grains that are conducive to achieving consistent electronic and optical properties. Results show that the properties of films prepared by the MOSD process can be tailored to meet the needs of device applications.     

Volterra series modeling of spatial light modulators

We present a multiple-input, single-output, weakly nonlinear model of spatial light modulators by use of a second-order Volterra series and describe an experimental method to measure the nonlinear transfer functions by means of sinusoidal perturbation and synchronous detection with a lock-in amplifier. We also present an application of this method to a liquid-crystal light valve.     

Integrated capillary electrophoresis devices with an efficient postcolumn reactor in planar quartz and glass chips

Methods to fabricate planar capillary electrophoresis devices integrated with a postcolumn reactor in fused silica (quartz) and Pyrex glass are presented. Quartz is etched at ～1 μm/min with a 2.1:1 width-to-depth ratio using a Cr/Au/Cr metal mask and concentrated HF/HNO(3). On-chip postcolumn reaction of o-phthaldialdehyde (OPA) and amino acids gave theoretical plate numbers up to 83?000 and ～90 ms peak widths, corresponding to 14 plates/V and a 0.5 μm theoretical plate height. The reactor geometry caused only a 10% degradation in efficiency.