The influence of the initial acidity of HFER on the status of Co species and catalytic performance of CoFER and InCoFER in CH4-SCR-NO

The role of the initial acidity of ferrierite type zeolite on the status of cobalt and the catalytic activity of CoFER and InCoFER was investigated. Two FER zeolites were used: NH₄FER without any pretreatment (FER-1) and the same zeolite, dehydroxylated at 825 K (FER-2). Dehydroxylation removed most of the Si–OH–Al groups, therefore the resulting zeolite revealed practically no ion exchange capacity. The status of cobalt was followed by IR spectroscopy with probe molecules: CO (a probe for Co²⁺) and NO (a probe for Co³⁺). The introduction of cobalt by solid-state ion exchange produced divalent cobalt in exchange positions and in the form of oxide-like clusters, their respective concentration was determined by quantitative IR experiments of CO sorption. The amount of Co³⁺, present in CoFER-1 and InCoFER-1, was also determined. All these forms of cobalt were practically absent from CoFER-2 and InCoFER-2. The NO conversion and selectivity to N₂ of CoFER-2 in CH₄-SCR-NO was poor, indicating the essential role of the initial acidity of the ferrierite matrix on the formation of catalytically active Co species. The introduction of indium into CoFER only slightly increased the NO conversion and shifted the reaction path from NO₂ towards N₂ formation for FER-1, while greatly improved the catalytic performance of the FER-2 series.     

Inner-tube chirality determination for double-walled carbon nanotubes by scanning tunneling microscopy

Evidence for modified electronic structure in double-walled carbon nanotubes with respect to their individual inner and outer constituent single-walled nanotubes is provided by scanning tunneling microscopy and spectroscopy experiments. The contribution originating from the inner tube to the local density of states of the double-walled system was identified in agreement with previous theoretical calculations. Consequently, the chiral index for the inner tube was extracted based on the additional van Hove singularities present in the experimental tunneling spectra.     

Atmospheric correction for NO2 absorption in retrieving water-leaving reflectances from the SeaWiFS and MODIS measurements

The absorption by atmospheric nitrogen dioxide (NO2) gas in the visible has been traditionally neglected in the retrieval of oceanic parameters from satellite measurements. Recent measurements of NO2 from spaceborne sensors show that over the Eastern United States the NO2 column amount often exceeds 1 Dobson Unit (approximately 2.69x10(16) molecules/cm2). Our radiative transfer sensitivity calculations show that under high NO2 conditions (approximately 1x10(16) molecules/cm2) the error in top-of-atmosphere (TOA) reflectance in the blue channels of the sea-viewing wide field-of-view sensor (SeaWiFS) and moderate-resolution imaging spectroradiometer (MODIS) sensors is approximately 1%. This translates into approximately 10% error in water-leaving radiance for clear waters and to higher values (>20%) in the coastal areas. We have developed an atmospheric-correction algorithm that allows an accurate retrieval of normalized water-leaving radiances (nLws) in the presence of NO2 in the atmosphere. The application of the algorithm to 52 MODIS scenes over the Chesapeake Bay area show a decrease in the frequency of negative nLw estimates in the 412 nm band and an increase in the value of nLws in the same band. For the particular scene reported in this paper, the mean value of nLws in the 412 nm band increased by 17%, which is significant, because for the MODIS sensor the error in nLws attributable to the digitization error in the observed TOA reflectance over case 2 waters is approximately 2.5%.     

Influence of inorganic ions on MTBE degradation by Fenton's reagent

The effect of selected inorganic anions on the effectiveness of the Fenton advanced oxidative treatment of waters contaminated with methyl t-butyl ether (MTBE) was examined. With respect to the chloride or phosphate ions used, inhibition of oxidation was clearly in evidence, whereas addition of sulfates or perchlorates influenced these rates to a much smaller extent. Anions suppress MTBE decomposition in the following sequence: ClO4- 相似文献   

Application of fluorescence spectroscopy in the studies of natural organic matter fractions reactivity with chlorine dioxide and ozone

The composition of natural organic matter (NOM) fractions before and after the reaction with chlorine dioxide as well as ozone was studied by means of total luminescence spectroscopy (TLS) and synchronous scanning fluorescence measurements. The excitation-emission matrices spectra (EEMs) of natural as well as oxidised NOM fractions revealed two well-resolved bands with maxima at Ex/Em of 250-265/422-452 nm and at Ex/Em 300-336/414-446 nm ascribed to humic and fulvic material. The study of emission and synchronous spectra also confirmed the presence of protein-like constituents in all examined NOM fractions. The study of EEMs proved, that oxidation of all NOM fractions with ClO(2) caused mainly the break-up of molecules into smaller fragments and a decrease of the aromaticity. Changes in EEMs after the oxidation of individual NOM fractions with O(3) confirmed the formation of a significant amount of ozonation by-products, i.e. carboxylic acids, aldehydes and ketones during the oxidation process. In addition, the fluorescence studies confirmed relatively high reactivity of all NOM fractions with ClO(2) as well as with ozone.     

Unique Pit Lake Created in an Opencast Potassium Salt Mine (Dombrovska Pit Lake in Kalush,Ukraine)

We studied the physicochemical and biological characteristics of the Dombrovska pit lake in Ukraine. The lake formed in an abandoned opencast potassium salt mine and is one of the most saline inland water bodies in the world. It is 85 m deep (November 2015) and an annual inflow of about 2 Mm³ of water. The lake has two distinct layers. The mesohaline surface (0–5 m) layer is well oxygenated and slightly alkaline (pH?=?7.5–8.8). Its mineralization, expressed as dry mass, was 50–134 g dm^??3, and its electrical conductivity (EC) was 58–134 mS cm^??1. The underlying layer consists of hypersaline water with low amounts of dissolved oxygen, a neutral pH (6.7–7.4), high mineralization (179–420 g dm^??3), high EC (169–215 mS cm^??1), and higher concentrations of major anions and cations (except Ca²⁺) and nutrients than the overlying water. The vertical relationship between major ions and metals and the future salinity of the lake are discussed. In terms of zooplankton, in July we found living specimens of the rotifer Brachionus plicatilis and the ciliates Paradileptus elephantinus and Tindinnidium sp. as well as dead rotifers, cladocerans, and copepods (in total, 19 species), but only live B. plicatilis and 9 dead species in November. In the littoral part of the pit lake, we found the diatoms Nitzschia pusilla and some Halamphora species (H. borealis, H. tenerrima, H. acutiuscula), which favour highly saline waters.     

Effect of pullulan on the physicochemical properties of yoghurt

The effects of pullulan (PUL) addition (0, 1.0 and 2.0% w/ v) on the physicochemical properties of yoghurts stored at 4 °C for 28 days were investigated. Fortification of the yoghurt with 1% PUL had a weakening effect on the gel network structure, leading to a decrease in initial viscosity and an extreme increase in syneresis, when compared to control. The addition of 2% PUL largely improved product stability by increasing gel firmness and adhesiveness, showing higher viscosity and consistency index values as well as displaying the lowest syneresis. Storage time increased yoghurt gel firmness and susceptibility to serum separation.     

Understanding Abiotic and Biotic Conditions in Post-Mining Pit Lakes for Efficient Management: A Case Study (Poland)

This study was aimed at determining whether the origin, morphometry, and hydrology of post-mining lakes affect their hydrochemical and hydrobiological parameters (i.e. water quality). The investigated post-mining lakes were very young compared to glacial lakes and represent early stages of ecosystem succession. Despite their different ages and morphometries, they are all mesotrophic and have good water quality. They have not been supplied with phosphorus and nitrogen, which can cause excessive development of pelagic phytoplankton; as a result, they share low chlorophyll a (Chl a) content, low phytoplankton biomass, and relatively high water transparency. Low abundance and species richness of zooplankton indicate low trophic levels in all of the lakes. Chl a in Lakes Przykona and Bogda?ów were within the range typical of mesotrophic lakes, while Lake Janiszew had very low Chl a, typical of an oligotrophic water body. The low N:P ratios (4–6), especially in summer, indicates nitrogen limitation of primary production. There is a risk that such a proportion of the major biogenic elements could lead to harmful cyanobacterial blooms. The lake basins were formed using quaternary deposits (sand, clay) at their bottoms; as a result, the lakes had a slightly alkaline pH (>8), which favors the development of aquatic organisms. Optimum depth helps establish lake stratification and ensures ecological stability. This applies to post-mining lakes as well; an optimum depth should be determined to ensure the development of thermal stratification, which affects lake processes.     

Insight into Details of the Photosynthetic Light Reactions and Selected Metabolic Changes in Tomato Seedlings Growing under Various Light Spectra

The objective of our study was to characterise the growth of tomato seedlings under various light spectra, but special attention has been paid to gaining a deeper insight into the details of photosynthetic light reactions. The following light combinations (generated by LEDs, constant light intensity at 300 μmol m⁻² s⁻¹) were used: blue/red light; blue/red light + far red; blue/red light + UV; white light that was supplemented with green, and white light that was supplemented with blue. Moreover, two combinations of white light for which the light intensity was changed by imitating the sunrise, sunset, and moon were also tested. The reference point was also light generated by high pressure sodium lamps (HPS). Plant growth/morphological parameters under various light conditions were only partly correlated with the photosynthetic efficiency of PSI and PSII. Illumination with blue/red as the main components had a negative effect on the functioning of PSII compared to the white light and HPS-generated light. On the other hand, the functioning of PSI was especially negatively affected under the blue/red light that was supplemented with FR. The FT-Raman studies showed that the general metabolic profile of the leaves (especially proteins and β-carotene) was similar in the plants that were grown under the HPS and under the LED-generated white light for which the light intensity changed during a day. The effect of various light conditions on the leaf hormonal balance (auxins, brassinosteroids) is also discussed.