Bonded aerospace repairs under tensile loading: Wet chemical surface treatment and selected environmental conditions

Repair of composite structures and the impact of demanding environmental conditions is a crucial issue for the aircraft industry because of the increasing use of composites in modern aircraft. Consequently, the impact of environmental conditions common for aircraft applications on repair specimens in comparison to nonrepaired specimens is studied. All specimens are produced from a woven carbon fiber-reinforced epoxy-based prepreg. For the repair-specimens, an epoxy-based film adhesive is used for the soft patch repair approach. During the repair process, the surface of the precured prepreg is prepared by a mechanical method (sanding) and an additional chemical functionalization, respectively. Moisture absorption of the repair specimens is independent of the surface preparation method and higher for the repaired than for the nonrepaired specimens. The key influencing environmental conditions for the tensile strength and the failure mode of the repair specimens are elevated temperature testing as well as hot/wet conditioning and conditioning in deionized water. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47506.     

Effect of midblock on the morphology and properties of blends of ABA triblock copolymers of PDLA-mid-block-PDLA with PLLA

A method to overcome the brittleness of poly (l-lactic acid) (PLLA) by kinetically trapping a continuous low T_g amorphous phase is presented. This morphology is accomplished by exploiting the significant difference in the crystallization temperatures of PLLA vs its stereocomplex with the poly (d-lactic acid) (PDLA) isomer. In our studies, the D isomer is the end block of a triblock copolymer with a configuration of the form PDLAn–Soft Blockm–PDLAn. As demonstrated in this study, when blended with PLLA, the obtained morphology, and improvement in the sample toughness and flexibility, strongly depend on the miscibility of the midblock in the triblock copolymer with the matrix PLLA. The difference in the chemical nature of the midblock clearly affected the stereocomplex crystallization between the PDLA end blocks, the PLLA matrix polymer, and the morphology formed. It is found that the miscible midblock gives rise to a soft continuous amorphous phase while in the case of an immiscible midblock, a glassy phase separated amorphous phase is formed. Dramatically different physical properties can be obtained for various PLLA/triblock copolymer blends giving access to tough, yet flexible, semicrystalline PLLA blends.     

Vermeidung von str?mungsinduzierte CO2-Korrosion in der Erdgasproduktion mit Hilfe von Korrosionsinhibitoren

CO₂ corrosion of carbon steel is a serious problem in oil and gas production, since the most used materials are low alloyed carbon steels. There are many approaches to handle the problem of CO₂ corrosion. One flexible and economic way to control corrosion in oil and gas facilities is inhibition but the efficiency of an inhibitor is often limited by flow velocities. To investigate inhibitor efficiency in a superficial flow with high gas velocities neither standardized test had been available nor publications about that topic. Therefore the goal was to do the first investigations in that important field. To reach this aim a special, not standardized flow loop test system has been constructed. Results of these investigations have shown that differences in inhibitor efficiencies are related to chemical composition and flow velocities.     

Sources and Bioactive Properties of Conjugated Dietary Fatty Acids

The group of conjugated fatty acids known as conjugated linoleic acid (CLA) isomers have been extensively studied with regard to their bioactive potential in treating some of the most prominent human health malignancies. However, CLA isomers are not the only group of potentially bioactive conjugated fatty acids currently undergoing study. In this regard, isomers of conjugated α‐linolenic acid, conjugated nonadecadienoic acid and conjugated eicosapentaenoic acid, to name but a few, have undergone experimental assessment. These studies have indicated many of these conjugated fatty acid isomers commonly possess anti‐carcinogenic, anti‐adipogenic, anti‐inflammatory and immune modulating properties, a number of which will be discussed in this review. The mechanisms through which these bioactivities are mediated have not yet been fully elucidated. However, existing evidence indicates that these fatty acids may play a role in modulating the expression of several oncogenes, cell cycle regulators, and genes associated with energy metabolism. Despite such bioactive potential, interest in these conjugated fatty acids has remained low relative to the CLA isomers. This may be partly attributed to the relatively recent emergence of these fatty acids as bioactives, but also due to a lack of awareness regarding sources from which they can be produced. In this review, we will also highlight the common sources of these conjugated fatty acids, including plants, algae, microbes and chemosynthesis.     

SPHERES, Jülich's high-flux neutron backscattering spectrometer at FRM II

SPHERES is a third-generation neutron backscattering spectrometer, located at the 20 MW German neutron source FRM II and operated by the Ju?lich Centre for Neutron Science. It offers an energy resolution (fwhm) better than 0.65 μeV, a dynamic range of ±?31 μeV, and a signal-to-noise ratio of up to 1750:1.     

Machine learning in continuous casting of steel: a state-of-the-art survey

Journal of Intelligent Manufacturing - Continuous casting is the most important route for the production of steel today. Due to the physical, mechanical, and chemical components involved in the...