纳米材料在涂料中的应用

简述了纳米微粒的基本性质，介绍了几种典型的功能纳米材料在涂料中的应用．并探究其对涂料的改性原理．对应用中存在的问题进行了剖析。     

Synthesis, characterization of bimetallic Sn-Zn-MCM41 and its catalytic performance in the hydroxylation of phenol

A series of Sn-Zn modified-MCM41 has been synthesized by direct hydrothermal method and characterized using ICP, XRD, TG/DTA, FT-IR, HRTEM and N_2-adsorption techniques. Catalytic performances of the obtained materials were evaluated in the hydroxylation of phenol with H₂O₂. Results indicated that all the samples exhibited typical hexagonal arrangement of mesoporous structure with high surface area and the heteroatoms were probably incorporated into the framework of MCM41. Catalytic tests revealed that the bimetallic incorporated materials were effective catalysts in the hydroxylation of phenol. The conversion of phenol could be reach to 56.8% for the catalysts with Sn: Zn: Si = 2.69: 4.57: 100 (molar ratio) under the optimized reaction conditions. Moreover, the materials containing Sn and Zn exhibited higher catalytic activity than monometallic Sn and Zn modified MCM41.     

气相法改性纳米二氧化硅表面

采用硅烷偶联剂A-151处理的纳米二氧化硅粒子，具有良好的疏水性，并且反应副产物没有腐蚀性，有利于保护设备和环境保护。分别用表面羟基数、亲油化度等性能来表征改性纳米二氧化硅的效果。红外光谱分析表明A-151确实已经和纳米二氧化硅表明的羟基发生了化学反应，通过透射电镜研究发现改性后纳米二氧化硅在乙醇中达到纳米级的分散。     

A new core–shell type fluorinated acrylic and siliconated polyurethane hybrid emulsion

A novel core–shell type fluorinated acrylic and siliconated polyurethane (FSiPUA) hybrid emulsion was prepared by seeded emulsion polymerization using siliconated polyurethane (SiPU) as a seed and forming the structure with SiPU as a shell and the copolymer of butyl acrylate (BA) with 2,2,2-trifluoroethylmethacrylate (TFEMA) as a core. SiPU was synthesized using isophorone diisocyanate (IPDI), polytetramethylene ether glycol (PTMG), polypropylene glycol (PPG), dihydroxybutyl-terminated polydimethylsiloxane (PDMS), dimethylol propionic acid (DMPA), 1,6-hexanediol (HDO) and triethylamine (TEA). The contents of siloxane and fluorine were determined according to the feed ratio. Fourier transform infrared spectroscopy (FTIR) was used to identify the chain structure of SiPU and FSiPUA. Investigation of transmission electron microscopy (TEM) confirmed the core–shell structure of FSiPUA emulsion and gave the particle size at about 50 nm. The measurement results of water contact angles and the solvent absorptions in water and n-octane for cured films showed that the water and the oil repellency for FSiPUA had been improved significantly with a suitable content of fluorine and siloxane.     

A_1-A_2-O-M工艺处理焦化废水的实验研究

采用厌氧-缺氧-好氧-复合(A1-A2-O-M)工艺处理焦化废水,考察了外加碳源和碱源对焦化废水COD和NH4+-N脱除效果的影响。试验结果表明:外加甲醇和碳酸氢钠对焦化废水的硝化和反硝化效果影响很小;不外加碳源和碱源时,焦化废水经处理后出水的COD和NH4+-N平均质量浓度分别为125.0mg/L和1.12mg/L,分别达到《污水综合排放标准》(GB8978-1996)中的二级标准和一级标准。     

基于FPGA实现AES的侧信道碰撞攻击

为了解决攻击点在能量迹中具体位置的识别问题,在对侧信道碰撞攻击技术研究的基础上,提出了通过计算能量迹中每个采样点的方差来识别攻击点的方差检查技术。并利用基于相关系数的碰撞检测方法,对一种AES的FPGA实现实施了攻击。实验结果表明,方差检查技术可以有效地识别攻击点在能量迹中的具体位置。     

基于硬件Kalman滤波器的航拍云台姿态获取

航拍云台姿态获取是航空摄影中相机姿态校正的基本依据,介绍了一种基于硬件Kalman滤波器的航拍云台姿态获取的实现方法。设计中采用MPU6050作为系统的姿态传感器,它提供三轴角速度和三轴加速度数据。根据系统特征建立Kalman滤波方程对这些数据进行数据融合处理,Kalman滤波过程中的加减乘除浮点数运算由FPGA实现,外部数据的采集和时序的控制也由FPGA完成。经过对实际数据的处理实验,得出该硬件模块可以获得较为准确的航拍云台姿态,输出结果误差在-1.5°~1.5°范围内。     

基于最佳竞争窗口的IEEE802.11DCF接入协议改进及性能分析

针对DCF协议的初始竞争窗口不能随着节点数变化选择其最佳值的不足,提出一个具有两级退避的接入协议(OCW-DCF),并用Markov模型分析了协议性能,确定其最佳竞争窗口值。仿真结果表明,OCW-DCF协议能有效减小信道接入延时,且采用基本接入模式的总体性能比RTS/CTS接入模式的好。     

一种分布式无线同步数据采集系统设计

介绍了一种分布式多点无线同步地震数据采集系统设计方法。该系统以C8051F020单片机为主控芯片,利用GPS模块提供的PPS信号实现分布式采集系统的同步,利用无线射频模块XbeePro实现数据的无线传输。整个系统通过上位机进行实时控制。实验证明,该系统能够实现严格同步采集,整个采集系统工作稳定,操作简单,具有较高的工程应用价值。     

基于FPGA的高速数据存储系统优化设计

针对遥测系统数据记录装置中数据传输速率与存储速率不匹配的问题,提出Flash的并行存储方案,采用交替双平面的编程方式可以使得存储器的存储速率达到单片Flash最高存储速率的2倍,即60 MB/s;对控制单元FPGA内部双端口RAM的逻辑设计进行改进,解决了数据存储异常的现象。在数据回收方面,提出了多备份的设计思想和备用读数接口的设计方案,已在工程应用中得到成功实践,验证了该数据记录装置的可靠性。