Experimental investigation of liquid water in flow field of proton exchange membrane fuel cell by combining X-ray with EIS technologies

The flow field is a pivotal part to manage the transport of water and gas in proton exchange membrane fuel cell. However, the reported water measurement methods (e.g., X-ray and electrochemical impedance spectroscopy (EIS)) cannot give a comprehensive understanding water distribution in the flow field, resulting in challenges in optimizing the channel design and enhancing fuel cell performance. Therefore, we propose a water measurement method combining the X-ray radiography with EIS to investigate the effect of different operating conditions on the growth law and distribution of liquid water in parallel and serpentine flow fields. The attenuation coefficient of liquid water to X-ray is calibrated with constant tube-current and tube-voltage of X-ray generator. Besides, the parallel flow field with hydrophobic treatment is studied. The results show that the water accumulation of the parallel flow field is far more than the serpentine flow field, and the water content of the middle region is higher than that of other regions in the parallel flow field. Furthermore, operating conditions (cathode inlet gas flow rate, inlet gas humidity, and back pressure) have little effect on the liquid water content of the middle region in the parallel flow field. The polarization curve, EIS result, and X-ray radiography show that the performance and water drainage capacity of the hydrophobic parallel flow field are better than the normal one.

     

电子束辐照预硫化技术在轮胎轻量化中的应用

研究电子束辐照预硫化技术在轮胎轻量化中的应用。采用经过电子束辐照预硫化的胎体,可以减薄、减窄过渡层,从而减小轮胎质量,降低生产成本,并且轮胎不会出现胎里露线现象,同时不会影响成品轮胎的充气外缘尺寸、高速性能和耐久性能。     

Experimental and numerical simulation of lignite chemical looping gasification with phosphogypsum as oxygen carrier in a fluidized bed

Phosphogypsum (PG) is a solid waste produced in the wet process of producing phosphoric acid.Lignite is a kind of promising chemical raw material.However,the high sulfur of lignite limits the utilization of lig-nite as a resource.Based on fluidized bed experiments,the optimal reaction conditions for the production syngas by lignite chemical looping gasification (CLG) with PG as oxygen carrier were studied.The study found that the optimal reaction temperature should not exceed 1123 K;the mole ratio of water vapor to lignite should be about 0.2;the mole ratio of PG oxygen carrier to lignite should be about 0.6.Meanwhile,commercial software Comsol was used to establish a fuel reaction kinetics model.Through computational fluid dynamics (CFD) numerical simulation,the process of reaction in fluidized bed were well captured.The model was based on a two-fluid model and coupled mass transfer,heat transfer and chemical reac-tions.This study showed that the fluidized bed presents a flow structure in which gas and solid coexist.There was a high temperature zone in the middle and lower parts of the fluidized bed.It could be seen from the results of the flow field simulated that the fluidized bed was beneficial to the progress of the gasification reaction.     

Room-Temperature Solid-State Lithium Metal Batteries Using Metal Organic Framework Composited Comb-Like Methoxy Poly(ethylene glycol) Acrylate Solid Polymer Electrolytes

Solid polymer electrolyte with good thermal stability and flexibility is an excellent candidate for solid-state lithium metal batteries, while its low ionic conductivity caused by high crystallinity limits its application at ambient temperature. Here a metal organic framework (zeolitic imidazolate framework-8, ZIF-8) composited comb-like methoxy poly(ethylene glycol) acrylate polymer electrolyte (MCPE) with high ionic conductivity (9.96 × 10⁻⁵ S cm⁻¹ at 30 °C) is prepared by an in situ UV polymerization method. The as-prepared MCPE exhibits improved mechanical property due to the introduction of porous ZIF-8 nanofillers, which is beneficial to suppress the growth of lithium dendrites. Consequently, the LiFePO₄||MCPE||Li cells show a high capacity of 116 mAh g⁻¹ at 30 °C and 0.5 C, and maintain 89.4% of initial capacity after 150 cycles with the average Coulombic efficiency of 99.9%. These results demonstrate that the MCPE shows great potential in solid-state lithium metal batteries near room temperature.     

Correction to: Bismuth Yttrium Oxide (Bi3YO6), A New Electrode Material For Asymmetric Aqueous Supercapacitors

Journal of Inorganic and Organometallic Polymers and Materials - The original version of this article unfortunately contained mistakes. In line 9 of the abstract, 5% should read as 2%. The...     

阴离子F掺杂SOFCs阴极La1?xSrxCo1?yFeyO3?δ的氧还原性能

固体氧化物燃料电池(SOFC)因其高效、清洁及便携性等优点被认为是当前最具应用前景的新能源技术之一。传统SOFC较高的工作温度（>800 ℃）限制了其商业推广,降低其工作温度成为当前研究的热点。钙钛矿阴极材料La_1?xSr_xCo_1?yFe_yO_3?δ(LSCF)因具有较高的电子离子混合导电性而成为中温SOFC阴极材料的较佳选择,同时实验证明F替代O位能有效提升SOFC稳定性。基于已有实验报道,本文采用第一性原理计算了F掺杂对LSCF电子结构影响、氧气分子在(100)表面吸附能的变化、阴极体内氧空位形成能及氧离子迁移活化能的影响。通过与未掺杂材料性能的比较,证明:适量F掺杂LSCF在有效提升阴极表面对氧气分子吸附能力同时能进一步提高体内氧离子迁移效率,从而提升阴极氧化还原反应能力。      

地下金属矿山斜坡道浆土路修筑工艺及应用研究

斜坡道是地下金属矿山的主要运输通道,其道路质量直接影响着矿山的安全运输和经济效益。针对斜坡道混凝土浇筑路面存在的筑路成本高、养护时间长、使用寿命短及维护困难等不足,引入浆土路修筑技术,开展了地下金属矿山斜坡道浆土路筑路材料配比试验、黏土搓条和崩解试验、水洗筛分试验,并在云南卡房分公司完成了浆土路试验路段的修筑。结果表明：浆土路筑路技术能够很好地应用于地下矿山道路修筑,具有施工工艺简单、筑路成本低、施工周期短、承载能力强、抑尘防滑和低碳环保等诸多优点,为地下金属矿山道路修筑提供了工程借鉴,对于矿山降本增效、节能减排及安全高效具有重要的意义。     

CO2/H2S对油气管材的腐蚀规律

本文综述了CO2、H2S对油气管材的腐蚀机理及影响因素,提出了开发经济型油管的设想.     

MasterCAM中MFC对话框的应用

为在CAM软件MasterCAM中使用MFC对话框,对其进行了二次开发,用动态链接库来实现MasterCAM和MFC对话框之间的通信,并在MasterCAM二次开发环境C-Hooks的应用程序中调用MFC对话框资源,给出了接口模型、实现过程和实例,实现了MFC对话框在MasterCAM中的应用.     

Ni3Al合金中晶界与位错交互作用的研究

运用嵌入原子法势函数和静态驰豫最陡梯度的计算方法,原子模拟了Ni_3Al合金中晶界与位错的交互作用.主要研究了晶界与位错交互作用的能量特征、晶界结构单元的畸变行为和晶界附近位错的核心结构,并分析讨论了各种因素对它们的影响以及与Ni_3Al晶界韧脆行为之间的关系