羊角山之造化

我国有悠久的饮茶历史,饮茶时所需的饮茶用具亦渊远流长,随着时代的进步,越来越考究,自北宋以来,人们尤以紫砂茶具著称为首,这种爱好,一直沿传至今。     

Glass crystallization making red phosphor for high-power warm white lighting

Rapid development of solid-state lighting technology requires new materials with highly efficient and stable luminescence, and especially relies on blue light p...     

Insights into the Reaction Network and Mechanism of Green Aerobic Oxidative Esterification of Methacrolein over Different Heterogeneous Catalysts

The oxidative esterification of methacrolein (MAL) is an important way to prepare high-valued methyl methacrylate (MMA), but this process is ultra-complex due t...     

我国钢管混凝土拱桥应用现状与展望

以轴压比、含钢率和钢材强度为参数,进行了8根高强钢管超高强混凝土柱和1根普通强度钢管超高强混凝土对比柱的拟静力试验,分析了各参数对破坏形态、荷载-位移滞回曲线、骨架曲线和各个抗震性能指标(如延性、耗能和强度与刚度退化等)的影响程度。结果表明：压弯破坏为主要破坏模式;弹性刚度受轴压比影响不大,但受含钢率和钢材强度影响较大;极限承载力受轴压比、含钢率和钢材强度影响较大,随前者增大而降低,随后两者增大而增大;延性受轴压比、钢材强度和含钢率影响较大,随前两者增大降低,随后者增大而增大;耗能能力随轴压比增大而减弱,随含钢率和钢材强度增大而增强;刚度和强度退化程度随轴压比增大而降低,随含钢率增大而增大,且前者随钢材强度增大而增大,后者则随钢材强度增大呈减小趋势。通过对比不同规程抗弯刚度计算方法,结果表明：受材料适用范围限制,各规程不适用于该类高强材料组合构件。     

Hydrogen Bond-Assisted Ultra-Stable and Fast Aqueous NH4+ Storage

Aqueous ammo-nium ion batteries are regarded as eco-friendly and sustainable energy storage systems.And appli-cable host for NH4+ in aqueous solution is always ...     

区域文化生境下地方大学的文化选择

当前地方大学在发展自身的同时,也要立足地方、服务地方。本文试图用阿特巴赫的中心—边缘学说和生物学上的生态位学说来分析地方大学的发展困境,提出对策,立足地方大学优势,从文化生态学角度来探讨区域大学的特色和发展方向,并更好地服务地方发展。     

自组织方式下的旧城居住空间发展与更新* ——以中部城市某旧城区为例

本文对具体案例进行分析,从自组织角度来考察一个较为完整居住空间的发展与更新过程,探讨在自组织方式下的空间架构和组织逻辑。     

Effects of substituents on the third-order nonlinear optical properties of poly(3-alkoxythiophene) derivatives

Poly(3-alkoxythiophenes) (P3AOTs) have been synthesized with octoxyl, dodecaoxyl and 4-nitro-benzyloxyl as sidechains, respectively. The novel poly(3-octoxycthiophen)-co-poly(3-(4-nitro-benzyloxy)-thiophene) (P3OOT-co-P3NBOT) has also been prepared. The absorption spectra of samples indicate that the side groups affect the bandgap of P3AOTs. The nonlinear optical (NLO) properties of P3AOTs were investigated using Z-scan method. The third-order NLO susceptibility (χ⁽³⁾) of the polymers shows a strong dependence on the length of the alkoxyl sidechains and polarity of polymers, which affect the intra- and intermolecular charge transfer. These polymers have potential application in optical limiting device.     

Fabrication and catalytic property of an Ag@poly(3,4-ethylenedioxythiophene) yolk/shell structure

Poly(3,4-ethylenedioxythiophene) (PEDOT) hollow spheres with the size ranged from 210 to 850 nm and a conductivity of 6 × 10^?2 S cm^?1 have been prepared via electrochemical polymerization of 3,4-ethylenedioxythiophene in the presence of poly(vinyl pyrrolidone) as a soft template. Then, a novel Ag@PEDOT yolk/shell structure has been prepared simply and directly by a penetration and reduction approach. The morphology, formation, and the catalytic activity of the as-prepared Ag@PEDOT yolk/shell structure have been investigated. The experimental result shows that the as-prepared Ag@PEDOT yolk/shell structure exhibits excellent catalytic activity on reduction of p-nitrophenol. The employed approach may shed some light on preparing other noble metal@conductive polymer core/shell structure.