Fabrication of a novel ZnO–CoO/rGO nanocomposite for nonenzymatic detection of glucose and hydrogen peroxide

Herein, a novel nanocomposite of binary ZnO–CoO nanoparticles loaded on the graphene nanosheets (ZnO–CoO/rGO) has been successfully constructed via a facile, economical and two–step process. The obtained ZnO–CoO/rGO hybrids with high electrical conductivity and abundant active sites, could be modified on a glassy carbon electrode to detect glucose and H₂O₂ multi–functionally. The fabricated biosensor exhibits wide linear range for glucose (10 μM to 11.205 mM) and H₂O₂ (25 μM to 11.1 mM), and their corresponding sensitivity are 168.7 μA mM^?1 cm^?2 and 183.3 μA mM^?1 cm^?2. The limits of detection are 1.3 μM and 0.44 μM for the oxidation of glucose and the reduction of H₂O₂, respectively. Furthermore, remarkable selectivity, long–term stability and outstanding reproducibility of the non–enzyme biosensor prove that ZnO–CoO/rGO hybrids are the promising candidate in practical applications.     

热定型机含油废气的特征及净化技术

介绍了热定型机油烟废气形成的过程,该废气具有温度高、含油量大及杂质多的特点,处理难度较大。进一步分析了现有几种含油废气处理技术的特点,以及处理过程中存在的问题,论述了国内外热定型机含油废气的处理现状,展望了技术发展前景。     

以石英砂为硅源合成4A沸石的研究

以石英砂为硅源,通过水热法合成4A沸石.详细考察了合成温度、时间、碱度以及硅铝比等因素对合成结果的影响.通过X射线粉末衍射、扫描电子显微镜和激光衍射粒径分析等方法对合成的4A沸石进行测试.结果表明石英砂在6mol/L的氢氧化钠溶液中,于密封反应釜中,200℃条件下反应4h可以完全被活化得到含活性氧化硅的碱液,以此为硅源...     

求解点堆动态方程的IGear方法

求解点堆中子动力学方程的改进的Gear方法——IGear,以其高阶和大稳定域的性质保持了Gear方法适应性强,计算精度较高的优点,并改进了它的缺点。因此能够灵活应用于各种反应性的输入。计算结果表明:从计算时间和计算精度上看,该方法都可以满足实际工程的需要,是求解点堆动态方程的一种较好的方法。     

基于智能手机的实时体重健康管理系统软件设计

随着生活节奏的加快,办公室人群普遍缺乏运动是诱发健康问题的主要原因。目前国内对于办公室人群的健康问题尚未引起足够重视,市场上也鲜有相关产品问世。该文基于安卓平台在智能手机上开发出一款实时体重健康管理软件,结合位于鞋垫的传感器进行数据传输,根据足底压力判断人的当前运动状态从而实时指导用户锻炼,养生等行为。结果表明,将智能手机应用于健康管理的范畴具有很强的现实意义。     

用ObjectARX开发AutoCAD2004应用程序

与以前版本相比，AutoCAD2004在用户界面、性能、功能等各方面都有较大的改进和完善，从而使AutoCAD上升到一个新的台阶。本文介绍了AutoCAD2004的开发环境，0bjectARX开发工具的功能和特点，并给出了具体实例。     

Synthesis of a novel DOPO‐based polyphosphoramide with high char yield and its application in flame‐retardant epoxy resins

A novel and highly effective flame retardant (FR), DOPO‐TPMP oligomer, was synthesized by a simple condensation of 4‐(hydroxymethyl)‐2,6,7‐trioxa‐1‐phosphabicyclo[2.2.2]octane‐1‐oxide and phosphorus oxychloride followed by a polycondensation reaction with 6‐(2,5‐dihydroxyphenyl)‐6H‐dibenzo[c,e][1,2]oxaphosphinine‐6‐oxide. The chemical structure of DOPO‐TPMP was well characterized using Fourier transform infrared and NMR spectra. DOPO‐TPMP was used as an additive‐type FR for epoxy resin (EP). The FR properties of the resultant EP composites were investigated by limiting oxygen index (LOI) test, UL‐94 vertical burning test and cone calorimeter measurements. Specifically, the EP composite containing 10.0% DOPO‐TPMP achieved a LOI value of 36.1%, V‐0 rating in the UL‐94 test and a 58% reduction in peak heat release rate. Further mechanism analysis attributed the enhanced flame retardancy to the increased char yield on the addition of DOPO‐TPMP. © 2019 Society of Chemical Industry     

曲面加工中走刀路线优化

针对刀具不同走刀路线对工件加工精度影响的问题,应用成组技术对曲面进行分析,并阐述了曲面加工时常用的插补方法.分析不同走刀路线对工件精度及加工效率的影响,优化二维与三维曲面加工,正确选择刀具走刀路线的方法,以更好地达到工件的加工精度及其他技术要求.     

基于高偏移阈值的补偿感应耦合电能系统传输特性分析

在传统感应耦合电能传输(inductively coupled power transfer,ICPT)系统拓扑中,系统谐振频率的漂移会引起耦合效率的下降。针对该问题,本文提出一种新型的基于PSS(原边采用并联串联补偿,副边采用串联补偿)补偿的ICPT系统拓扑。对其电路模型进行了分析和建模,得出不同品质因数下,补偿系统的电压、电流增益、传输效率的特性曲线,该补偿拓扑具有较高的补偿因数;分析了系统中补偿系数对谐振元件电压电流的应力影响,选取合适的补偿系数以降低系统的设计成本。最后,设计了1台基于PSS补偿拓扑的ICPT系统样机,实验验证了对PSS补偿拓扑的特性分析。