Crystallization and melting behaviour of poly(butylene terephthalate) in poly(butylene terephthalate)/polyarylate blends

Summary The crystallization and melting behaviour of poly(butylene terephthalate) has been studied in the pure state and in its blends with a polyarylate of bisphenol A and isophthalic/terephthalic acids. Differential scanning calorimetry has been used as experimental technique and the effects of different thermal treatments have been analyzed. Results show the hindrance for the crystallization of poly(butylene terephthalate) imposed by the presence of polyarylate, as well as the existence of multiple melting after isothermal crystallization. Explanations are given for the observed behaviours.     

Ischemia‐reperfusion injury. A phenomenon,that also occurs in the bone

Ischemia‐reperfusion injury of the bone occurs due to traumatic and non‐traumatic alterations affecting blood supply to the bone. It is likely to occur also upon insertion of an implant. Ischemia‐reperfusion injury of the bone has been studied by interruption of blood supply in situ, in limb replantation/transplantation models, in revascularized bone grafts and non‐vascularized bone fragments, as well as in isolated cultured cells. All cells of the bone are affected, including osteoblasts, osteocytes, osteoclasts, chondrocytes, and bone marrow cells. Critical ischemia times for induction of bone cell death, either in the ischemic period or following reperfusion, are in the range of 3 to 7 h. These critical ischemia times are significantly increased by decreasing the temperature from 37 °C to 0–4 °C. Anoxia is the most likely trigger of cell injury in the ischemic phase. In the reperfusion phase, reactive oxygen species are decisively involved in the injurious process. In general, however, the available information on the mechanism of ischemia‐reperfusion injury of the bone is relatively sparse. On the other hand, there are clear similarities to the mechanisms of ischemia‐reperfusion injury known from other organs, and there is a clear potential for protection against ischemia‐reperfusion injury of the bone.     

Knight Shift Data and Superconducting T c Modeling Based on an Effective Hole Model

The superconducting T _c of cuprates have been modeled on a linear scaling with hole concentration per CuO₂ plane and a deleterious influence of bond resonance with the apical system (effective hole formalism). In cases where distribution between various hole reservoirs is not trivial, Knight shift can provide actual hole concentrations. It is shown here that when Knight shift data are used in an effective hole algorithm, satisfactory T _c predictions can be made, corroborating the deleterious influence on T _c of apical O and earlier assumptions concerning hole distributions. For the case of stacking of more than two CuO₂ planes, the inner plane has to be treated as an infinite layer analog in the effective hole model. A separation into inner and outer planes with different dopings is indeed observed by Knight shift, with higher doping in the latter. This is explained here as being due to a tendency to equalize an effective doping degree, as the outer planes lose holes in resonance of bonding with the apical system.     

Department of Applied Chemistry and Chemical Engineering, Claude Bernard University (Lyon I): Current Research in Adhesion Science

This paper reviews the activity in adhesion science of the Department of Applied Chemistry and Chemical Engineering (CNRS, URA 417) of the University of Lyon, France. This work essentially concerns treatments and modifications of surfaces by various chemical, electrochemical and physical techniques-electropolymerization, plasma polymerization, sol-gel processes, phosphatation, etc. Examples of the characterization of these surfaces and that of bonded joints are shown. Emphasis is placed on the possibilities offered by the techniques developed in the laboratory (low-energy electron-induced X-ray spectrometry and the three-point flexure test).     

On LP-MUSIC

Studies the consistency properties of a method recently proposed for temporal or spatial frequency estimation from noisy data. The method in question is a MUSIC technique that makes use of a linear prediction algorithm to determine the signal subspace. It is shown that the signal subspace determined by the subject linear prediction-MUSIC (LP-MUSIC) algorithm can collapse in certain scenarios and. Hence, that the LP-MUSIC frequency estimates are not always consistent. The difficulties LP-MUSIC may encounter in some cases are illustrated by means of numerical examples     

Phase Relations and Properties of Phases in the TlInSe2–TlPrSe2 System

The phase diagram of the TlInSe₂–TlPrSe₂ system was mapped out using differential thermal analysis and x-ray diffraction data. The system was found to contain a partial solid-solution series (0–10 mol % TlPrSe₂) and a quaternary compound of composition Tl₂InPrSe₄. The electrical conductivity, Hall coefficient, and thermoelectric power of TlPrSe₂ and Tl₂InPrSe₄ were measured in the temperature range 300–1100 K. The charge carriers in these compounds were shown to be scattered mainly by longitudinal acoustic phonons.