Against general wisdom in crystallization,the nucleation of InP and Ⅲ-Ⅴ quantum dots (QDs) often dominates their growth.Systematic studies on InP QDs identified the key reason for this:the dense and tight alkanoate-ligand shell around each nanocrystal.Different strategies were explored to enable necessary ligand dynamics—i.e.,ligands rapidly switching between being bonded to and detached from a nanocrystal upon thermal agitation—on nanocrystals to simultaneously retain colloidal stability and allow appreciable growth.Among all the surface-activation reagents tested,2,4-diketones (such as acetylacetone) allowed the full growth of InP QDs with indium alkanoates and trimethylsilylphosphine as precursors.While small fatty acids (such as acetic acid) were partially active,common neutral ligands (such as fatty amines,organophosphines,and phosphine oxides) showed limited activation effects.The existing amine-based synthesis of InP QDs was activated by acetic acid formed in situ.Surface activation with common precursors enabled the growth of InP QDs with a distinguishable absorption peak between ~450 and 650 nm at mild temperatures (140-180 ℃).Furthermore,surface activation was generally applicable for InAs and Ⅲ-Ⅴ based core/shell QDs. 相似文献
Two-dimensional (2D) ultrathin SiC has received intense attention due to its broad band gap and resistance to large mechanical deformation and external chemical corrosion. However, the synthesis and application of ultrasmall 2D SiC quantum dots (QDs) has not been explored. Herein, we synthesize a type of monolayered 2D SiC QDs with advanced photoluminescence (PL) properties via a facile hydrothermal route. Their average size and thickness can be easily adjusted by altering the reaction time. The ultrasmall 2D SiC QDs exhibit a long fluorescence lifetime of 2.59 μs due to efficient quantum confinement. The applications of SiC QDs are demonstrated through labeling A549, HeLa, and NHDF cells and delivering agents for intracellular low-abundant microRNA (miRNA) detection. This advance in preparing photoluminescent SiC QDs is of great significance for broadening their potential in biomedical and optical applications.
Influence maximization of temporal social networks (IMT) is a problem that aims to find the most influential set of nodes in the temporal network so that their information can be the most widely spread. To solve the IMT problem, we propose an influence maximization algorithm based on an improved K-shell method, namely improved K-shell in temporal social networks (KT). The algorithm takes into account the global and local structures of temporal social networks. First, to obtain the kernel value Ks of each node, in the global scope, it layers the network according to the temporal characteristic of nodes by improving the K-shell method. Then, in the local scope, the calculation method of comprehensive degree is proposed to weigh the influence of nodes. Finally, the node with the highest comprehensive degree in each core layer is selected as the seed. However, the seed selection strategy of KT can easily lose some influential nodes. Thus, by optimizing the seed selection strategy, this paper proposes an efficient heuristic algorithm called improved K-shell in temporal social networks for influence maximization (KTIM). According to the hierarchical distribution of cores, the algorithm adds nodes near the central core to the candidate seed set. It then searches for seeds in the candidate seed set according to the comprehensive degree. Experiments show that KTIM is close to the best performing improved method for influence maximization of temporal graph (IMIT) algorithm in terms of effectiveness, but runs at least an order of magnitude faster than it. Therefore, considering the effectiveness and efficiency simultaneously in temporal social networks, the KTIM algorithm works better than other baseline algorithms. 相似文献