基于软件定义网络和移动边缘计算的车联网高效任务卸载方案

随着车联网(IoV)中车辆和智能应用数目的增加使计算密集型任务激增,传统架构难以满足用户需求。为解决车联网计算资源不足且分配不均匀、应用时延需求无法满足、任务能耗成本较高的问题,结合移动边缘计算(MEC)和软件定义网络(SDN),设计了一种从宏基站到MEC服务器到车辆的车联网架构中的高效任务卸载方案,并提出一种改进的低复杂度非支配排序遗传算法,优化任务卸载成本和MEC服务器的负载均衡率。实验仿真结果表明,相比于随机卸载,NO-MEC卸载,NO-I卸载,传统NSGA、NSGA-Ⅱ卸载,GA卸载,Q-learning卸载,DQN卸载方案,所提方案有着更低的卸载成本,更优的负载均衡率,得到近似最高的系统效用,能够给车联网中的车辆用户带来更优质的网络服务。     

Solid extraction of caffeine and theophylline from green tea by molecular imprinted polymers

This paper involves a feasibility study on using molecular imprinted polymers as the sorbent materials in solid phase extraction for caffeine and theophylline from green tea. Two kinds of MIPs, with caffeine-theophylline mixture and pentoxifylline-theophylline mixture as the templates respectively, MAA as the monomer, EDMA as the crosslinker and ATBN as the initiator, were applied to this purpose. Mixture solution of caffeine and theophylline (1 Μg/ ml in acetonitrile) was applied to the solid extraction cartridges following a load, wash and elute procedure with acetonitrile, methanol, methanol-acetic acid (90/10, v/v) as the solvents, respectively. This solid phase extraction protocol was applied for extraction of caffeine and theophylline from green tea. Comparison between the results obtained with the MIPs cartridges and a traditional C₁₈ reversed-phase cartridge was made. It showed that the MIP-based sorbent on the solid phase extraction was comparable with that of C₁₈ material. HPLC analysis using a C₁₈ column (5 Μm, 250× 4.6 mm from Rstech corporation), methanol: water (60 :40, v/v) as the mobile phase at a flow rate of 0.6 ml/min was applied for the quantitative determination.     

羟基烷基磺酸镀液电镀Sn—Pb合金的研究

我国自行研制生产的羟基烷基磺酸电镀Sn-Pb合金镀液已经在部分厂家投产使用.生产实践证明,该镀液能获得不同铅含量的、可焊性优良且镀层结晶细致而光亮的Sn-Pb合金镀层.本研究重点测定了该镀液的电化学性能,如阴极电流效率、分散能力及深镀能力.并对添加剂的作用进行了研究探讨.     

混杂增强聚氨酯复合硬质泡沫塑料的研制

系统介绍混杂增强聚氨酯复合硬质泡沫塑料的制备情况，详细分析聚氨酯硬质泡沫塑料制备过程中的工艺问题，表征与分析其结构与性能，着重分析偶联剂对填充物增强性能的影响以及填充物含量对聚氨酯硬质泡沫塑料吸水性能的影响，介绍聚氨酯硬质泡沫塑料的应用，最后指出其发展前景。     

丙二醇单甲醚丙酸酯合成体系的气相色谱分析

自行研制了氰乙基(25%,质量分数)甲基硅橡胶(XE-60)石英毛细管色谱柱。建立了对含游离酸的丙二醇单甲醚丙酸酯的色谱分析方法。该法具有分离效果好,分析速度快的优点。     

带轴涡轮转子在立式超速试验台上的超速试验

对带轴涡轮转子提供了可行的试验处理方法 ,并成功地进行了超速试验     

金安金沙江悬索桥隧道式锚碇变形破坏机制研究

隧道式锚碇的变形破坏机制涉及到结构与围岩的协同作用问题。以华丽高速公路金安金沙江悬索桥两岸隧道锚变形破坏机制为研究对象,利用工程类比法评价了其稳定性控制要素,设计了超载数值试验。根据塑性区的扩展过程确定了施工安全监测和需要采取预加固的重点部位,确定了隧道锚围岩的破坏模式。根据锚面监测点位移由mm到cm量级突变确定的两岸锚岩系统极限荷载均为6~8倍设计缆力,则锚岩系统的设计承载力取3倍设计缆力下变形安全是有保障的。丽江岸塑性区在10 P下贯通;华坪岸塑性区在14 P下贯通。设计缆力作用下,丽江岸锚碇最大位移1.5 mm、围岩1.2 mm、地表0.5 mm;华坪岸锚碇最大位移1.7 mm、围岩1.5 mm、地表0.7 mm,其响应顺序为后锚面监测点前锚面监测点锚碇中间岩体地表点,可作为后期结构及围岩安全监测布点和预警的参考,也证明当前设计缆力下变形和强度均是安全的。     

Formation of Polymeric Lewis Acid–Lewis Base Complexes with Well-defined Organoboron Polymers

The binding of Lewis bases to organoboron polymeric Lewis acids has been studied and the parameters that determine the complexation equilibrium have been investigated, which include (i) the strength of the individual Lewis acids and Lewis bases, (ii) concentration, and (iii) temperature. While the strongly Lewis acidic borane polymers poly(4-bis(pentafluorophenyl)borylstyrene) (PS-BPf) and poly(4-(di-2-thienylboryl)styrene) (PS-BTh) form isolable complexes with strong Lewis bases such as 4-t-butylpyridine (^tPy), a temperature dependent equilibrium is established with weaker bases such as THF. Similarly, the weakly Lewis acidic boronate polymer poly(4-diethoxyborylstyrene) (PS-BOEt) undergoes a temperature dependent equilibrium with the strong Lewis base 4-dimethylaminopyridine (DMAP), while poly(4-pinacolatoborylstyrene) (PS-BPin) does not significantly bind to pyridine bases. Decomplexation of PS-BTh· ^t Py is achieved by treatment with the stronger Lewis acid, B(C₆F₅)₃, thereby confirming the reversible nature of the polymeric Lewis acid–base adducts. This paper is dedicated to Professor Ian Manners in gratitude of his guidance throughout the years and recognition of his scientific accomplishments     

Seasonal evolution of the interannual variability of chlorophyll-a concentration and its forcing factors in the northwestern Pacific from 1998 to 2010

The northwestern Pacific Ocean is a complex region with significant biological spatial variations on a seasonal timescale. To investigate the joint variation patterns on both seasonal and interannual timescales, a season-reliant empirical orthogonal function (S-EOF) analysis was applied to seasonal mean chlorophyll-a concentration (chl-a) anomalies in the northwestern Pacific Ocean during the period 1998–2010. The first two dominant modes accounted for nearly 31% of the total interannual variance, with the second S-EOF mode (S-EOF2) lagging behind the first S-EOF mode (S-EOF1) by one year. S-EOF1 featured a strong variation pattern to the north of 30° N, with maximum chl-a in winter and minimum chl-a in summer. However, S-EOF2 indicated an opposite seasonally evolving pattern compared with S-EOF1, with chl-a increasing along the Kuroshio and extension current from boreal winter to autumn. Both these modes revealed significant relationships with climate-related indices. The two modes corresponded to the central Pacific (CP) La Niña developing episodes and the turnaround from eastern Pacific (EP) La Niña to CP El Niño, respectively. Both modes were associated with the cold phase of the Pacific Decadal Oscillation, which played an important role in prolonging the impact of the El Niño/Southern Oscillation on chl-a seasonal evolution from 1998 to 2010. In addition, we discuss the possible factors dominating chl-a seasonal variation, in terms of the subregions of the northwestern Pacific Ocean. In the subtropical northwestern Pacific Ocean (15° N – 30° N), the chl-a growth was primarily nutrient-limited, whereas in the mid-latitude northwestern Pacific Ocean (35° N – 50° N), the chl-a growth was mainly light-limited.     

光亮碱性化学镀镍工艺研究

通过均匀设计法 ,优选了芳香基磺酸盐、芳香醛、炔醇以及含铅、含碘添加剂 ,从而开发了一种光亮碱性化学镀镍新工艺。所得镀层光亮 ,色泽均匀。讨论了主盐、还原剂、温度及pH值对镀速的影响 ,检测了镀液、镀层的性能