地方设计院建筑师之路的探索

在建筑设计市场激烈竞争的态势下,地方设计院建筑是如何迎接挑战,如何把握机遇已经成为必需直面并且寻求探索的问题.江阴市建筑设计研究院有限公司发挥地方设计院建筑师的地方资料优势,地方文化的优势和地方技术的优势,取得了丰硕的成果,既占领了地方市场,又培养了一批高素质的建筑设计人员.     

城镇园林植物规划方法及其应用(3)--热带、亚热带植物规划

完美的植物景观,必须具备科学性与艺术性两方面的高度统一.植物造景中的种植设计,不能单独追求艺术效果而不顾植物生长习性的要求,应因地制宜,选择与种植地点的环境和生态相适应的植物种类,否则植物不能存活或生长不良,达不到造景的要求.例举适合热带地区及南亚热带地区生长的数百种植物,以供种植设计时参考.     

制导系统精度分析及误差分配方法

研究了一种新的方法流程,针对非线性导弹模型,选用蒙特卡罗方法,对影响精度的各类误差源分类,并进行脱靶量仿真。提出基准弹道概念,按照瑞利准则分析指标要求的精度;根据误差源的控制难度和它们对脱靶量的影响,以及自身的变化灵敏度,合理分配误差指标;仿真结果表明:该方法可以确定影响制导性能的主要误差来源,合理分配各环节的设计指标;它为设计过程中改进制导性能和落实合理的工程指标提供理论依据,是研制过程中一个科学的方法流程。     

难溶有机药物阿莫西林纳米结构的制备

在表面活性剂SDS的辅助下,运用简单的化学沉淀法制备了三种阿莫西林纳米结构.运用扫描电镜和红外光谱对制备的阿莫西林进行了形貌、尺寸和化学结构的表征.实验发现通过调节阿莫西林钠溶液的pH值,可以得到阿莫西林纳米和微米颗粒纳米带和纳米纤维,在一定程度上实现了这一难溶有机药物的可控生长.     

导弹综合试验与评估方法研究

科学合理的导弹试验与评估方法能够有效缩短研制周期,提高试验效益。导弹综合试验与评估方法旨在总体规划和设计导弹试验过程和内容,依据导弹模型验证技术提高建模与仿真在导弹试验与评估中的地位和作用,采用多源信息融合技术和Bayes评估技术提高导弹试验与评估结果的可信性。详细阐述了基于ST&E的导弹试验设计方法,并就综合试验设计的关键问题提出解决思路和方法。     

校企合作化学与材料专业工程创新训练平台的规划与建设

强化工程训练教学环节,是地方本科学校应用技术人才培养模式创新的核心内容。本文从指导思想、原则和目标、具体措施等方面进行阐述和探讨,论述了化学与材料专业工程创新训练平台规划与建设的内容和保证其正常运行的措施。     

利用反应结晶制备大颗粒硫酸钾的研究

为解决国产硫酸钾粒度小的问题,采用软钾镁矾和氯化钾为原料,分别以不同的加料速率、搅拌速率、反应温度、加入晶种的量进行了反应结晶实验。研究结果表明,随加料速率的增大,硫酸钾晶体的成核速率和生长速率增大,产品平均粒径减小;随搅拌速率的增大,成核速率增大,生长速率减小,产品平均粒径减小;晶体成核速率和生长速率受温度影响较小;随着加入晶种量的增大,晶体成核速率先减小后增大,生长速率先增大后减小,并首次建立了硫酸钾反应结晶动力学模型。在优化条件下,实验产品的平均粒径最大可达394.3μm。     

冬季自然冷却法除硝方案

通过工艺计算和试验验证,制定了冬季自然冷却除硝法的实施方案并付诸实施,取得了较好的效果。     

Influences of heat-treatment on the microstructure and properties of silica–titania composite aerogels

Silica–titania composite aerogels were synthesized via ambient pressure drying by using water glass and titanium tetrachloride as raw materials. The influences of heat-treatment at different temperature with different heating rate on the microstructure and properties of the composite aerogels were investigated by differential thermal analyzer, Fourier transform infrared spectrometer, X-ray diffraction, nitrogen adsorption–desorption, scanning electron microscope and transmission electron microscope analysis. The results indicate that the silica–titania composite aerogels heat-treated at 250 °C exhibited highest specific surface area, pore volume and average pore diameter. When the heat-treatment temperature was higher than 450 °C, the –CH₃ groups on the surface of silica–titania composite aerogels would transform into –OH groups gradually, and in the meantime, the composite aerogels network structure would be destroyed gradually and the crystallinity of TiO₂ would be improved with the increase of heat-treatment temperature. Particularly, heat-treatment at temperatures above 750 °C would cause serious damage to the network structure of the composite aerogels. The adsorption/photocatalytic activity experiments showed that the composite aerogels heat-treated at 550 °C exhibit highest darkroom adsorption efficiency, and the 650 °C-heat-treated samples exhibited highest efficiency for removing the Rhodamine B from water.     

Enantioselective Construction of Cyclic Enaminone‐Based 3‐Substituted 3‐Amino‐2‐oxindole Scaffolds via Catalytic Asymmetric Additions of Isatin‐Derived Imines

The first catalytic asymmetric construction of the cyclic enaminone‐based 3‐substituted 3‐amino‐2‐oxindole scaffold with potential bioactivity has been developed via chiral phosphoric acid‐catalyzed enantioselective addition reactions of cyclic enaminones to isatin‐derived imines, which afforded a series of cyclic enaminone‐based 3‐substituted 3‐amino‐2‐oxindoles in high yields and excellent enantioselectivities (up to 99% yield, 97% ee). The investigation of the reaction mechanism suggested that it was facilitated by a dual hydrogen‐bonding activation mode between the two substrates and the chiral phosphoric acid. Besides, this method could be utilized for a large‐scale synthesis with maintained enantioselectivity. This approach will not only offer a useful method for enantioselective construction of the cyclic enaminone‐based 3‐substituted 3‐amino‐2‐oxindole scaffold, but also enrich the research on catalytic asymmetric addition reactions of isatin‐derived imines by using electron‐rich olefins as nucleophiles. More importantly, a preliminary evaluation on the cytotoxicity of some selected products revealed that two of the enantio‐pure compounds exhibited moderate to strong cytotoxicity to A549, 786‐0, ECA109 and BT474 cancer cell lines.