Structure and red emissions of Eu3+-doped hydrocalumite prepared in ethanol/water media

Eu~(3+)-doped hydrocalumites (Eu~(3+)-doped CaAl-LDH) were prepared in an ethanol/water media. Various techniques, including inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray diffraction (XRD), and fluorescent spetctra (FL), etc., were employed to study the structure, composition,and fluorescence of samples. Compositional analyses reveal that the contents of all the elements calculated from the chemical formula are close to that of the actual found from measurement. XRD results suggest that the samples with different molar ratios of Ca~(2+)/(Al~(3+)+Eu~(3+)) present typical layered structure. Moreover, all the samples exhibit monoclinic structure. Fluorescent spectra show strong red emissions ascribed to~5D_0→~7F_J(J=1, 2) transitions of Eu3+ions for all the Eu~(3+)-doped hydrocalumites,revealing that the hydrocalumite is favorable for the emission of Eu~(3+). The Eu~(3+)-doped hydrocalumite may be a latent fluorescent material applied in biological or medical fields in consideration of the biocompatibility of Ca~(2+) ions and fluorescent property of Eu~(3+) ions.     

Fenton 絮凝工艺去除废水中的有机物试验

为了研究废水中有机物的去除问题,针对某企业含有机物废水进行了对比试验,采用了Fenton 絮凝联合工艺去除废水中的COD（化学需氧量）和浊度,考察了初始pH值、H2O2投加量、H2O2与Fe2+投加物质的量比、反应时间、絮凝剂投加量以及絮凝剂投加时的pH值对COD以及浊度去除效果的影响。结果表明,采用最佳工艺参数组合后,浊度去除率和COD的去除率分别为99.32%和97.27%。     

Microstructural and Mechanical Characteristics of Porous Irons Produced with Small Particle Size Corn Starch

Powder Metallurgy and Metal Ceramics - The space holder technique was widely used in manufacturing high melting-point porous metals. Corn powders with a smaller size (11.4 μm on average) than...     

轧制工艺对VN微合金化厚钢板截面不均匀性的影响

在厚板轧制过程中,由于板厚所引起的由表面到心部变形不均匀,将导致组织与力学性能沿厚度方向上有较大差异,最终影响钢板的整体质量.因此合理选择控轧工艺对于厚板生产至关重要.该研究采用有限元方式模拟了50 mm厚板的轧制过程,得出了不同轧制条件下的厚板截面不同位置的变形情况.同时结合Gleeble热模拟实验,研究了不同控轧工艺对VN微合金化50 mm厚钢板截面效应的影响.结果表明,对于VN微合金化厚板,870 ℃终轧并保温可得到最佳的截面均匀性.     

Combination Strategy of Genetic Dereplication and Manipulation of Epigenetic Regulators Reveals a Novel Compound from Plant Endophytic Fungus

The strategies of genetic dereplication and manipulation of epigenetic regulators to activate the cryptic gene clusters are effective to discover natural products with novel structure in filamentous fungi. In this study, a combination of genetic dereplication (deletion of pesthetic acid biosynthetic gene, PfptaA) and manipulation of epigenetic regulators (deletion of histone methyltransferase gene PfcclA and histone deacetylase gene PfhdaA) was developed in plant endophytic fungus Pestalotiopsis fici. The deletion of PfptaA with PfcclA and/or PfhdaA led to isolation of 1 novel compound, pestaloficiol X (1), as well as another 11 known compounds with obvious yield changes. The proposed biosynthesis pathway of pestaloficiol X was speculated using comparative analysis of homologous biosynthetic gene clusters. Moreover, phenotypic effects on the conidial development and response to oxidative stressors in the mutants were explored. Our results revealed that the new strain with deletion of PfcclA or PfhdaA in ΔPfptaA background host can neutralise the hyperformation of conidia in the PfptaA mutant, and that the ΔPfptaA ΔPfhdaA mutant was generally not sensitive to oxidative stressors as much as the ΔPfptaA ΔcclA mutant in comparison with the single mutant ΔPfptaA or the parental strains. This combinatorial approach can be applied to discover new natural products in filamentous fungi.     

手持式激光测距仪"测距标准偏差综合评定"的扩展不确定度

在确定的函数关系(数学模型)中,因变量(输出量)随自变量(输入量)的变化规律完全由数学逻辑所确定,自变量到因变量的传递系数(灵敏系数)也可由因变量的标准差和自变量的标准差之比所决定,而与自变量的来历(测量的或者给定的)没有关系[1].本文根据这一基本原理,采用模拟自变量随机变化的方法,成功计算了手持式激光测距仪的测距固定偏差和比例偏差系数的测量不确定度,从而计算出测距标准差综合评定的扩展不确定度,同时解决了复杂的数学模型中多个输入量到输出量的灵敏系数和输出量的不确定度的计算问题.     

Comparison of the Antimicrobial and Sanitizer Resistance of Salmonella Isolates from Chicken Slaughter Processes in Korea

Salmonella is a foodborne pathogen worldwide. Outbreaks of Salmonella are commonly associated with consumption of contaminated foods such as poultry products. Therefore, the objective of this study was to determine the occurrence, biofilm formation, antibiotic resistance, and sanitizer resistance of Salmonella enterica isolated from chicken carcasses. A total of 318 samples were collected from 15 chicken slaughterhouses in 8 provinces of Korea. They were then examined for Salmonella contamination. S. enterica isolates were tested for their susceptibilities to 15 antimicrobials by broth microdilution method. Their biofilm formation ability and resistance to sanitizers were also evaluated. Eighty‐two isolates of S. enterica were obtained from the 318 samples. There were 14 serotypes and 2 untypable isolates. Fifty‐seven (69.5%) isolates were resistant to at least one antibiotic while 30 (36.6%) isolates were resistant to 5 or more antibiotics. Two S. Senftenberg and 3 S. Montevideo isolates exhibited considerable biofilm formation ability (A₆₀₀>0.2) following incubation in Luria‐Bertani (LB) broth for 48 h. Biofilm cell survival and recovery growth assay after sanitization showed that most isolates were highly susceptible to 2.5% lactic acid and 0.1% cetylpyridinium chloride. Therefore, lactic acid and cetylpyridinium chloride might be alternatively or additionally used in addition to chlorine‐based sanitizers that are frequently used to reduce Salmonella contamination of chicken carcasses. Our results provide basic information on the distribution of Salmonella serotypes in chicken slaughterhouses. This study also highlights the necessity to improve farming practices and use antimicrobial agents cautiously. This study also suggests that sanitization during the slaughtering process might be necessary to reduce Salmonella contamination of chicken carcasses.     

快速气相色谱法测定烟草中有机氯农药残留

建立了一种同时测定烟草中17种有机氯农药残留量的毛细管气相色谱分析方法。样品在索格利特萃取器中用正己烷和弗罗里硅土一步提取和净化,采用SE-54弹性毛细管柱,GC-ECD(Ni63)检测,外标法定量。试验表明,样品的加标回收率在75.14%~106.93%,相对标准偏差(RSD)为1,52%~16,99%,并对3个不同产地的烟叶样品进行了实际有机氯农药残留量的测定。      

甘蔗渣纤维表面Zeta电位变化特性及其对酶水解效果的影响

将纤维素原料降解为可发酵糖是木质纤维素生物质生物转化乙醇过程中的重要环节,通过对原料的预处理可以提高纤维素酶的催化效率.本文通过改变甘蔗渣纤维的尺寸、添加多聚磷酸盐等方法,发现均能改变蔗渣纤维的表面Zeta电位.初步研究了其Zeta电位变化规律及Zeta电位的变化对纤维素酶水解效果的影响,并对Zeta电位的变化影响纤维...     

羟丙基磷酸交联糯玉米淀粉的性质及其作为面条品质改良剂的研究

研究了羟丙基磷酸交联糯玉米淀粉的糊化特性、糊的透明度和冻融稳定性 ,并将其添加到普通面粉中制作面条 ,结果表明 ,它可显著改善面条的烹煮特性和感官品质