Polymerization of epoxides catalyzed by a mixed‐valent iron trifluoroacetate [Fe3O(O2CCF3)6(H2O)3]

The readily available mixed‐valent iron trifluoroacetate complex [Fe₂^IIIFe^II(µ₃‐O)(O₂CCF₃)₆(H₂O)₃] is an effective catalyst for the polymerization of epoxides. A very small amount of the catalyst (1.0–0.01 mol%) could initiate the polymerization of cyclohexene oxide, cyclopentene oxide and epichlorohydrin. Based on quantitative end‐group analysis by ¹⁹F NMR spectroscopy, a Lewis acid (LA^⊕) catalyzed anionic reaction mechanism is proposed. Copyright © 2012 Society of Chemical Industry     

The effect of liposome on dyeing mohair/wool blends

The aim of this study was to examine the use of liposome in the dyeing of wool and mohair fibres with acid dyestuffs. Soybean lecithin and cholesterol were used to form the liposome membrane utilised in the dyebath. Liposome production was performed according to the thin lipid layer method (Bangham Method) using a rotary evaporator. Two different forms of liposome were used for dyeing wool and mohair fibres. In its first form, liposome was utilised as an auxiliary agent, where it was added to a conventional dyebath at the beginning of the process. In its second form, dyes were encapsulated with liposome and then used in dyeing. The effects of these two different forms of liposome were compared with conventional dyeing. Dyeing was carried out at depths of shade of 0.5%, 1.0% and 2.0% using three different concentrations of liposome (0.33%, 0.66% and 1.33%). An analysis of K/S values, fastness to washing, and the alkali solubility of fibres was conducted. The fibre samples dyed in the presence of liposome exhibited very good fastness to light (grade 8). The wash fastness test results of the liposomal‐dyed samples were significantly better (grade 4‐5) than for those samples which were conventionally dyed. In the presence of liposome, the tensile strength of fibres was 20 gf, whereas it was 11 gf without liposomes.     

Enhanced fracture toughness in carbon-nanotube-reinforced amorphous silicon nitride nanocomposite coatings

Multiwalled-carbon-nanotube (MWCNT)-reinforced silicon nitride coatings were grown to evaluate the toughness contribution of nanotubes in a ceramic coating. An MWCNT array was first grown using catalytic chemical vapor deposition of acetylene on a silicon substrate. This aligned MWCNT preform was then infiltrated with an amorphous silicon nitride matrix by low-pressure chemical vapor deposition of dichlorosilane (DCS) and ammonia (NH₃). The fracture toughness of this material was determined by generating cracks using nanoindentation and then employing finite-element analysis to estimate the bridging toughness contribution of the MWCNTs. The MWCNT bridging toughness of the composites is determined to be ～5.6 MPa m^1/2, which is seven times higher than that of the matrix. The interfacial frictional stress is also estimated and ranges from 7 to 20 MPa.     

Numerical simulation of various cross sectional workpieces using conventional deep drawing and hydroforming technologies

This study focuses on the determination of optimum sheet metal forming process and process parameters for various cross sectional workpieces by comparing the numerical results of high-pressure sheet metal forming, hydro-mechanical deep drawing (DD) and conventional DD simulations. Within the range of each cross section, depth, characteristic dimensions ratio and fillet radius have been altered systematically. Steel of types St14 and DC04 have been used as the specimen material in the numerical analyses and the experimental verification throughout the study. All numerical simulations have been carried out by using a dynamic–explicit commercial finite element code and an elasto-plastic material model. During the analyses each workpiece was simulated by the three competing processes. The results of analyses, such as sheet thickness distribution, necking, forming of radii etc., are used for assessing the success of each forming process alternative. The analyses revealed that depending on the workpiece geometry and dimensional properties certain processes are preferable for obtaining more satisfactory products. Working windows for each process have been established based on the analyzed parameters of the circular, elliptic, rectangular and square cross sectional product geometries. This data is expected to be useful for selecting the appropriate production process for a given workpiece geometry and understand the limits of each sheet metal forming processes.     

Ytterbium (III) oxide reinforced novel TeO2–B2O3–V2O5 glass system: Synthesis and optical,structural, physical and thermal properties

Different samples of xTeO₂.(25-y)B₂O₃.zV₂O₅.yYb₂O₃ (or TBVY) new glass material were synthesized by the classical melt-quenching method. Structural, optical, physical, and thermal analyses of the synthesized glasses were performed in addition to Monte Carlo simulation to test radiation shielding properties. The results showed that increasing ratios of Yb₂O₃ (y = 0.0, 0.5, 1.0, and 1.5 mol%) produced monotonic density values of the synthesized glasses ranging from 4.70058 g cm^?3 to 5.01038 g cm^?3. XRD and FTIR analyses were used to confirm the glass structure of all samples. Optical transmittance and absorption parameters varied almost monotonically with increasing ratios of Yb₂O₃ indicating the ability to predict and control these properties using Yb₂O₃ additive. Furthermore, simulated radiation interaction parameters, such as attenuation coefficients and half-value layer, exhibited well-behaved dependence on the concentration ratio of the Yb₂O₃ additive. This approach to glass material synthesis demonstrate the useful synergetic effect of combining structural, optical, and radiation characteristics.     

Regulatory reform in Turkish energy industry: An analysis

The Republic of Turkey has initiated an ambitious reform program in the most important segments of her energy market; which requires privatization, liberalization as well as a radical restructuring of these industries. However, there is no consensus that the measures introduced are optimal. The present article attempts, first, to evaluate the regulatory framework created by the laws of 2001 in terms of economic efficiency considerations; and second, to determine what still needs to be done to improve the current situation. The paper not only provides an analysis of these reforms but also lists some policy suggestions. The study concludes that despite relatively good legislative framework, in practice, the reforms in Turkey are far from ideal as they are mainly in the form of “textbook reforms”; and therefore a significant amount of work still lies ahead of Turkey to set up a fully fledged energy market.     

Electricity demand analysis using cointegration and ARIMA modelling: A case study of Turkey

In the early 2000s, the Republic of Turkey has initiated an ambitious reform program in her electricity market, which requires privatization, liberalization as well as a radical restructuring. The most controversial reason behind, or justification for, recent reforms has been the rapid electricity demand growth; that is to say, the whole reform process has been a part of the endeavors to avoid the so-called “energy crisis”. Using cointegration analysis and autoregressive integrated moving average (ARIMA) modelling, the present article focuses on this issue by both providing an electricity demand estimation and forecast, and comparing the results with official projections. The study concludes, first, that consumers’ respond to price and income changes is quite limited and therefore there is a need for economic regulation in Turkish electricity market; and second, that the current official electricity demand projections highly overestimate the electricity demand, which may endanger the development of both a coherent energy policy in general and a healthy electricity market in particular.     

Understanding the Chena Hot Springs,Alaska, geothermal system using temperature and pressure data from exploration boreholes

Chena Hot Springs is a small, moderate temperature, deep circulating geothermal system, apparently typical of those associated to hot springs of interior Alaska. Multi-stage drilling was used in some exploration boreholes and was found to be useful for understanding subsurface flow characteristics and developing a conceptual model of the system. The results illustrate how temperature profiles illuminate varying pressure versus depth characteristics and can be used alone in cases where staged drilling is not practical. The extensive exploration activities helped define optimal fluid production and injection areas, and showed that the system could provide sufficient hot fluids (∼57 °C) to run a 400-kWe binary power plant, which came on line in 2006.     

New low component count floating inductor simulators consisting of a single DDCC

In this paper, five novel and minimum number count floating inductor simulators (FIs) are proposed. Three of the presented FIs depending on the passive component choice can provide parallel R–L, (–R)–(–L) and series R–L, (–R)–(–L) from the same configuration while other two provide one of parallel R–L or series R–L. Some of the introduced positive lossy inductor simulators employ a grounded capacitor; accordingly, they are convenient for integrated circuit (IC) implementation. So as to exhibit the performance of the proposed structures, computer simulations based on SPICE program are given.