Impacts of changing the minimum diameter of roundwood on the accumulation of logging residue in first thinnings of Scots pine and Norway spruce

The aim of this study was to examine the impacts of different minimum top diameters of roundwood on the accumulation of logging residue in first thinnings of Scots pine and Norway spruce. The aim was also to compare estimates of residue accumulation calculated by tree-specific models with field measurements from thinnings. Felling experiments were performed in young pine and spruce stands to evaluate the model calculations. The felling was performed by a harvester with a single-grip harvester head. Sample trees were felled and processed to a minimum diameter of 12, 10, 8 and 6 cm and the delimbed branches and stem wood between these cutting points were weighed. The mean relative masses of the tree tops of spruce were nearly doubled with each increment of 2 cm in the top diameter. Respectively in pine, the mean relative tree top mass was increased by 50-60% when the top diameter was increased by 2 cm. The mass of total residue (tree top and all delimbed branches) was similarly increased, but the differences were not as large. Compared to pine, smaller variation in the crown mass of the spruce sample resulted in a more accurate model prediction of the mass of tree tops and total residue. The results of this study suggest that the biomass quantity and distribution of a small amount of trees cannot be predicted very reliably, but when these results are generalized to stand-level, the model predictions can be improved to a practicable level.     

Microchip technology in mass spectrometry

Microfabrication of analytical devices is currently of growing interest and many microfabricated instruments have also entered the field of mass spectrometry (MS). Various (atmospheric pressure) ion sources as well as mass analyzers have been developed exploiting microfabrication techniques. The most common approach thus far has been the miniaturization of the electrospray ion source and its integration with various separation and sampling units. Other ionization techniques, mainly atmospheric pressure chemical ionization and photoionization, have also been subject to miniaturization, though they have not attracted as much attention. Likewise, all common types of mass analyzers have been realized by microfabrication and, in most cases, successfully applied to MS analysis in conjunction with on‐chip ionization. This review summarizes the latest achievements in the field of microfabricated ion sources and mass analyzers. Representative applications are reviewed focusing on the development of fully microfabricated systems where ion sources or analyzers are integrated with microfluidic separation devices or microfabricated pums and detectors, respectively. Also the main microfabrication methods, with their possibilities and constraints, are briefly discussed together with the most commonly used materials. © 2009 Wiley Periodicals, Inc., Mass Spec Rev 29:351‐391, 2010     

Occupational exposure to RF fields from base station antennas on rooftops

At specific situations, workers need to approach very close to the transmitting base station antennas. In this study, occupational exposure to RF fields from base station antennas was assessed at several rooftops. The measurements were carried out by mapping the power densities around the antennas. The results were compared with the ICNIRP guidelines. The results indicate that the reference levels for workers and the general public may be exceeded in front of the transmitting antenna at distances up to 1 and 2 m, respectively.     

Comparison of direct and alternating current vacuum ultraviolet lamps in atmospheric pressure photoionization

A direct current induced vacuum ultraviolet (dc-VUV) krypton discharge lamp and an alternating current, radio frequency (rf) induced VUV lamp that are essentially similar to lamps in commercial atmospheric pressure photoionization (APPI) ion sources were compared. The emission distributions along the diameter of the lamp exit window were measured, and they showed that the beam of the rf lamp is much wider than that of the dc lamp. Thus, the rf lamp has larger efficient ionization area, and it also emits more photons than the dc lamp. The ionization efficiencies of the lamps were compared using identical spray geometries with both lamps in microchip APPI mass spectrometry (μAPPI-MS) and desorption atmospheric pressure photoionization-mass spectrometry (DAPPI-MS). A comprehensive view on the ionization was gained by studying six different μAPPI solvent compositions, five DAPPI spray solvents, and completely solvent-free DAPPI. The observed reactant ions for each solvent composition were very similar with both lamps except for toluene, which showed a higher amount of solvent originating oxidation products with the rf lamp than with the dc lamp in μAPPI. Moreover, the same analyte ions were detected with both lamps, and thus, the ionization mechanisms with both lamps are similar. The rf lamp showed a higher ionization efficiency than the dc lamp in all experiments. The difference between the lamp ionization efficiencies was greatest when high ionization energy (IE) solvent compositions (IEs above 10 eV), i.e., hexane, methanol, and methanol/water, (1:1 v:v) were used. The higher ionization efficiency of the rf lamp is likely due to the larger area of high intensity light emission, and the resulting larger efficient ionization area and higher amount of photons emitted. These result in higher solvent reactant ion production, which in turn enables more efficient analyte ion production.     

Measurement of the trapping efficiency of an elliptical optical trap with rigid and elastic objects

Optical tweezers and their various modifications offer a sophisticated way to perform noncontact cell manipulation. In this paper, we quantify forces existing in an elliptical trap formed by two cylindrical lenses and compare the results with a point optical trap case. The trapping efficiency of point and elliptical traps was analyzed by measuring the Q values of both traps. Polystyrene microspheres and red blood cells (RBCs) were used as samples. Stretching of the RBC was taken into account in the Q value measurements. Although the Q value of a point optical trap is larger than that of an elliptical trap when measured for a single RBC, we can manipulate the orientation of an RBC in a point trap with the elliptical trap and can also trap several RBCs simultaneously in the elliptical trap far from the cuvette surfaces by using a long-working-distance water immersion objective. This opens new possibilities for studying light-matter interactions at the cellular level.     

Atmospheric pressure photoionization-mass spectrometry with a microchip heated nebulizer

A novel, microfabricated heated nebulizer chip for atmospheric pressure photoionization-mass spectrometry (APPI-MS) is presented. The chip consists of fluidic and gas inlets, a mixer, and a nozzle etched onto silicon wafer that is anodically bonded to a Pyrex glass wafer, on which an aluminum heater is sputtered. A krypton discharge lamp is used as the source for 10-eV photons to initiate the photoionization process. Dopant, delivered as part of the sample solution, is used to achieve efficient ionization. The use of the microfabricated heated nebulizer with APPI in the analysis of four analytes is demonstrated, and the spectra are compared to those obtained with a conventional APPI source. Ionization in positive and negative ion modes was successfully achieved and the spectra were mainly similar to those obtained with conventional APPI, indicating that the ionization in microfabricated and conventional APPI sources takes place by the same mechanisms. The flow rates with conventional APPI are approximately 100 muL/min, whereas the microchip heated nebulizer allows the use of flow rates 0.05-5 muL/min, thus being compatible with microfluidic separation systems or micro- and nano-LC. A stable signal was demonstrated throughout a 5-h measurement, which proved the excellent stability of the micro-APPI. The same heated nebulizer chip can be used for weeks.     

Physico-chemical characterization of poly(vinyl chloride). I. Solution properties

Poly(vinyl chloride) was fractionated and its solution properties were studied. Calibration of the gel permeation chromatograph was carried out using poly(vinyl chloride) and polystyrene. Empirical correlations were established for the calibration plots.     

The clinical outcome in pregnancies of grand grand multiparous women

Recent public health concern about the Jacob-Creutzfeld disease related to administration of growth hormone in children or the "mad cow" disease in cattle fed contaminated products requires a review of the association between Jacob-Creutzfeldt disease and pregnancy. Four cases of this transmissible spongiform encephalopathy have been described in pregnant women and none of the offspring, currently 22, 10, 7 and 3 years of age, have developed the disease. Vertical transmission of Jacob-Creutzfeldt disease cannot however be excluded as it occurs in animals and since injections of cord blood and placenta extracts of women with this disease into mice brains has proven the presence of the infectious agent. The rarity of Jacob-Creutzfeldt disease in women of reproductive age and the particularly long incubation period of this type of encephalopathy would incite prudence and long-term follow-up to determine outcome in children born from disease women or who developed signs of the disease during the years following delivery.     

Diel patterns in spatial distribution of fish assemblages in lentic and lotic habitat in a regulated river

Fish assemblages in large rivers are governed by spatio‐temporal changes in habitat conditions, which must be accounted for when designing effective monitoring programmes. Using boat electrofishing surveys, this study contrasts species richness, catch per unit effort (CPUE), total biomass, and spatial distribution of fish species in the Saint John River, New Brunswick, Canada, sampled during different diel periods (day and night) and macrohabitats (hydropower regulated river and its reservoir) in the vicinity of the Mactaquac (hydropower) Generating Station. Taxa richness, total CPUE, and total biomass were significantly higher during night surveys, resulting in marked differences in community composition between the two diel periods. Furthermore, the magnitude of diel differences in catch rate was more pronounced in lentic than in lotic macrohabitats. The required sampling effort (i.e., number of sites) to increase accuracy and precision of CPUE estimates varied widely between fish species, diel periods, and macrohabitats and ranged from 15 to 185 electrofishing sites. Determining a correction factor to contrast accuracy and precision of day‐ with night‐time surveys provide useful insights to improve the design of long‐term monitoring programmes for fish communities in large rivers. The study also shows the importance of multihabitat surveys to detect differences in the magnitude of diel changes in fish community metrics.