Inorganic–organic hybrid materials with zirconium oxoclusters as protective coatings on aluminium alloys

Inorganic–organic hybrid materials are attracting a strong scientific interest mainly for their outstanding inherent mechanical and thermal properties, which can be traced back to the intimate coupling of both inorganic and organic components. By carefully choosing the experimental parameters used for their synthesis, chemically and thermally stable acrylate-based hybrid material embedding the zirconium oxocluster Zr₄O₄(OMc)₁₂, where OMcCH₂C(CH₃)C(O)O, can be deposited as UV-cured films on aluminium alloys.

In particular, the molar ratios between the oxocluster and the monomer, the polymerisation time, the amount of photo-initiator and the deposition conditions, by using an home-made spray-coating equipment, were optimised in order to obtain the best performing layers in terms of transparency and hardness to coat aluminium alloy (AA1050, AA6060 and AA2024) sheets. Furthermore, it was also evaluated whether the hybrid coatings behave as barrier to corrosion.

Several coated samples were prepared and characterised. Environmental scanning electronic microscopy (ESEM) and scratch test were used to investigate the morphology of the films and to evaluate their scratch resistance, respectively. Electrochemical impedance spectroscopy (EIS) was performed in order to evaluate if the coatings actually protect the metallic substrate from corrosion.

In order to measure shear storage modulus (G′) and loss modulus (G″) of the materials used for coatings, bulk samples were also obtained by UV-curing of the precursors solution. Dynamical mechanical thermal analysis (DMTA) was performed in shear mode on cured disks of both the hybrid materials and pristine polymer for comparison. The values of T_g were read off as the temperatures of peak of loss modulus. The length and mass of all the samples were measured before and after the DMTA analysis, so that the shrinkage of the materials in that temperature range was exactly evaluated.     

Effect of Bonder at Skin/Core Interface on the Mechanical Performances of Sandwich Structures Used in Marine Industry

The present work is aimed to extend the knowledge of mechanical properties of sandwich structures used for marine applications focusing on the possibility to increase the performances of such structures by adding a bonder at the skin/core interface. Therefore, three sandwich structures that are utilised in different structural components of a yacht were realised by manual lay-up. The mechanical characterisation was performed by flatwise compressive, edgewise compressive and three point flexural tests. The tests execution has allowed both to determine the mechanical performances and to understand the fracture mechanisms that take place when the bonder is added in the stacking sequence of the samples.     

纵横波联合反演在苏里格含气性检测中的应用

苏里格气田目的层属于辫状河和曲流河沉积环境下的多种砂体组合，而且含气层速度值与泥岩的速度值有较大的重叠。因此，单纯纵波反演在该地区不能有效地剔除低速泥岩，区分致密砂岩与有效砂岩。AVO理论和实践证明，含气砂岩随饱和度的下降，纵波速度明显变化，而横波速度变化较小。纵横波联合反演可得到纵波阻抗和横波阻抗，进而可有效区分岩性。纵波阻抗和横波阻抗的比值，可消除密度项得到纵横波速度比。根据Aki Richards公式可知，在纵横波速度比为1.5左右时，可确定砂岩含气。据此，在推导纵横波联合反演公式和确定反演过程的基础上，对苏里格气田某测线进行纵横波联合反演，得到纵波阻抗、横波阻抗和纵横波速度比，从而确定了低速泥岩、致密砂岩与有效砂岩的分布范围。     

天然气长输管道泄漏检测方案对比

大口径、长距离天然气输送管道的泄漏检测和定位技术日益受到人们的重视。总结评价了用于天然气长输管道泄漏检测和安全预警的各种技术方案，讨论了其基本原理、适用范围、技术成熟度、优点和缺点以及工程应用情况；采用灵敏度、定位精度等7项技术指标对各种泄漏检测方法进行了评价和对比。目前，音波泄漏检测技术和分布式光纤泄漏检测技术由于具有诸多方面的优点，是近年来国内外泄漏检测技术研究的重点和热点，这两种技术已初步应用于实际，并取得了良好的效果。重点对这两种泄漏检测技术的原理、适用范围、所能达到的技术指标、优、缺点以及工程案例进行了详细讨论、分析和对比，可为我国天然气长输管道泄漏检测和安全预警系统的开发和研究提供技术依据。     

固定化微生物脱除工业酸性废气中H_2S的研究

以H 2软性填料作为氧化亚铁硫杆菌的固定化载体 ,构成了固定床生物反应器。在一定操作条件下 ,考察了固定床生物反应器对Fe2 +的氧化速率 ,最大可达 7.6 7g/ (L·h)。并对固定床生物反应器运行中在载体表面形成的络合物进行了研究 ,X射线衍射证明此络合物为黄钾铁矾 [KFe3(SO4 ) 2 (OH) 6]。     

锌电积的节电探讨

分析厂影响锌电积电能消耗的因素，提出了锌电积的节电对策与展望。     

方圆坯铸机开发新断面自动化程序的实现

文章介绍了包钢连铸机结晶器液位、喷淋水、热坯压力等主要参数实现自动控制的过程,阐述了上述参数如何根据不同铸坯断面而改变,并针对钢厂开发新断面如何实现参数的切换提出解决办法.     

基于显微视觉的宏/微双重驱动微动台的自动标定

提出了基于压电技术的微操作系统的自动标定方法,采用混合式步进电机直接驱动的宏动平台,实现系统大行程宏动定位,安装在宏动平台上的压电陶瓷驱动的微动平台和精密光栅,实现亚微米级的分辨率和定位精度,通过以上两部分实现定位机构的全闭环反馈控制,采用显微视觉反馈获取微动台操作器在图像中的位置信息进行标定。实验结果表明:系统的动态和稳定性能良好,自动标定运算速度快,运行速度达到11 frame/s,实现了对系统的精确标定,标定精度达到0.1μm。