Preparation and properties of high molecular weight poly(1-germa-) or poly(1-sila-cis-pent-3-enes)

High molecular weight poly(1,1-dimethyl-1-germa-cis-pent-3-ene), poly(1,1-diphenyl-1-germa-cis-pent-3-ene), poly(1,1-dimethyl-1-sila-cis-pent-3-ene), and poly(1-methyl-1-phenyl-1-sila-cis-pent-3-ene) have been prepared. The thermal stability of these polymers is found to increase with their molecular weight.     

充气压力对充气工况载重斜交轮胎影响的有限元分析

进行了充气压力对充气工况载重斜交轮胎影响的有限元分析.结果表明,充气工况下,充气压力对斜交轮胎外形轮廓尺寸影响明显,其外直径、断面宽度均随充气压力的增大而增加;充气压力的大小对胎圈接触应力分布影响很小,但胎圈最大接触应力随充气压力的增加而增大.     

Studies on membrane formation mechanism by the light transmission technique. I

New parameters, light transmission rate and minimum light transmissions, are proposed. These two parameters reflect the characteristics of the membrane‐forming system and the formation process of the membranes by phase inversion. The relationship between the light transmission and the porous structure of the membrane can be explained by the geometrical optics principles. Variation of the two parameters combining Reuvers's phase separation theory provided a convenient analytical method to predict effectively membrane morphologies. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 174–181, 2003     

碟式分离机转鼓零件的最宜超转速探讨

本文通过对超速处理后的AISI316L钢的碟式分离机转鼓零件在各种工况下的应力场分析,探讨了分离机转鼓超速自增强的最宜超转速问题,并提出了确定最宜超转速的基本原则和方法.通过分析表明:用本文方法所得到的最宜超转速与已知的国外数据是相当一致的.     

High temperature polymerization of propylene catalyzed by MgCl2‐supported Ziegler–Natta catalyst with various cocatalysts

Four cocatalysts, referred to as ethylaluminoxanes, were synthesized by the reaction between triethylaluminium (AIEt₃) and water under various molar ratios of H₂O/Al at ?78°C. Aluminoxanes were used as cocatalysts for a MgCl₂‐supported Ziegler–Natta catalyst for propylene polymerization at temperatures ranging from 70 to 100°C. When the polymerization was activated by AlEt₃, the activity as well as the molecular weight and isotacticity of the resulting polymer gradually dropped as the temperature varied from 70 to 100°C. When ethylaluminoxane was employed as the cocatalyst, good activity and high molecular weight and isotacticity were obtained at 100°C. Furthermore, when the cocatalyst varied from AlEt₃ to ethylaluminoxane, the atactic fraction and polymer fraction with moderate isotacticity decreased and the high isotactic fraction slightly increased, which indicated that the variation of the cocatalyst significantly affects the isospecificity of active sites. It was suggested that the reactivity of the Al‐Et group and the size of the cocatalyst were correlated to the performance of the Ziegler–Natta catalyst at different temperatures. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1978–1982, 2006     

尿素生产中尿液的不稳定流动对尿素一分塔的影响

介绍了水溶液全循环法尿素生产系统中,一分塔的精馏段由泡罩塔盘改为规整填料后出现的一系列问题,针对尿液的不稳定流动造成一分塔规整填料严重腐蚀的原因,进行分析并提出整改和预防措施。     

防止过拟合的属性约简

近年来,机器学习的过拟合问题备受关注,尤其在属性约简中。为解决这一难题,提出一种融合集成策略和去除操作的算法。首先将训练模型数据平分为◢M份;然后将其中M◣-1份采用集成策略进行潜在约简计算;最后将剩余的一份进行提前测试,一旦发生过拟合则将刚加入的属性从潜在约简集中去除。利用提前测试潜在属性约简的方法来防止过拟合现象的发生,几组UCI数据的实验结果说明了新算法的有效性,同时为丰富和发展属性约简提供了一种新的方向。     

认识隐患预防事故

事故隐患是客观存在的，不论你是否承认，是否意识到，它都存在于企业的生产全过程，而且对员工的人身安全，国家的财产安全和企业的生存、发展都直接构成威胁。正确认识隐患的特征，对熟悉和掌握隐患产生的原因，及时研究并落实防范对策是十分重要的。下面就这方面的问题，谈一点粗浅认识。     

基于分布的中文词表示研究

针对基于分布的中文词表示构造过程中的参数选择问题进行了系统性的研究。选择了六种参数进行对比实验,在中文语义相似度任务上对不同参数设置下得到的中文词表示的质量进行了评估。实验结果表明,通过选择合适的参数,基于分布的词表示在中文语义相似度任务上能够得到较高的性能,而且,这种高维的词分布表示的质量甚至优于目前流行的基于神经网络（Skip-gram）或矩阵分解（GloVe）得到的低维的词表示。     

基于数据密度的半监督自训练分类算法

在实际的分类任务中,无标记样本数量充足而有标记样本数量稀少的情况经常出现,目前处理这种情况的常用方法是半监督自训练分类算法。提出了一种基于数据密度的半监督自训练分类算法,该算法首先依据数据的密度对数据集进行划分,从而确定数据的空间结构;然后再按照数据的空间结构对分类器进行自训练的迭代,最终得到一个新的分类器。在UCI中6个数据集上的实验结果表明,与三种监督学习算法以及其分别对应的自训练版本相比,提出的算法分类效果更好。