高压高温触媒法合成硼-碳-氮化合物

通过实验研究了在各种触媒作用下,乱层石墨结构的硼-碳-氮(B-C-N)前驱物在5.5 GPa和1500℃条件下的晶化与相变规律.采用X射线衍射(XRD)、透射电子显微镜(TEM)以及电子能量损失谱(EELS)对样品进行了结构、形貌和成分分析.结果表明,在Fe触媒作用下,得到了一种结晶很好的六方BC2N化合物,而在Ni,Co,Mg或Li3N触媒作用下,均没有B-C-N相生成.     

双子表面活性剂合成及在酒精废液处理中应用

合成了4种碳链长度的酯基阳离子双子表面活性剂,并作为絮凝剂对干法工艺处理的玉米酒精糟废液进行了絮凝处理实验。絮凝后对废液的透光率及COD进行了测定,考察了在不调节pH值及室温条件下与双子表面活性剂、淀粉阳离子、壳聚糖阳离子对比絮凝处理效果,双阳离子表面活性剂好于淀粉阳离子、壳聚糖阳离子的絮凝能力;同时考察了酯基阳离子双子表面活性剂碳链长度对絮凝效果的影响,碳链长度对COD去除率的高低顺序为C14>C16>C12>C10。实现了不用碱中和废液而直接进行絮凝处理的工艺改造。     

MDD应用于RIA的建模研究

分析RIA技术的特征,研究如何将MDD（模型驱动开发）应用在RIA领域当中,即针对WebML做扩展并模型化RIA应用,完成开发的建模阶段,最后以库存管理系统（IMS）为例给出示意图。     

时延动态神经网络的稳定性分析

基于时延动态网络模型的优化计算易于收敛到非法解或局部极小解,以及其算法对模型参数和初始条件具有很强的依赖性等缺点,对时延动态神经网络的稳定性进行了深入地研究讨论,通过Razumikhin-type定理对时延动态神经网络的稳定性进行了分析研究.     

核电SA508-3钢在不同冷速下的显微组织

针对由某公司生产首次应用到核电上的SA508-3钢,采用膨胀法在Gleeble1500D热模拟机上测定了其焊接连续冷却转变的膨胀曲线,结合显微组织和硬度,获得了每个冷速下对应的相变点温度.结果表明,在0.015～0.05℃/s冷速范围内.为高温转变的铁素体和珠光体区,0.1～7℃/s冷速范围内,为中温转变的贝氏体区,20～80℃/s的冷速范围内,为低温转变的马氏体区;随着冷却速度的增大,硬度值也越来越大,0.015℃/s对应的硬度值为199 HV,80℃/s对应的硬度值为546 HV,这为制定合理的焊接工艺提供了依据.     

Carbon spheres prepared via solvent-thermal reaction method and their microstructures after high temperature treatment

Carbon spheres with size of 50–300 nm were synthesized via a solvent-thermal reaction with calcium carbide and chloroform as reactants in a sealed autoclave. The morphologies and microstructures of carbon spheres before and after high temperature treatment (HTT) were characterized by X-ray diffractometry (XRD), scanning electronic microscopy (SEM), energy diffraction spectroscopy (EDS), and transmission electron microscopy (TEM). The formation mechanism of carbon spheres was discussed. The results indicate that the carbon spheres convert to hollow polyhedron through HTT. Carbon spheres are composed of entangled and curve graphitic layers with short range order similar to cotton structure, and carbon polyhedron with dimension of 50–250 nm and shell thickness of 15–30 nm. The change of solid spheres to hollow polyhedron with branches gives a new evidence for formation mechanism of hollow carbon spheres.     

基于组合单元的圆钢管混凝土结构非线性分析

基于圆钢管混凝土组合截面轴力-应变关系和轴力一弯矩一曲率关系实用计算方法,采用U.L列式单元增量平衡方程,引入平面梁单元非线性分析方法,建立了钢管混凝土结构组合单元法非线性有限元分析理论.编制了相应的非线性有限元程序,对已有钢管混凝土结构的面内受力,如钢管混凝土偏压柱、不等端弯矩钢管混凝土偏压柱、钢管混凝土压弯构件和钢管混凝土模型拱肋等进行双重非线性有限元分析,与基于钢管混凝土拉压数值本构模型的分层梁单元非线性分析理论比较.结果表明,两种分析方法的载荷一变形曲线和极限承载力都很接近试验结果,与分层法相比,组合单元法直接根据杆端力求解截面刚度,不用分层计算截面刚度,加快了计算速度.     

应力型大模面积光子晶体光纤的纤芯设计

通过施加完美匹配层,利用有限元法,研究热应力诱导的单偏振大模面积光子晶体光纤的偏振特性,计算纤芯参数对场能量分布系数和偏振损耗比的影响.结果表明,随着纤芯折射率提高,两正交偏振模的损耗比下降,当纤芯直径减小时,场能量分布系数降低.     

Influence of nitrogen hetero-substitution on the electrochemical performance of coal-based activated carbons measured in non-aqueous electrolyte

Nitrogen-containing carbons were prepared by modification of activated carbons. The modified carbons were used as electrode materials with improved electrochemical performance. Precursor anthracite was activated by KOH (KOH: anthracite= 1:1), modified by melamine or urea and then treated at 1173 K to obtain the modified carbons. The porous structure, the chemical composition and the electrochemical characteristics of the carbons were investigated by nitrogen sorption, XPS and electrochemical methods respectively. Electrochemical experiments were performed in an organic electrolytic solution of 1 M (C2H5)4NBF4/PC.The samples modified by the different methods showed differences in chemical composition that introduced varying degrees of electrochemical performance enhancement. The presence of nitrogen enhanced the electron donor properties and the surface wettability of the activated carbons: this ensured a sufficient utilization of the exposed surface for charge storage.     

复合掺杂Nd（III）和Zn（II）非晶态Ni（OH）2电极活性材料的制备及其表征

以NiSO4、ZnSO4和Nd（NO3）3为原料,采用共沉淀快速冷冻法制备出了复合掺杂稀土Nd（III）和Zn（II）的非晶态氢氧化镍粉体材料。测试发现：样品材料微结构无序性强,结晶水含量较高。将样品材料制备成镍电极并组装成MH—Ni电池,在80mA／g恒电流充电5．5h、40mA／g恒电流放电、终止电压为1．0V的充放电制度下,复合掺杂6％Nd（III）和6％Zn（II）样品材料电池的放电平台为1．2624V,放电比容量为343．12mAh／g,远高于目前应用的B-Ni（OH）2电极活性材料的放电比容量。