Acidic polyelectrolyte copolymers containing 2-hydroxyethyl methacrylate (HEMA), methyl methacrylate (MMA), and methacrylic acid (MAA) were prepared by free radical polymerization to high conversion in solution. Copolymer yields were obtained by gravimetry (all in the 30–50% range), relative molecular weights estimated by intrinsic viscosity measurements (all in the 50–70 cc/g range), tacticity by 13C nuclear magnetic resonance (NMR) spectroscopy (all polymers predominantly syndiotactic with some atactic content), and composition by acid/base titrations in conjunction with 1H-NMR spectroscopy (all close to the monomer charge ratios). Acid strengths or apparent pKa's were examined as a function of extent of ionization. Measurements performed in water indicated that the compact/extended coil transformation in predominantly syndiotactic polymethacrylic acid occurs also in copolymers of similar tacticity containing moderate to high concentrations of MAA. The apparent pKa of such polymers containing only small amounts of MAA did not vary with extent of ionization, indicating a low degree of interaction between the acid groups. In copolymer pairs containing similar amounts of MAA but differing HEMA and MMA contents, the polymer containing more HEMA appeared the stronger acid, presumably due to a better solvation of that polymer which would increase the net spatial charge–charge separation and decrease cooperative effects that lead to suppressed ionization. 相似文献
3D movies/videos have become increasingly popular in the market; however, they are usually produced by professionals. This paper presents a new technique for the automatic conversion of 2D to 3D video based on RGB-D sensors, which can be easily conducted by ordinary users. To generate a 3D image, one approach is to combine the original 2D color image and its corresponding depth map together to perform depth image-based rendering (DIBR). An RGB-D sensor is one of the inexpensive ways to capture an image and its corresponding depth map. The quality of the depth map and the DIBR algorithm are crucial to this process. Our approach is twofold. First, the depth maps captured directly by RGB-D sensors are generally of poor quality because there are many regions missing depth information, especially near the edges of objects. This paper proposes a new RGB-D sensor based depth map inpainting method that divides the regions with missing depths into interior holes and border holes. Different schemes are used to inpaint the different types of holes. Second, an improved hole filling approach for DIBR is proposed to synthesize the 3D images by using the corresponding color images and the inpainted depth maps. Extensive experiments were conducted on different evaluation datasets. The results show the effectiveness of our method.
Information Systems Frontiers - System logs that trace system states and record valuable events comprise a significant component of any computer system in our daily life. Each log contains... 相似文献