矩形坯连铸生产CrMo系列汽车用钢

简述汽车用钢的发展,对首钢采用BOF-LF精炼-矩形坯连铸-优质棒材轧制工艺路线生产CrMo系列汽车用钢的情况进行总结,认为工艺设计合理顺行.     

空气-乙炔碳氮氧离子多元共渗工艺研究

用空气-乙炔混合气体作为气源,对40Cr钢进行了离子碳氮氧多元共渗;用光学金相显微镜、X射线衍射仪和显微硬度计,对渗层形貌、物相和显微硬度进行了分析检测。结果表明:乙炔浓度是影响性能的关键因素,它对硬度、物相起着决定性的作用。与常规离子渗氮相比,以空气-乙炔混合气体作为气源的碳氮氧离子多元共渗工艺操作简便,成本低廉。     

Research of quasi-solid fracture behavior of casting Al-4.5Cu alloys

The influencing mechanisms of elements Ti and Ce and their interactions on fracture behaviors of casting alloys Al-4.5Cu-0.6Mn were studied by observing tensile fracture behavior in quasi-solid zone under SEM and EDX instruments.The results indicate that the resistance stress against hot cracking can be improved obviously by addition of Ti, because of its grain refining function. It is also found that, when Ce is added into the alloys, besides its effect in refining crystalline, the mechanical behavior of lower melting point eutectic phase in quasi-solid zone can be improved efficiently by some compounds with Ce formed and deposited between dendrites. Therefore, a coiligating effect of Ti and Ce on improving resistance stress against hot cracking is more efficient than that only single alloy element is applied. When hot cracking occurs, grains yield at first, and then crack spreads. Both inter-grain and trans-grain fractures are observed, but the major fracture manner is brittleness.     

Ti3SiC2在900℃与1000℃下的热腐蚀行为

研究了Ti3SiC2三元层状陶瓷材料在900和1000℃下由Na2SO4盐膜引起的热腐蚀行为，用XRD及SEM分析了腐蚀产物膜的成分、结构和形貌等。实验表明，腐蚀膜由TiO2和SiO2混合组成：在结构上明显地分成两层，外层晶粒粗大且多孔，内层晶粒细小且致密。Ti3SiC2与熔融盐接触时遭受较严重的腐蚀。     

自生TiC颗粒增强低合金钢基复合材料的组织

通过加入一定量的Mn、Si合金元素,使得TiC颗粒增强低合金钢基复合材料在湿砂型铸造条件下具有自淬火特性,获得单一马氏体组织或马氏体和珠光体的混合基体组织.经过热处理后,基体获得单一马氏体组织.含2.71% Ti的复合材料铸态最高硬度达到55 HRC,热处理硬度59.9 HRC,冲击韧度达到9.17 J/cm2.     

半固态金属金相图片的计算机定量分析

基于Matlab的图形图像处理功能,开发出半固态金属金相组织的计算机分析软件,用以定量地分析半固态金相组织中的非枝晶组织分数(固相率)及晶粒尺寸.并且以镁合金半固态组织为例,与相关文献和目测结果进行了对比,证明该软件具有测量准确,简单容易,方便快捷,适应广泛等特点.     

环氧与酚醛改性环氧涂层固化反应与吸水性关系的研究

采用示差扫描量热分析技术，研究了一种环氧树脂粉末涂料与酚醋改性的该种涂料的固化反应机制和两种涂膜的交联结构，并结合两种涂膜有９０℃蒸馏水中的静态浸泡实验结果，分析了涂膜交联结构对涂膜吸水性的影响。结果表明：酚醛改性环氧粉末涂料的固化反应包括酚醛树脂与一部分环氧树脂的共聚反应，环氧树脂与固化剂的交联反应，以及少量酚醛树脂的自聚反应。而环氧粉末涂料的固化反应只有环氧树脂与固化剂－双氰胺的交联反应。酚醛     

热处理工艺对1Cr22Mn15N不锈钢析出行为的影响

用金相法、电镜观察等分析研究了固溶 时效处理过程中温度、时间对1Cr22Mn15N不锈钢碳(氮)化物析出的影响。结果表明,对于1Cr22Mn15N不锈钢,在试验温度范围内Cr23C6多呈颗粒状、蠕虫状、层片状、菊花状沿晶界分布,并逐渐向晶内生长,而σ相多呈颗粒状析出;得到了其相应的等温析出物动力学曲线,Cr23C6的等温析出的鼻尖温度约为850℃,相应的孕育期为100～180s,950℃以上析出物较少,其中不析出的临界冷却速度约为3.3℃/s;析出物主要是Cr23C6,时效时间越长析出物就越多,随时效时间的延长有少许σ相的析出,氮主要是以Cr23C6和过饱和间隙原子的形式存在。     

Determination of isothermal section of Fe-Ti-Zr ternary system at 1173 K

Phase relations in the Fe-Ti-Zr ternary system at 1173 K were investigated by means of diffusion-triple approach together with electron probe microanalysis（EPMA） technique. A series of tie lines and tie-triangles were determined and the isothermal section at 1 173 K was established, which consists of four three-phase fields： β（Ti, Zr）＋FeZr2＋FeTi, FeZr2＋FeTi＋Fe2Zr, FeTi ＋Fe2Zr ＋Fe2Ti and Fe2Zr ＋Fe2Ti ＋Fe. The results show that the largest solubility of Ti in Fe2Zr is about 11.3 %（mole fraction） and the solid solubility of Ti in FeZr2 is about 26.9%, the solid solubility of Zr in Fe2Ti is about 8.1% and the solid solubility of Zr in FeTi is 7.2%. The binary compound FeZr2 is nearly a linear compound. No ternary compound is found.     

获得贝氏体球铁控制冷却过程研究

测定控制冷却贝氏体球墨铸铁TTT曲线和磨球冷却速度及温度分布发现 :控制冷却贝氏体复相球铁TTT图存在贝氏体区 ,与珠光体区分离 ;控制冷却比浸入式水淬具有均匀的冷却速度和温度分布 ,高温阶段可避开珠光体区 ,低温阶段形成类似等温条件 ,缓慢通过贝氏体区