Effects of surfactant/silica and silica/cerium ratios on the characteristics of mesoporous Ce-MCM-41

Using the surfactant CTMABr (cetyltrimethyl ammonium bromide) and cerium(IV) sulfate, mesoporous Ce-MCM-41 molecular sieves were produced under a hydrothermal condition with various surfactant/silica (surfactant/Si) and silica/cerium (Si/Ce) ratios. Changes to the structural traits caused by changing the molar ratios of both surfactant/Si and Si/Ce were investigated. XRD (X-ray diffraction), FT-IR (fourier transform infrared spectroscopy), and SEM (scanning electro microscopy) were used for the characterization of prepared mesoporous samples. Among the tested molar ratios, surfactant/Si ratio of 0.5 and 0.2 showed highest values of d_1 0 0 and intensity, respectively, for the Si-MCM-41. XRD analysis also identified a quintessential hexagonal structure of Ce-MCM-41 for the Si/Ce molar ratio higher than 40 (maintaining the surfactant/Si ratio at 0.2). When cerium content was increased to have the Si/Ce molar ratio of 20, the hexagonal structure of Ce-MCM-41 was collapsed due to the structural stress of substituted cerium. FT-IR results confirmed calcination of Ce-MCM-41 and the incorporation of Ce⁴⁺ ions of cerium sulfate into the silica surface with proper removal of the surfactant. Rod-like shape with rounded edges of the prepared Ce-MCM-41 samples was identified by SEM. These results suggest surfactant/Si ratio of 0.2 and Si/Ce ratio of 40 for the production of Ce-MCM-41 with the highest level of crystallinity.     

"橄榄型"社会阶层结构范式论

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从2004年开始中国实行“双稳健”的财政、货币政策后，中央宏观调控政策首次改弦易辙，政府的调控目标从2007年的“单防”，转变为“双防”。因此2008年的中央经济工作非同以往。2008年实施从紧的货币政策，与稳健的财政政策配合，尚属于历史首次。     

一部特具匠心的精品教材——评张仲谋《宋词欣赏教程》

张仲谋教授的新著《宋词欣赏教程》，是南京大学出版社出版的“江苏省高等学校精品教材系列”中的一种。该书共8章，既构成一个严谨的教学体系，又多有创新出彩之处；对于词的艺术个性有深刻的把握和精当的阐发；又善于引导学生，循循善诱。该书既是教材，亦具有学术专著的品格。     

提高开卷线纵剪机精度的研究

通过对纵剪机右立柱轴承间隙测量方法和左立柱导向结构的改进，保证了加工精度，易于操作，提高了生产效率。     

集聚纺纱胶辊、胶圈的应用技术探讨

针对集聚纺纱对胶辊、胶圈的技术要求更高的特点,通过试验指出,胶辊硬度低、直径大有利于提高成纱质量.结合生产实践指出,精磨胶辊磨削量以0.2 mm为宜,表面粗糙度Ra值以0.4μm～0.5μm为宜,并适当缩短磨砺周期,牵伸胶辊与牵引胶辊应按比例控制磨削量.胶圈要新旧搭配,并且要及时清洗.     

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介绍了弹力竹节牛仔布的生产工艺 ,同时对KT36 8剑杆织机织造该织物的工艺进行了优化研究     

汽车漆漆膜质量的改进与提高

通过对车身漆膜质量问题的分析,采取专业清洁公司整体承包车间保洁、工艺方面改进、更换生产外材料、供应商加强对汽车漆使用的监控等一系列措施,漆膜质量水平得以提高.