The effect of core-sheath proportion on the characteristics of hollow yarns: part I mechanical properties

In the scope of this study, core yarns in the yarn count of 59 tex were produced by using cotton, viscose, wool, and polyester fibers in the sheath and different ratios of polyvinyl alcohol (PVA) in the core. After completion of yarn production on ring spinning frame, winding process was performed in order to get packages. These yarns in the form of packages were washed during a time period in order to remove PVA from the yarn structures to obtain hollow yarn structure. Yarn irregularity and yarn tensile tests were performed in the form of packages before and after washing process. As a result of these tests; it was observed that values of yarn unevenness and tensile tests were significantly influenced by the core-sheath proportion and washing process.     

The effect of core-sheath proportion on the characteristics of fabrics produced with hollow yarns: part II comfort and mechanical properties

The study aims to investigate the effect of hollow yarn structure and the sheath-core proportion of hollow yarns on the permeability properties of the knitted fabrics. In order to accomplish this, core yarns in the yarn count of 59 tex were produced by using cotton, viscose, wool, and polyester fibers in the sheath and different ratios of polyvinyl alcohol (PVA) in the core. After completion of yarn production on ring spinning frame, the yarns in the form of packages were used to produce plain knitted fabrics. Fabrics were then divided into two groups, one of which was washed during a time period in order to remove PVA from the core to obtain hollow yarn structure. Air and water permeability, and wicking properties of the knitted fabrics were measured before and after washing processes. Mechanical properties such as pilling and bursting strength of the fabrics were also examined. The results show that washing process and PVA proportion used to produce core spun yarns have a significant effect on the permeability and mechanical properties of the fabrics.     

The production of fuel from,and the thermal stability of,sunflower oil,corn oil,and canola oil

Frying of sunflower, corn, and canola oils was carried out for seven running days at 175°C in this study. Fatty acid composition, free fatty acid, viscosity, iodine value, peroxide value, density, pH, saponification value, refractive index, average molecular weight, color, and the higher heating value of these oils have been analyzed. While the contents of free fatty acid, viscosity, saponification value, peroxide value, and colors (red and yellow) increase with the frying times, the contents of average molecular weight, iodine value, pH, and the higher heating value decreased for all oils in this work. However, reduction in the higher heating value is relatively low. This work indicated that recycling as a fuel of these oils can make a major economic contribution.     

Estimation of strength and deformation properties of Quaternary caliche deposits

The aim of this study was to develop and evaluate statistical models for predicting the uniaxial compressive strength (UCS) and average Young’s modulus (E _av) for caliches, using some index and physical properties. The caliche samples, from Adana, southern Turkey, were of low strength and difficult to sample. X-ray diffraction and microscopy were undertaken and the following physical parameters established: unit weight, apparent porosity, Schmidt rebound number, Shore hardness, P-wave velocity, slake durability, point load, uniaxial compressive strength and average Young’s modulus. Simple and linear regression variable selection analyses were performed. The best relationships were obtained for UCS with P-wave velocity and unit weight and for average Young’s modulus with P-wave velocity, porosity and slake durability. Empirical equations are proposed, although it is emphasised that these may only be applicable for caliche of a similar geological character.      

The Synthesis of Boron Carbide Ceramic via Electrospinning Technique

In this study, polyvinyl alcohol (PVA) and boric acid (BA) were mixed in an aqueous medium by heating in order to prepare a PVA/BA hybrid material. The viscosity and pH values of the PVA/BA hybrid material mixed in various proportions were determined. Then the hybrid polymer was electrospun to give dimensions to fibers. The FT-IR spectra of these fibers revealed that BA chemically reacted with PVA and formed B–O–C bonds. The fibers were first calcified at 500 °C and then the calcified products were pelleted and exposed to the sintering process at 1300 °C. The XRD peaks of the sintered product were seen at 2θ = 34.7 and 37.7° verified the formation of boron carbide. The study proved that it was possible to use sub-micron fibers for the production of sub-micron boron carbide material.     

Preparation of Gadolina Stabilized Bismuth Oxide Doped with Boron via Electrospinning Technique

In this study, boron doped and undoped poly (vinyl) alcohol/bismuth–gadolina acetate (PVA/Bi–Gd) nanofibers were prepared using electrospinning technique then calcinated at 800 °C for 2 h. The originality of this study is the addition of boron to metal acetates. The effects of boron doping were investigated in terms of solution properties, morphological changes and thermal characteristics. The characteristics of the fibers were investigated with FT-IR, XRD, SEM and BET. The addition of boron did not only increase the thermal stability of the fibers, but also their diameters, which yielded stronger fibers. XRD analyses showed that boron doping increased the peak intensities and indicated that the boron doping enhanced the crystallite size. Moreover, no shifts were noticed in diffraction angles for boron doped and undoped samples. Therefore, boron doping did not significantly alter the lattice spacing. The SEM micrograph of the fibers showed that the addition of boron resulted in the formation of cross-linked bright-surfaced fibers. The average fiber diameter for boron doped and undoped fiber mats were 204 and 123 nm, respectively. Also, grain diameters of boron doped and undoped nanocrystalline sintered powders were measured as 140 and 118 nm, respectively. The BET results showed that boron undoped and doped Bi₂O₃–La₂O₃ nanocrystalline powder ceramic structures sintered at 800 °C have surface areas of 59.72 and 39.80 m²/g, respectively.     

Whey protein nanoparticles prepared with desolvation with ethanol: Characterization,thermal stability and interfacial behavior

Whey protein isolate (WPI) nanoparticles were prepared by diluting an alkaline solution of protein in ethanol at concentrations varying between 50 and 80%. The nanoparticles were then immediately diluted in buffer. While the nanoparticles were not stable at pH 7, they showed no changes in size when diluted at pH 3. When 75–80% ethanol was added during preparation, the size of the WPI nanoparticles ranged between 10 and 100 nm, with no change in size after dilution and storage at pH 3 for 96 h at 22 °C. When heating was applied, particle aggregation occurred, and large aggregates (>1 μm) were observed at temperatures > 60 °C. The particle size of the heat-induced aggregates could be reduced by homogenization. The nanoparticles prepared by desolvation showed interfacial pressure values similar to those of the corresponding protein solutions, indicating similar interfacial properties and the potential to be used to stabilize emulsions but as supramolecular aggregates of WPI.     

Molecular characterization of mulberry (Morus spp.) genotypes via RAPD and ISSR

BACKGROUND: In recent years, DNA‐based markers have been used quite extensively because of their many advantages over the traditional morphological and biochemical markers. Many studies have shown that molecular markers are useful in delineating the genetic relationships among closely related mulberry genotypes and cultivars. Thus, in the present study, polymer chain reaction based DNA fingerprinting techniques were used to investigate the genetic relationships among mulberry genotypes growing in different agro‐climatic regions of Turkey. RESULTS: 20 RAPD primers generated a total of 173 bands, of which 157 (90.75%) were polymorphic. As for 11 ISSR primers, 124 bands (96.55%) were polymorphic in a total of 128. The similarity index for RAPD technique ranged between 0.24–0.98; 25?s203 with 25?s112 were found to be the closest genotypes, while 24Ke10 and 25?s123 were the most distant ones. According to the ISSR result, the genetic similarity index changed between 0.21–095; 25?s203 with 25?s112 genotypes were the closest, while 25?s08 and 01KaD2 were the most distant ones. CONCLUSION: The RAPD and ISSR markers were found to be promising for assessing genetic diversity in mulberry genotypes. Copyright © 2011 Society of Chemical Industry