固液两相单位体积的吉布斯自由能差的研究

推导出凝固热力学中固液两相单位体积的吉布斯自由能差为ΔＧＶ＝Ｌｍξ／（αＴｍξ－１）－Ｔｍ（ＣＶＳ－ＣＶＬ）［ξ＋（１－ξ）ｌｎ（１－ξ）］     

Influence of additive element on surface oxide film ofA356 alloy

The influences of RE-modification and Sr-modification on the hydrogen content and surface oxide film ofA356 aluminum alloy melt were investigated. The hydrogen content of the melt was measured by reduce pressure test. The phases in the surface oxide film were analyzed by X-ray diffractometry （XRD）, and the morphology of the surface oxide film was observed by scanning electronic microscopy （SEM）. The results show that RE-modification reduces the hydrogen content ofA356 aluminum alloy greatly. Contrarily, Sr-modification increases the hydrogen content remarkably. After being treated with RE, a large number of LaAl11O18 consisting of Al2O3 and La2O3, are generated in the surface oxide film of A356 alloy. The surface oxide film of Sr-modification is almost composed of Al2SrO4. According to the results of SEM, the surface oxide film of Sr-modification is very easy to crack, destroy the continuity and compactness of surface oxide film, accelerate the vapor diffusing into the melt, consequently, increase the hydrogen content of A356 alloy melt significantly. But RE-modification makes the surface oxide film compact, and restrains the aluminum exposed to water, so reduces the hydrogen content ofA356 alloy melt.     

雾化Al-Si合金液滴冷却凝固过程模拟

在群体动力学模型基础上，提出了描述雾化共晶合金液滴组织演变的数学模型，并将其与液滴的运动与传热方程相耦合，对合金的冷却凝固过程进行研究，探讨液滴尺寸对合金冷却凝固过程的影响，结合A390合金进行了计算。结果表明：随着液滴尺寸的减小，所获得的冷却速度及过冷度增大，而析出初生Si相的尺寸及体积分数减小，当液滴尺寸足够小时，液滴温度的变化趋势及微观组织将发生突变。     

EFFECT OF MELT SUPERHEAT ON DIRECTIONAL SOLIDIFICATION PROPERTIES OF Al-Cu ALLOY

本文研究了熔液过热对溶质分配系数及对定向凝固过程中界面形态临界条件的影响。 研究发现,实际溶质分配系数是液体状态的函数。提高熔液过热度导致实际溶质分配系数的增大(K_o<<的元素),并减小固-液界面形态稳定的临界比值(G/R),从而有利于定向凝固的进行。     

单晶Cu-Al系形状记忆合金制备研究

设计单晶熔炼炉和单晶结晶器炼制单晶Cu-Al-Be和Cu-Al-Ni来减轻晶界影响。该装置的新颖性在于单晶结晶器从单晶炉的顶端自上而下通过整个炉膛完成选晶,并且保证单晶稳定生长。试验研究表明,自行设计制造的单晶定向凝固炉成功地拉制出了Cu-Al-Be形状记忆合金单晶试样。     

高硅Al-Si合金活塞材料研究进展

论述了Al-Si活塞合金主要的制备方法和应用现状,以及存在的问题.要得到性能优异的Al-Si活塞材料,快速凝固和后期处理相结合的方法将是一条重要路径.     

行星盘挤压铸造成型工艺分析及优化

对压缩机行星盘挤压铸造成型工艺进行分析及优化.应用光镜对挤压铸造成型行星盘铸件在机械加工过程中的开裂故障进行分析,并对其偏析层分布及厚度进行统计分析.残留在枝晶间的共晶液体受挤压使先析出的枝晶结构破坏,沿着枝晶间的通道向铸件外表面流动,在随后冷却凝固过程中形成了表面共晶偏析组织.塑性较差的共晶偏析组织与氧化夹杂共同作用,使毛坯在随后的收口加工过程中出现裂纹破坏.增加铸件外轮廓尺寸使加工余量增加到0.6～0.8 mm,可望将引起裂纹破坏的偏析层切除,从而消除裂纹源,使由于裂纹而导致的报废几率明显减小.