Electrochemical preparation and properties of polypyrrole and its blend with poly(vinyl sulfonate) doped with perchlorate anions

In this article, we report polypyrrole (PPy)/poly(vinyl sulfonate) (PVS) and PPy/perchlorate (ClO) composite films generated by the electrochemical oxidation of pyrrole on a glassy carbon electrode (GCE) in an aqueous solution. The response of the produced films to an applied potential at 0.7 V was obtained by a cyclic voltammetry study in acetonitrile media. The films were significantly similar in their electrochemical behavior when ClO ions doped during the redox process. We concluded that with an increasing number of cycles, the anodic current increased because the number of the electroactive participants transported in the copolymer matrix was increased. Theoretical studies based on the Nernst and Butler–Volmer equations indicated that the ClO ion was transported during the oxidation/reduction process of the PPY/PVS and PPY/ClO films. The produced films were characterized further by means of IR spectroscopy, electrochemical impedance spectroscopy, and scanning electron microscopy to verify that the anion of ClO was doped into the copolymer matrix as well. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Risk constrained self-scheduling of hydro/wind units for short term electricity markets considering intermittency and uncertainty

In view of the intermittency and uncertainty associated with both the electricity production sector of restructured power system and their competitive markets, it is necessary to develop an appropriate risk managing scheme. So that it is desirable to trade-off between optimum utilization of intermittent generation resources (i.e. renewable energy resources), uncertain market prices and related risks in order to maximize participants' benefits and minimize the corresponding risks in the multi-product market environment. The main goal of this paper is to investigate risk management by introducing a novel multi-risk index to quantify expected downside risk (EDR) which is caused by both the wind power and market price uncertainties. Value-at-Risk (VaR) method is used to assess the mentioned risk issue by the proposed weighted EDR, so that an optimal trade-off between the profit and risk is made for the system operations. Also, the roulette wheel mechanism is employed for random market price scenario generation wherein the stochastic procedure is converted into its respective deterministic equivalents. Moreover, the autoregressive integrated moving average (ARIMA) model is employed to characterize the stochastic wind farm (WF) generation by predetermined mean level and standard deviation of wind behavior as well as temporal correlation. The problem is formulated as a mixed-integer stochastic framework for a hydro-wind power system scheduling and tested on a generation company (GENCO).     

Recognition of electrocardiographic left arm/left leg lead reversal

The electrocardiographic error of left arm/left leg lead reversal is difficult to identify. PI amplitude greater than PII as a terminal positive component to PIII may diagnose 90% of such errors.     

Verification of numerical study of scour around spur dikes using experimental data

Scour phenomenon around a series of impermeable, nonsubmerged spur dikes has been investigated with both experimental and numerical methods. The experiments were conducted under different states of flow intensity (U/U_cr). The scour geometry was measured with a high‐resolution laser bed‐profiler (LBP). For the numerical simulation phase, a three‐dimensional computational fluid dynamics (CFD) model, namely SSIIM 2.0, was used to compute the sediment transport around the spur dikes. The numerical model was based on the finite‐volume method. Two turbulence models, namely k‐ε standard and k‐ε with re‐normalization group (RNG) extensions, were used to predict turbulence, and the k‐ε model with some RNG extensions was selected because of its best agreement with the measurements. Furthermore, a variety of grids and empirical sediment transport equations were used to find the best state for simulation of scour around a series of spur dikes. Finally, a comparison between experimental and numerical results was carried out to verify the CFD model.     

Reanalyzing the basic bandgap reference voltage circuit considering thermal dependence of bandgap energy

The basic bandgap reference voltage generator, BGR, is thoroughly analyzed and relations are reconstructed considering dependency of bandgap energy, E_g, to absolute temperature. The previous works all consider E_g as a constant, independent of temperature variations. However, E_g varies around 25 meV when the temperature is increased from 2 to 92 °C. In this paper the dependence of E_g to absolute temperature, based on HSPICE mosfet models in HSPICE MOSFET Models Manual (Version X-2005.09, 2005), is approximated by a third-order polynomial using Lagrangian interpolating method within the temperature range of 2–92 °C. Accurate analysis on the simplified polynomial reveals that the TC of V_BE must be corrected to ?1.72 mV/°K at 27 °C which has been formerly reported about ?1.5 mV/°K in Razavi (Design of analog CMOS integrated circuits, 2001) and Colombo et al. (Impact of noise on trim circuits for bandgap voltage references, 2007), ?2 mV/°K in Gray et al. (Analysis and design of analog integrated circuits, 2001), Leung and Mok (A sub-1-V 15-ppm/°C CMOS bandgap voltage reference without requiring low threshold voltage device, 2002), Banba et al. (A CMOS bandgap reference circuit with sub-1-V operation, 1999), and ?2.2 mV/°K in Jones and Martin (Analog integrated circuit design, 1997), Tham and Nagaraj (A low supply voltage high PSRR voltage reference in CMOS process, 1995). Another important conclusion is that the typical weighting coefficient of TC+ and TC? terms is modified to about 19.84 at 27 °C temperature from otherwise 16.76, when E_g is considered constant, and also 17.2, in widely read literatures, (Razavi in Design of analog CMOS integrated circuits, 2001). Neglecting the temperature dependence of E_g might introduce a relative error of about 20.5 % in TC of V_BE. Also, resistance and transistor size ratios, which denote the weighting coefficient of TC+ term, might be encountered to utmost 20.3 % error when the temperature dependence of E_g is ignored.     

Life-cycle prediction of steel bridges using reliability-based fatigue deterioration profile: Case study of neka bridge

Fatigue deterioration profiles of critical elements in a railway truss bridge are determined using a probabilistic approach. A performance function including fatigue strength, R, and fatigue action, D, is used, where R is a material property with lognormal distribution. The random variable D depends on AASHTO category, stress spectrum and traffic features. By applying Monte-Carlo simulations on the performance function of each year, reliability index profile is calculated. The reliability profile decreases with life, and whenever reaches to a critical value, an MR&R action should be implemented. A numerical approach is presented to specify the effects of MR&R actions on the deterioration profile. These actions include re-welding, attaching CFRP and combination of them. The structural model is calibrated by results of a loading test. In addition, the uncertainties arisen from future traffic volume and the relevant S-N curve are considered by a statistical analysis. For a target reliability of 2.0, the retrofit time for deck and truss are estimated. Finally, the outputs of the research are used to recommend a plan for maintenance of Neka Bridge.     

Novel single-stage second-order structure for low-pass wide-band low-power continuous-time filters

A novel single-stage second-order structure for Gm-C filters is presented. It allows ample reduction in hardware and thus power consumption. Moreover, due to exploiting otherwise parasitic poles, the structure allows much higher bandwidth than in conventional designs, be achieved. To verify effectiveness of new concept, and based on the new approach to implement second-order stages, a third-order and a fifth-order continuous-time low-pass filters were implemented. The filters fabricated in a CMOS process, achieved more than 430 MHz, bandwidth and less than THD for a 400 mV_p–p 100 MHz input signal. All these accomplished with a factor of about four reduction in hardware and power. The bandwidth, output voltage swing, and dynamic range are far larger than those of any other CMOS low-pass filters thus far reported, which have bandwidth higher than 100 MHz.     

An effectiveness analysis of information channeling in choice decision making with attribute importance weights

In multi-alternative, multi-attribute choice decision tasks, decision makers use either alternative-based or attribute-based information processing patterns. Evidence suggests that channeling of access patterns may be effective. Restricted search of only key information attributes may be further encouraged when importance weights for attributes are predetermined and provided to the decision makers. This study examines the effectiveness of alternative-based channeling and attribute-based channeling with or without the provision of attribute importance weights. Both alternative-based and attribute-based channeling improves the decision accuracy when attribute weights are provided. In addition, the results indicate statistically significant effects on decision accuracy for the type of information display.     

Frequency–amplitude relations for cross‐coupled voltage‐controlled oscillator

Dependence of frequency on amplitude and control bias is considered for the cross‐coupled voltage‐controlled oscillator. Closed form expressions are derived for frequency of oscillation as a function of amplitude, for positive and negative control bias voltages. Theory of nonlinear ordinary differential equations is utilized to show that the capacitance–voltage relation is the main cause of frequency shift with amplitude. Furthermore, the case of small amplitudes relative to control voltage is analyzed, and a closed form expression is derived for dependence of frequency on amplitude. This relation is then verified using the concept of effective capacitance. The effective capacitance approach is also used to extend the analysis to large voltage swings. Dependence of frequency on tuner control voltage is calculated for both bias polarities. Implications of the aforementioned equations for voltage‐controlled oscillator performance are discussed. Numerical calculations and simulations are used to compare and verify the closed form equations, showing good agreement. Copyright © 2012 John Wiley & Sons, Ltd.     

Poly (vinyl alcohol)/graphene oxide nanocomposite films and hydrogels prepared by gamma ray

ABSTRACT

Poly (vinyl alcohol)/graphene oxide (PVA/GO) gamma irradiated nanocomposite films and hydrogels were prepared. In composite films, GO was initially irradiated by gamma ray in order to improve interactions between GO and PVA. The film containing 1?wt-% GO was very strong where tensile modulus and tensile yield strength were 45 and 115% higher than those of pure PVA. In the second set of experiments PVA/GO hydrogels were made by irradiating PVA/GO suspensions by gamma ray at various doses. It was an interesting finding that GO increased the gel portion of hydrogels through contribution of H-bonds between PVA and GO. The hydrogels prepared at 20?kGy had remarkable water swelling ratio that reached as high as 20 at water temperature of 80°C. The hydrogel metal ion adsorption capability was tested on Cu²⁺ ions. It was shown that the GO contributed significantly to the adsorption capacity of PVA hydrogels.