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In this paper, synthetic leather samples were screen printed with pigmented pastes including two types of photoinitiators and three different concentrations of ultraviolet (UV)‐curable water‐borne polyurethane acrylate binder. The curing process was conducted under different combinations of lamps (gallium, mercury, gallium/mercury and gallium/gallium/mercury) at three power levels. Abrasion resistance, crock fastness, hardness and colour strength were investigated. Chemical changes in the clear and pigmented film structures because of UV curing were analysed by Fourier Transform‐infrared spectroscopy measurements. In hardness measurements, the highest hardness values were obtained with clear and pigmented formulations which have the highest solid content (57%). In colour measurements, higher K/S values were obtained in samples printed with the formulation having a binder concentration of 46%. Wet crock fastness values improved as the energy level increased during curing, and the highest values were obtained with a formulation which had a binder concentration of 57%. Greater amounts of binder in the formulations and increased amounts of energy applied to the surface during curing increased the hardness value of the prints, thus better abrasion resistance was obtained. Overall results suggested that the highest hardness, crock fastness and abrasion resistance values were obtained with the formulation with a binder concentration of 57%. However, for ease of application, printing efficiency and colour strength, the formulation with a binder concentration of 46% is recommended for printing, and curing under consecutive passes with gallium and mercury lamps at 120 W/cm is proposed in terms of energy efficiency and printing performance.  相似文献   
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Despite the outstanding role of mesoscopic structures on the efficiency and stability of perovskite solar cells (PSCs) in the regular (n–i–p) architecture, mesoscopic PSCs in inverted (p–i–n) architecture have rarely been reported. Herein, an efficient and stable mesoscopic NiOx (mp-NiOx) scaffold formed via a simple and low-cost triblock copolymer template-assisted strategy is employed, and this mp-NiOx film is utilized as a hole transport layer (HTL) in PSCs, for the first time. Promisingly, this approach allows the fabrication of homogenous, crack-free, and robust 150 nm thick mp-NiOx HTLs through a facile chemical approach. Such a high-quality templated mp-NiOx structure promotes the growth of the perovskite film yielding better surface coverage and enlarged grains. These desired structural and morphological features effectively translate into improved charge extraction, accelerated charge transportation, and suppressed trap-assisted recombination. Ultimately, a considerable efficiency of 20.2% is achieved with negligible hysteresis which is among the highest efficiencies for mp-NiOx based inverted PSCs so far. Moreover, mesoscopic devices indicate higher long-term stability under ambient conditions compared to planar devices. Overall, these results may set new benchmarks in terms of performance for mesoscopic inverted PSCs employing templated mp-NiOx films as highly efficient, stable, and easy fabricated HTLs.  相似文献   
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In this study, structural, morphological and optical properties, and gas sensor performance of magnesium oxide (MgO) doped titanium dioxide (TiO2) thin films were investigated in detail. Gas sensor metallic patterns were fabricated on Si substrate using traditional photolithographic technique. MgO doped TiO2 thin films were deposited on formed Pt electrode surface by confocal sputtering (co-sputtering) system as the active layer. Thin film characterizations were realized by using secondary ion mass spectroscopy (SIMS), atomic force microscope (AFM) and UV–Vis Spectrometer (UV–Vis). Gas sensing measurements were performed by gas sensing test system against methane gas at working temperature of 300?°C. To evaluate deposition and thermal annealing effects on the sensing performance, sensors were tested under gas. The sensitivity and response/recovery time of gas sensors were measured in 1000?ppm. MgO doped TiO2 based sensor at substrate temperature of 100?°C has high sensitivity and short response/recovery time.  相似文献   
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Silicon nitride-based ceramics have provided significant advantages due to their high chemical resistance, high elastic modulus, and combination of hardness and fracture toughness (depending on self-reinforcement). Over the past two decades, a significant amount of interest has been generated for the bio-applications of these materials. However, the effect of the grain boundary phase on such applications is still not very well understood. In this study, the effect of different cations on biological (such as antibacterial and cytocompatibilty) and material properties (like wetting angles and isoelectric points [IEP]) of oxynitride glasses, mimicking the grain boundary phase in Si3N4 and SiAlON ceramics, were investigated. Results revealed that the antibacterial behavior and mammalian cell viability were inversely correlated in glasses with rare-earth cation additions. Ca was the best cation when the two properties (bacterial response and cell proliferation) were considered together, and, thus should be further studied for a wide range of applications.  相似文献   
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BACKGROUND: Prospective studies have shown that doses equivalent to conjugated equine estrogens of 0.625 mg/d or higher are needed to produce a significant increase in bone mineral density of the lumbar spine. OBJECTIVES: To determine the effects of unopposed esterified estrogens on bone mineral density, lipid levels, and endometrial tissue structure, and to relate these effects to changes in plasma estradiol levels. METHODS: Four hundred six postmenopausal women were given calcium, 1000 mg/d, and randomly assigned to receive continuous esterified estrogens (0.3, 0.625, or 1.25 mg/d) or placebo for 24 months. Bone mineral density measurements and endometrial and laboratory assessments were conducted every 6 months; plasma estradiol concentrations were measured after 12, 18, and 24 months. RESULTS: All doses of esterified estrogens produced significant increases in bone mineral density of the lumbar spine compared with baseline and with placebo at 6, 12, 18, and 24 months. Mean plasma estradiol levels increased with esterified estrogens dose, and individual subject bone mineral density changes appeared related to plasma estradiol concentrations. Clinically relevant rates of endometrial hyperplasia were noted only in the groups receiving 0.625 and 1.25 mg of esterified estrogens daily. Lipid changes were dose related and apparent in all groups. CONCLUSIONS: Esterified estrogens at doses from 0.3 to 1.25 mg/d, administered unopposed by progestin, produce a continuum of positive changes on bone and lipids. Plasma estradiol concentrations increased with esterified estrogens dose and were related to positive bone mineral densities. The 0.3-mg dose resulted in positive bone and lipid changes without inducing endometrial hyperplasia.  相似文献   
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In this paper, a new position control method based on the reaching law control (RLC) approach is proposed for the robust position control of electrical drive systems. The main aim of this study is to investigate the robustness of the RLC approach under inertial-frictional variations and external disturbances and to address the application problems of the RLC approach for position control systems. New components are added to the controller in order to improve the robustness. The control method is applied to a vector-controlled induction motor drive system. It is shown in the paper that the practical constraints such as torque limitation, and the demand of high control performance, i.e., high bandwidth, result in undesirable overshoots. The performance of the control method is shown by simulation and experimental results.List of symbols X, X k Continuous and discrete-time state vectors - x 1, x 2 State variables (the shaft position and speed of the rotor) - , re Position and reference angles (rad) - Angular velocity (rad/s) - A,A n State variable matrix with true and nominal parameters - B,B n Control input matrix, with true and nominal parameters - u,u max Control signal, and its maximum value - A,B Uncertain parts of the state matrix and the control input matrix - Equivalent terms of A, B uncertainties referred to matching condition - C Gain vector of switching function - s k Switching function - q A constant used in the reaching law - A constant used in the reaching law - A constant used in the chattering reduction approach - T sampling period - J,J n True and nominal inertia coefficient (kg m2) - B,B n True and nominal friction coefficient (kg m2/s) - J,B The uncertain parts of the inertia and friction coefficients - T e Produced (electrical) torque (control signal) (Nm) - Load torque (Nm) - Equivalent term of A referred to matching condition and scalar component - Equivalent term of B referred to matching condition - All uncertainties and disturbances referred to matching condition - J0,B0 The variation ratios of the inertia and friction coefficients - G State variable matrix in discrete-time model - H Control input matrix in discrete-time model - Slope of the sliding line (surface) - a Mechanical time constant - v sd, v sq Stator voltages in d-q axis (V) - i sd, i sq Stator currents in d-q axis (A) - L s, L R Stator and rotor self inductances (H) - L m Mutual inductance (H) - Leakage factor - e, sl Stator and slip angular velocity (rad/s) - r Rotor time constant - P Number of poles  相似文献   
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