全文获取类型
收费全文 | 1894篇 |
免费 | 104篇 |
国内免费 | 8篇 |
专业分类
电工技术 | 36篇 |
综合类 | 2篇 |
化学工业 | 422篇 |
金属工艺 | 39篇 |
机械仪表 | 46篇 |
建筑科学 | 54篇 |
矿业工程 | 2篇 |
能源动力 | 111篇 |
轻工业 | 206篇 |
水利工程 | 19篇 |
石油天然气 | 40篇 |
无线电 | 221篇 |
一般工业技术 | 394篇 |
冶金工业 | 88篇 |
原子能技术 | 11篇 |
自动化技术 | 315篇 |
出版年
2024年 | 4篇 |
2023年 | 52篇 |
2022年 | 98篇 |
2021年 | 136篇 |
2020年 | 83篇 |
2019年 | 74篇 |
2018年 | 114篇 |
2017年 | 101篇 |
2016年 | 94篇 |
2015年 | 59篇 |
2014年 | 79篇 |
2013年 | 153篇 |
2012年 | 114篇 |
2011年 | 116篇 |
2010年 | 79篇 |
2009年 | 93篇 |
2008年 | 73篇 |
2007年 | 78篇 |
2006年 | 52篇 |
2005年 | 43篇 |
2004年 | 35篇 |
2003年 | 35篇 |
2002年 | 17篇 |
2001年 | 9篇 |
2000年 | 16篇 |
1999年 | 14篇 |
1998年 | 12篇 |
1997年 | 17篇 |
1996年 | 13篇 |
1995年 | 16篇 |
1994年 | 12篇 |
1993年 | 14篇 |
1992年 | 10篇 |
1991年 | 12篇 |
1990年 | 8篇 |
1989年 | 8篇 |
1988年 | 6篇 |
1987年 | 7篇 |
1986年 | 6篇 |
1985年 | 7篇 |
1984年 | 6篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 8篇 |
1980年 | 3篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1970年 | 2篇 |
排序方式: 共有2006条查询结果,搜索用时 0 毫秒
91.
Mohammed A. Amin Hamdy H. Hassan Omar A. Hazzazi Mohsen M. Qhatani 《Journal of Applied Electrochemistry》2008,38(11):1589-1598
The study of both meta-stable and stable pitting events on the surface of pure Al and three Al–Si alloys, namely (Al + 6%Si),
(Al + 12%Si) and (Al + 18%Si) alloys, was carried out in deaerated neutral NaClO4 solutions of various concentrations (10−4–10−2 M). Measurements were carried out under the effect of various experimental conditions using potentiodynamic anodic polarization
and potentiostatic techniques. The results presented below showed that meta-stable pits (appeared as oscillations in current)
form at potentials close to the pitting potential (E
pit) and during the induction time for stable pit formation. Various factors affecting the rate of meta-stable and stable pits
were studied. The presence of Si as an alloying element in Al reduces the rate of formation of meta-stable pits, corresponding
to a reduction in the probability of developing stable pits, and an increase in the pitting potential results. The inhibitive
effects of chromate, silicate, molybdate and tungstate on pitting corrosion in Al were also studied. Results obtained showed
that these known inhibitors retard both meta-stable and stable pitting events. This makes attainment of stable pit growth
more difficult in presence of these inhibitors.
相似文献
Mohammed A. AminEmail: |
92.
Cutting process of titanium alloy Ti-6Al-4V is considered difficult due to chemical affinity between tool and work material, adhesion, built-up edge and burr formation, and tool wear resulting in loss of productivity. Three dimensional (3-D) chip flow together with local field variables such as temperature, elastic/plastic strain, strain-rate and velocity in the shear zones during micro milling process can be predicted using continuum-mechanics based 3-D Finite Element (FE) modelling and simulation of elastic/viscoplastic work material deformations. This paper provides much needed process insight for chip flow, built-up edge and burr formation by using modeling work with experimental validation. Scanning electron microscopic (SEM) observation of the 3-D chip morphology and burrs demonstrate ductile fractured surfaces together with localized instability and failure behaviors. FE simulations are utilized to investigate the effects of micro milling operation i.e. up and down milling and tool edge radius on 3-D chip flow, built-up edge, and 3-D burr formation. Simulated results are compared with measurements of chip morphology, shape, and dimensions together with tool edge condition of built-up edge and chip adhesion yielding to good agreements. 相似文献
93.
Omar Azouani Mourad Keddam Omar Allaoui Abdelaziz Sehisseh 《Protection of Metals and Physical Chemistry of Surfaces》2017,53(2):306-311
In this work, the EN-GJS-400-15 cast iron was pack-borided in a powder mixture composed of 5% B4C, 5% NaBF4 and 90% SiC at the three temperatures: 900, 950 and 1000°C for 2, 4 and 6 h, respectively. The pack-borided EN-GJS-400-15 cast iron was characterized by the following experimental techniques: optical microscopy, XRD analysis and Microhardness Vickers tester. The growth kinetics of boride layers was also investigated. As a consequence, the boron activation energy was found to be 212.28 kJ mol–1 for the EN-GJS-400-15 cast iron. Based on a regression model, a useful equation was derived to estimate the boride layer thickness as a function of the boriding parameters (time and temperature). A good agreement was then obtained between the predicted values of boride layers thicknesses and those measured experimentally. In addition, an iso-thickness diagram was proposed to be used as a simple tool to select the boride layers thicknesses according to the potential applications of EN-GJS-400-15 cast iron in industry. 相似文献
94.
Commercially available cellulose (Avicel PH101) was successfully acylated under homogeneous solution conditions by the following novel procedure: 2.0 g of cellulose and 5.0 g of LiCl were introduced into a glass reactor, magnetic stirring was started, the pressure was reduced to 2 mmHg, the temperature was raised to 110°C in 30 min, and the reactor was kept under these conditions for another 30 min. N,N‐Dimethylacetamide, 60 mL, was introduced, atmospheric pressure was restored, and the temperature was raised to 150°C in 30 min. The system was kept under these conditions for 1 h, then the temperature was decreased to 40°C; in 2 h a clear cellulose solution was obtained. Acid anhydride was added, and the solution was stirred at 60°C for additional 18 h. Acetates, propionates, butyrates, and acetate/butyrate mixed ester were prepared with excellent reproducibility of the degree of substitution, from 1 to 3. The degree of polymerization of cellulose is negligibly affected by these reaction conditions. The distribution of the acetyl moiety among the three OH groups of the anhydroglucose unit follows the order C6 > C2 > C3. Features relevant to the industrial application of this novel procedure are discussed. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 74: 1355–1360, 1999 相似文献
95.
Alka Gupta Ambreen Nisar Shobit Omar Kantesh Balani 《JOM Journal of the Minerals, Metals and Materials Society》2018,70(10):1937-1945
The grain growth kinetics of 8YSZ ceramics processed using spark plasma sintering (SPS) has been investigated in the temperature ranging from 1100°C to 1500°C. The activation energy during SPS densification was obtained as 332 kJ/mol with grain boundary diffusion as a dominant mechanism. Further, the effect of CeO2 on the densification kinetics of 8YSZ ceramic processed via SPS and conventional sintering (CS) has been delineated. The lower grain boundary mobility of CS-processed composites (an order of magnitude lower than SPS) is attributed to the solute drag and lattice distortion mechanism. However, no significant change in the grain boundary mobility was observed with CeO2 addition (~?14.7–43.9?×?10?18 m3/N/s for CS and 107.2–116.7?×?10?18 m3/N/s for SPS) revealing that the defect concentration is nearly constant in 8YSZ. The study highlights the effect of sintering techniques (SPS and CS) and reinforcement (CeO2) on engineering the desired microstructure of 8YSZ ceramic. 相似文献
96.
In this study, pure rhodium was fabricated and mechanically investigated at the nanoscale for the first time. The nanopillars approach was employed to study the effects of size on the yield point. Nanopillars with different diameters were fabricated using electroplating followed by uniaxial compression tests. Scanning electron microscopy (SEM) was used as a quality control technique by imaging the pillars before and after compression to ensure the absence of cracks, buckling, barrelling or any other problems. Transmission electron microscopy and SEM were used as microstructural characterization techniques. Due to substrate-induced effects, only the plastic region of the stress–strain curves were investigated, and it was revealed that the yield point increases with size reduction up to certain limit, then decreases with further reduction of the nanopillar size (diameter). The later weakening effect is consistent with the literature, which demonstrates the reversed size effect (the failure of the plasticity theory) in nanocrystalline metals, i.e. smaller is weaker. In this study, however, the effect of size reduction is not only weakening, but is strengthening-then-weakening, which the authors believe is the true behavior of nanocrystalline materials. 相似文献
97.
A fluidized bed crystallization technology was found to be a feasible method for the reduction of scaling tendency of seawater. Seeded crystallization experiments in a pilot plant fluidized bed crystallizer were conducted. The obtained results for seawater, with initial salinity of 55.75 g/kg and initial pH of 8.23 at a constant temperature of 50 °C, have proven that the Ryznar Stability Index of seawater has been changed dramatically from its initial value of 4.77 (in the range of high scaling potential) to the value of 5.10 (in the range of middle to small scaling potential) over a time period of 180 min. 相似文献
98.
Shamila Vibhushan Manuela Bratti Juan Eduardo Montero-Hernndez Alaa El Ghoneimi Marc Benhamou Nicolas Charles Eric Daugas Ulrich Blank 《International journal of molecular sciences》2021,22(1)
A sizable part (~2%) of the human genome encodes for proteases. They are involved in many physiological processes, such as development, reproduction and inflammation, but also play a role in pathology. Mast cells (MC) contain a variety of MC specific proteases, the expression of which may differ between various MC subtypes. Amongst these proteases, chymase represents up to 25% of the total proteins in the MC and is released from cytoplasmic granules upon activation. Once secreted, it cleaves the targets in the local tissue environment, but may also act in lymph nodes infiltrated by MC, or systemically, when reaching the circulation during an inflammatory response. MC have been recognized as important components in the development of kidney disease. Based on this observation, MC chymase has gained interest following the discovery that it contributes to the angiotensin-converting enzyme’s independent generation of angiotensin II, an important inflammatory mediator in the development of kidney disease. Hence, progress regarding its role has been made based on studies using inhibitors but also on mice deficient in MC protease 4 (mMCP-4), the functional murine counterpart of human chymase. In this review, we discuss the role and actions of chymase in kidney disease. While initially believed to contribute to pathogenesis, the accumulated data favor a more subtle view, indicating that chymase may also have beneficial actions. 相似文献
99.
Gualberto Antonio Zumbardo-Bacelis Linnette Aracely Meza-Villegas Cesar Antonio Pérez-Aranda Rossana Vargas-Coronado Omar Castillo-Cruz Vanessa Montaño-Machado Diego Mantovani Juan Valerio Cauich-Rodríguez 《应用聚合物科学杂志》2021,138(42):51247
Polymer blends based on Tecoflex™ and an experimental aliphatic polyurethane (HMDI-PCL-arginine stands for 4,4 (metylene-biscyclohexyl) isocyanate - poly (ε caprolactone) diol, SPUUR stands for segmented poly(urea)urethanes using amino acid of L-Arginine as chain extender) were obtained by solvent casting, and further studied by fourier transform infrared (FTIR) and Raman spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis, and X-ray diffraction (XRD). Their biological performances were assessed in terms of hemocompatibility and Human umbilical vein endothelial cell (HUVEC) cytotoxicity. Tensile properties of dumbbell specimens were compared to longitudinal and circumferential tensile properties of tubular vascular graft. FTIR showed that as the SPUUR content increased in the blend, absorptions at 2860 cm−1 increased, carbonyl absorptions at 1724 cm−1 broaden and the small peak at 2796 cm−1, typical of Tecoflex™ disappeared. Raman spectroscopy showed that the low intensity carbonyl absorption at 1724 cm−1 also increased with SPUUR content. DSC allowed detection of PCL soft segment melting (Tm = 50°C) in agreement with X-ray reflections at 21.3° and 23.6°, assigned to SPUUR. However, no improvements in thermal stability were detected by TGA by blending. The addition of SPUUR to Tecoflex™ improved hemocompatibility and HUVEC cytotoxicity. The vascular grafts performance showed that 40% SPUUR blends exhibited the highest force in the longitudinal test whereas 50% SPUUR blends showed the highest circumferential force. Pressure burst strength was higher than 1000 mmHg for all blends. Overall, these blends can be used for high caliber vascular grafts. 相似文献
100.